Digital Commons Network^™

Studies Of Electrocatalytic Properties Of Electrode Of Dispersed Pt On Gc Support In Ethylene Glycol Oxidation, Shengpei Chen, Shigang Sun, Zhiyou Zhou, Shuanjing Hong

Journal of Electrochemistry

The structures and properties of electrocatalyst of dispersed Plutinum (Pt) on glassy carbon (GC) support under different conditions were studied using cyclic voltammetry, potential step technique, X-ray diffraction (XRD) and scanning Electron microscopy (SEM). The results indicated that after having been treated in high temperature,the dispersed Pt on GC support was recrystallised with preferented orientation, and the grain of Pt microcrystal become large and regular. It was illustrated that the dispersed Pt on GC support after high temperature treatment exhibited better stability and high activity for ethylene glycol oxidation.

Polymer Electrolyte Fuel Cell Powered Vehicles, Naichao Li, Baolian Yi

Journal of Electrochemistry

The background, status and commercialization prospect of polymer electrolyte fuel cell vehicles are surveyed in this paper. The technology of this cell and system used in vehicles is discussed.

Electrochemical Behavior Of Superoxide Dismutase On Gold Minigrid With Thin Layer Cell, Xiaqin Wu, Qian Liu, Bin Xu, Xiaoyun Men, Zongrang Zhang

Journal of Electrochemistry

The electrochemical behavior of superoxide dismutase (Cu, Zn-SOD) was investigated on gold wire electrode and gold minigrid with thin layer cell by cyclic voltammetry. A quasi reversible redox wave of SOD has obtained on gold minigrid thin layer electrode, but only oxidation peak has observed on gold wire electrode. The electrochemical reaction parameters, such as the formal potential E^0′, diffusion coefficient D and standard rate constant k^0′ were estimated.

Surface Modification Of Molten Carbonate Fuel Cell Anode, Baizeng Fang, Xinyu Liu, Xindong Wang, Shuzhen Duan

Journal of Electrochemistry

In this study, the anode material of molten carbonate fuel cell was modified by the deposition of niobium on nickel surface. The results of polarization experiments reveal that the corrosion resistant properties as well as electrocatalytic activity have been improved greatly.

Electroluminescence Of Photoelectrochemically Etched N+-Si, Guozheng Li, Chengqian Zhang, Xiumei Yang

Journal of Electrochemistry

Porous silicon with micrometer size pores, which is made on n⁺-Si by photoelectrochemically etched, has electroluminescent property. Each monochromic intensity and wavelength range of luminescent spectra depend on polarized potential. The intersity and the stability of cathodic electroluminescence is high than those of anodic one. Voltammetric behavior before quenching indicated that the electrochemical reactions of some surface species are involved in except the reduction of S₂O₈^2-, which leads to radiative recombination. The energy band diagram based on n⁺-Si(E_g=1.1 eV)/PS(E_g=1.8 eV) junction is proposed.

Investigating The Use Of Kalman Filtering Approaches For Dynamic Origin-Destination Trip Table Estimation, Pushkin Kachroo, Kaan Ozbay, Arvind Narayanan

Electrical & Computer Engineering Faculty Research

This paper studies the applicability of Kalman filtering approaches for network wide traveler origin-destination estimation from link traffic volumes. The paper evaluates the modeling assumptions of the Kalman filters and examines the implications of such assumptions.

Feedback Control Solutions To Network Level User-Equilibrium Real-Time Dynamic Traffic Assignment Problems, Pushkin Kachroo, Kaan Ozbay

Electrical & Computer Engineering Faculty Research

A new method for performing dynamic traffic assignment (DTA) is presented which is applicable in real time, since the solution is based on feedback control. This method employs the design of nonlinear H∞ feedback control systems which is robust to certain class of uncertainties in the system. The solution aims at achieving user equilibrium on alternate routes in a network setting.

Least-Squares Approximate Solution Of Overdetermined Sylvester Equations, A. Scottedward Hodel, Pradeep Misra

Electrical Engineering Faculty Publications

We address the problem of computing a low-rank estimate Y of the solution X of the Lyapunov equation AX + XA' + Q = O without computing the matrix X itself. This problem has applications in both the reduced-order modeling and the control of large dimensional systems as well as in a hybrid algorithm for the rapid numerical solution of the Lyapunov equation via the alternating direction implicit method. While no known methods for low-rank approximate solution provide the two-norm optimal rank k estimate Xk of the exact solution X of the Lyapunov equation, our iterative algorithms provide an effective …

Rate-Equation Approximations In High-Gain Lasers, Lee W. Casperson

Electrical and Computer Engineering Faculty Publications and Presentations

The rate-equation approximation is one of the most fundamental and universally employed simplifications in laser analyses. The accuracy and regions of applicability of this approximation are explored in comparisons with more rigorous semiclassical models. Higher-order rate-equation approximations are also developed, and these improved models can yield much better accuracy than conventional rate equations with little added complexity. The modified adiabatic elimination methods reported here would also be useful in reducing the mathematical models governing other physical systems.

Predicting Timing Behavior In Architectural Design Exploration Of Real-Time Embedded Systems, Rajeshkumar Sambandam

Masters Theses

This thesis aims at developing efficient analytical techniques to perform trade-off studies in the architectural design exploration phase of real-time embedded systems. Real-time embedded systems (RTES) have stringent timing requirements. In the process of designing such a system, a key issue is to determine if a system is able to meet all the timing requirements imposed on it, though it may prove attractive in terms of cost and performance. Traditional methods of using event-driven simulation for modern RTES are very time consuming and are not guaranteed to prove feasibility. Specifically, we identify a flexibility metric to compare various options in …

An Adaptive Scheme For Admission Control In Atm Networks, Saragur M. Srinidhi, William H. Thesling, Vijaya K. Konangi

Electrical and Computer Engineering Faculty Publications

This paper presents a real time front-end admission control scheme for ATM networks. A call management scheme which uses the burstiness associated with traffic sources in a heterogeneous ATM environment to effect dynamic assignment of bandwidth is presented. In the proposed scheme, call acceptance is based on an on-line evaluation of the upper bound on cell loss probability which is derived from the estimated distribution of the number of calls arriving. Using this scheme, the negotiated quality of service will be assured when there is no estimation error. The control mechanism is effective when the number of …

Generalized Beam Matrices. Iv. Optical System Design, Anthony A. Tovar, Lee W. Casperson

Electrical and Computer Engineering Faculty Publications and Presentations

Systematic procedures are presented for determining the optical components needed to produce an arbitrary transformation of a Gaussian light beams's spot size, radius of curvature, displacement, and direction of propagation. As an example, an optical system is considered that spatially separates the two coincident Gaussian beams produced by a high-diffraction-loss resonator that uses a Gaussian variable-reflectivity output coupler. In addition, an ABCDGH reverse matrix theorem and an ABCDGH Sylvester theorem are also derived. These matrix theorems may be used to satisfy special constraints inherent in the design of multipass and periodic optical systems.

Broadband Dynamic Modification Using Feedforward Control, Kendeas Antonis Karantonis

Mechanical & Aerospace Engineering Theses & Dissertations

The use of feedforward control for dynamic modification is relatively new to the area of structural vibration control. In this thesis the disturbance path dynamics of a flexible aluminum beam, pinned at both ends and under the influence of broadband excitation inputs, are modified through the use of feedforward control. The ideal algebraically determined feedforward control method for response cancellation is first presented. Theoretically, this compensator modifies the disturbance path dynamics to any desired behavior. This ideal algebraic approach can only be used for minimum phase systems. In non-minimum phase systems, right half s-plane plant zeros emerge as unstable poles …

High Resolution Wavelength Modulation Spectroscopy For Precise Gaseous Characterization, Audra Michiele Bullock

Electrical & Computer Engineering Theses & Dissertations

Wavelength modulation spectroscopy is a highly sensitive, non-intrusive technique for probing gaseous species. Parameters such as velocity, density, and temperature can be measured and monitored with a high degree of precision. In addition, with the use of this technique multiple molecular species may be identified with a single laser probe. This measurement technique utilizes the well-known principles of modulation absorption spectroscopy in a novel way.

The research focuses on harmonic detection and the advantages gained by performing detection at higher harmonics, those greater than the commonly used second harmonic. We show that there is an increase in the sensitivity to …

Electromagnetic Scattering From A Cavity In A Ground Plane: Theory And Experiment, William D. Wood Jr.

Theses and Dissertations

The electromagnetic scattering from an arbitrarily shaped open cavity embedded in a perfectly conducting, infinite ground plane is examined. The cavity is filled with a linear, isotropic, homogeneous material. The fields in the cavity interior and above the ground plane are expressed in terms of the tangential fields on the cavity surface and aperture. A coupled set of three integral equations is developed governing the tangential fields on the aperture and cavity surface. The support of the unknown tangential fields is finite. A moment-method based algorithm to approximate the solution to the integral equations for axisymmetric geometries is developed. The …

Performance Of Mhpm In Rician And Rayleigh Fading Mobile Channels, Fuqin Xiong, S Bgatnyket

Electrical and Computer Engineering Faculty Publications

This paper evaluates the error probability of the rectangular frequency pulse multi-h modulation (MHPM) scheme in slowly-fading, frequency-nonselective or frequency-selective Rician and Rayleigh channels. The evaluation is performed with a method combining analysis and computer simulation. Performance degradations are evaluated for various direct-to-reflected signal ratio, Doppler shifts, and relative time delays in Rician fading channels. Compared with minimum shift keying (MSK), MHPM schemes appear to have retained their coding gains

Advances In Time-Domain Electromagnetic Simulation Capabilities Through The Use Of Overset Grids And Massively Parallel Computing, Douglas C. Blake

Theses and Dissertations

A new methodology is presented for conducting numerical simulations of electromagnetic scattering and wave propagation phenomena. Technologies from several scientific disciplines, including computational fluid dynamics, computational electromagnetics, and parallel computing, are uniquely combined to form a simulation capability that is both versatile and practical. In the process of creating this capability, work is accomplished to conduct the first study designed to quantify the effects of domain decomposition on the performance of a class of explicit hyperbolic partial differential equations solvers; to develop a new method of partitioning computational domains comprised of overset grids; and to provide the first detailed assessment …

Electrochemical Studies Of Spinel Limn2O4 Rechargeable Lithium Battery, Li Feng, Yuqin Chang, Lie Wu, Hong Li, Yibin San, Tianhong Lu

Journal of Electrochemistry

The spinel Li intercalation compound LiMn₂O₄ was prepared and studied using ac impedance and cyclic voltammogram techniques. It was first discussed that the impedance behaviors of LiMn₂O₄ electrode varied as lithium ion was intercalated in or out the electrode with the help of fractal theory. The Li reversible behaviors in LiMn₂O₄ electrode were shown by the cyclic voltammogram results.

Studies On An Iron Heteropolyacid Redox Flow Battery, Peiju Sun, Wansheng You, Zhorgyin Tan

Journal of Electrochemistry

This paper reports a new Fe-HP redox flow cell. The positive and negative electrodes active materials are phosphomolybdic acid and acidified ferrous sulphate solutions respectively. Two activated porous carbon felt electrodes where the electrochemical reactions take place, are separated by a selective cation exchange membrane. The both couples have a suitable electrochemical reversibility on carbon and graphite electrodes. The active materials of the cell have very high stability. Moreover the cell has no life cycle limiting.

Electrochemical Synthesis And Characterization Of Ba-Pb-O And Bi-Pb-O Oxides, Min Xie, Liangzhong Zhao, Cuiying Xu, Jinbiao Zhang

Journal of Electrochemistry

Pb-based oxides Ba-Pb-O and Bi-Pb-O were synthesized from aqueous solutions by using electrochemical method. The resulting Ba-Pb-O and Bi-Pb-O were characterized using XPS, EDX and XRD. The results show that perovskite BaPb_0.9O₃ can be electrodeposited on the anode only from strong alkaline solution. In acid aqueous solution, conducting BiPb₂O_z oxide is fromed on the anode. In these oxides the nominal valence of lead is +4.

Problems Of The Study Of Anodic Films On Pb In Sulfuric Acid Solution (Ⅲ), Houtian Liu, Qunzhou Wang, Weifang Zhou, Wenbin Cai

Journal of Electrochemistry

The interstitial liquid among the particles in anodic Pb(Ⅱ) films could be the major passage for ion transportation. This is discussed with the mechanism of the cathodic reduction of anodic PbSO₄ film and the effect of Sb on the growth of anodic Pb(Ⅱ) oxides film.

Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅱ. The Carbon Material With Core Shell Structure And Its Positive Effect On Cell Performance Of Graphite Anode, Shuhua Ma, Hanju Guo, Ji Li, Hongze Liang, Xiabin Jing, Fosong Wang

Journal of Electrochemistry

The carbon powders and film electrode with core shell structure were prepared by carbonization in gas state with using refined coal as shell material and Artificial Graphite and Mesocarbon Microbeads (2 800 ℃) graphite as core material. Galvanostatic charge/discharge measurement showed that both steady charge/discharge capacity and first charge/discharge efficiency were improved. Cyclic voltammetry indicated that the peak at about 0.7 V vs. Li⁺/Li characteristic of decomposition of electrolyte got weakened, and a more compact film was formed. X-ray diffraction measurement suggested the existence of amorphous carbon shell on the carbon powders and carbon film.

Minimizing Channel Density With Movable Terminals, Ronald I. Greenberg, Jau-Der Shih

Computer Science: Faculty Publications and Other Works

We give algorithms to minimize density for VLSI channel routing problems with terminals that are movable subject to certain constraints. The main cases considered are channels with linear order constraints, channels with linear order constraints and separation constraints, channels with movable modules containing fixed terminals, and channels with movable modules and terminals. In each case, we improve previous results for running time and space by a factor of L/\lgn and L, respectively, where L is the channel length, and n is the number of terminals.

Teaching Electromagnetic Field Theory Using Differential Forms, Karl F. Warnick, Richard H. Selfridge, David V. Arnold

Faculty Publications

The calculus of differential forms has significant advantages over traditional methods as a tool for teaching electromagnetic (EM) field theory. First, films clarify the relationship between field intensity and flux density, by providing distinct mathematical and graphical representations for the two types of fields. Second, Ampere's and Faraday's laws obtain graphical representations that are as intuitive as the representation of Gauss's law. Third, the vector Stokes theorem and the divergence theorem become special cases of a single relationship that is easier for the student to remember, apply, and visualize than their vector formulations. Fourth, computational simplifications result from the use …

Adaptive Distributed Detection With Applications To Cellular Cdma, Jian-Guo Chen

Dissertations

Chair and Varshney have derived an optimal rule for fusing decisions based on the Bayesian criterion. To implement the rule, probabilities of detection P_D and false alarm P_F for each detector must be known, which is not readily available in practice. This dissertation presents an adaptive fusion model which estimates the P_D and P_F adaptively by a simple counting process. Since reference signals are not given, the decision of a local detector is arbitrated by the fused decision of all the other local detectors. Adaptive algorithms for both equal probable and unequal probable sources, for independent …

Bilinear Time-Frequency Representations Of Heart Rate Variability And Respiration During Stress, Rindala Saliba

Dissertations

Recently, joint time-frequency signal representation has received considerable attention as a powerful tool for analyzing a variety of signals and systems. In particular, if the frequency content is time varying as in signals of biological origin which often do not comply with the stationarity assumptions, then this approach is quite attractive. In this dissertation, we explore the possibility of better representation of two particular biological signals, namely heart rate variability (HRV) and respiration. We propose the use of time-frequency analysis as a new and innovative approach to examine the physical and mental exertion attributed to exercise. Two studies are used …

Two Dimensional Agonistic Control, Daqing Yang

Dissertations

The conventional method of precise multiple-axis motion control entails use of a multiple axis positioning system with each axis carrying not only the workpiece but also the positioning system of the remaining axes. The resultant structure is heavy, sluggish, and expensive. An alternative positioning technique is being investigated in which the motion of the workpiece is controlled by pulling it with tendons, each of which has its own actuator. Since the actuators can be mounted on the base of the structure instead of being carried by motion system of the other axes, they can be relatively large and powerful without …

Counterpulsation Cardiac Assist Device Controller Defection Filter Simulation And Canine Experiments, Carl Edward Werner

Dissertations

Electronic control systems for counterpulsation Cardiac Assist Devices (CADs) are an essential part of cardiac assistance. Synchronization of the counterpulsation CAD controller with the cardiac cycle is critical to the efficacy of the CAD. The robustness of counterpulsation CAD controllers varies with the ability of the CAD controller to properly trigger on aortic pressure (Pa) and electrocardiogram (ECG) signals for sinusoid rhythms, non-sinusoid rhythms and non-ideal signals resulting from surgical intervention. An analog-to-digital converter and digital-to-analog converter based CAD controller development platform was devised on a 33Mhz PC-AT.

Counterpulsation Pa systolic rise and dicrotic notch detectors were demonstrated with a …

A Cost Model For Multi-Lifecycle Engineering Design, Bin Zhang

Theses

Design for Environment aims to yield a product whose aggregate environmental impact is as small as possible. This thesis characterizes a product recovery system and defines the concepts of product lifetime and part lifetime. A multi-lifecycle product recovery model is developed based on the concepts of product tree and disassembly path representation, four product recovery choices, time varying costs, cost comparison. The four product recovery choices of a part in the product tree are: Reconditioning, Part Remanufacturing, Material Recycling, and Landfill. This thesis focuses on how to improve the product design while minimizing environmental impact of the product and introduces …

Tcp/Ip Traffic Over Atm Network With Abr Flow And Congestion Control, Liping An

Theses

Most traffics over the existing ATM network are generated by applications running over TCP/IP protocol stack. In the near future, the success of ATM technology will depend largely on how well it supports the huge legacy of existing TCP/IP applications.

In this thesis, we study and compare the performance of TCP/IP traffic running on different rate based ABR flow control algorithms such as EFCI, ERICA and FMMRA by extensive simulations. Infinite source-end traffic behavior is chosen to represent, FTP application running on TCP/IP. Background VBR traffic with different ON-OFF frequency is introduced to produce transient network states as well as …