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A New Method For The Preparation Of The Electrodes With Very Low Platinum Loading Used In Proton Exchange Membrane Fuel Cell, Zhi-Gang Shao, Bao-Lian Yi, Ming Han, Ya-Guang Qiao, Hao Liu, Jing-Rong Yu

Journal of Electrochemistry

Research and development on low platinum loading electrode is very important in reducing the cost of proton exchange membrane fuel cell(PEMFC) stack. This paper has put forward a new method to prepare the electrode of PEMFC. The pore forming substances were used in this methd. The low platinum loading electrodes (0.02 mg_Pt⋅cm^-2) have already been prepared with the method. Compared with the traditional method, the new method is simple, cheep, and easy to scale up. The superior composition of the electrodes is catalyst: pore forming substance: Nafion= 3:3:1. The performance of a single cell using this …

A Study On The Cylindrical Zinc-Air Battery, Sheng-Sian Li, Gui-Mao Zhou, Xin-Ping Ai, Han-Xi Yang

Journal of Electrochemistry

The zinc air battery has advantages of high specific energies and low cost, therefore attracts much interests. However, its application is limited only in prismatic and button type.This paper reported a novel design of cylindrical zinc air batteries and the performances of the batteries tested at various conditions. The results showed that when discharged at the current of 40 mA at 20 °C, the capacity of AA size and AAA size batteries reached 4000mAh and 1400mAh respectively, corresponding to the energy densities 280 Wh/kg and 200 Wh/kg. The effects of the discharge current, temperature and humidity on the performances of …

Process Modeling, Monitoring And Control Of Laser Metal Forming, N. Munjuluri, Sanjeev Agarwal, Frank W. Liou

Electrical and Computer Engineering Faculty Research & Creative Works

Laser Metal Forming (LMF) process is one of the prominent Rapid Prototyping (RP) process that can be used to develop functional and fully dense metal parts. This paper addresses process modeling, monitoring and control of a laser metal forming system currently under development at Laser Aided Manufacturing Processes (LAMP) laboratory at University of Missouri--Rolla. This LMF system is based on a 2.5kW Nd:YAG laser as energy source and integrates five axis metal deposition and five axis machining. The current paper is aimed at characterization of effects of operating parameters such as traverse speed, mass flow-rate and laser power on the …

Experimental And Fdtd Study Of The Emi Performance Of An Open-Pin-Field Connector For Modules-On-Backplanes, Xiaoning Ye, Jim Nadolny, James L. Drewniak, Richard E. Dubroff, Thomas Van Doren, Todd H. Hubing

Electrical and Computer Engineering Faculty Research & Creative Works

Experimental measurements and numerical modeling were used to study the EMI performance of a module-on-backplane connector for various configurations of signal-return pin-outs. A commercially available open-pin-field connector was used in these results to connect between the mother-board and the daughter-card. The experimental techniques, based on measuring |S₂₁|, included both common-mode current measurements and monopole near-field probe measurements. The FDTD method was used to provide numerical support of the near-field measurements and generally agreed with the measured results for frequencies up to 3 GHz. The FDTD method was also used to investigate the relationship between the radiated EMI at …

Distributed Arithmetic Implementation Of Multivariable Controllers For Smart Structural Systems, Lingfeng Yuan, Sridhar Sana, Hardy J. Pottinger, Vittal S. Rao

Electrical and Computer Engineering Faculty Research & Creative Works

Smart structural systems require the electronic control systems which are integrated into the structures to be small, lightweight and power-efficient. The field programmable gate array (FPGA) is a good platform to implement such controllers. In our previous work, FPGA-based digital controllers were built and tested on a simple structural system. In order to implement multivariable controllers, the hardware resources for FPGA-based architecture need to be further reduced. Distributed arithmetic (DA) has long been proven to be a very efficient means to mechanize computations that are dominated by inner products involving constant multiplicand. The computational requirements of the smart structural controllers …

Real-Time Performance Analysis Of Wireless Multimedia Networks Based On Partially Observed Multivariate Point Processes, William S. Hortos

Electrical Engineering and Computer Science Faculty Publications

Third-generation (3G) wireless networks will support integrated multimedia services based on a cellular extension of a packet-switched architecture using variants of the Internet protocol (IP). Services can be categorized as real-time and delaysensitive, or non-real-time and delay-insensitive. Each call, arriving to or active within the network, carries demand for one or more services in parallel; each service type with a guaranteed quality of service (QoS). Admission of new calls to the wireless IP network (WIN) from the gateway of a wired network or from a mobile subscriber (MS) is allowed by call admission control (CAC) procedures. Roaming of the MSs …

Diversity Performance Of Dual-Antenna Handsets Near Operator Tissue, Michael A. Jensen, Bruce M. Green

Faculty Publications

This paper presents a computational and experimental study of the diversity performance of two dual-antenna handsets operating indoors in the 902-928 MHz industrial, scientific, and medical (ISM) band. Of particular interest is the effect of the operator tissue on the diversity operation. Key indicators of diversity gain such as branch mean effective gain (MEG) and envelope correlation coefficient are obtained from finite-difference time-domain (FDTD) method simulations as well as from experimental measurements in three different indoor environments. Diversity gain for the handsets is also measured directly. Reasonable agreement is observed between the experimental and simulated results, with both approaches indicating …

Thermal Lattice Boltzmann Simulation For Multispecies Fluid Equilibration, Linda L. Vahala, Darren Wah, George Vahala, Jonathan Carter, Pavol Pavlo

Electrical & Computer Engineering Faculty Publications

The equilibration rate for multispecies fluids is examined using thermal lattice Boltzmann simulations. Two-dimensional free-decay simulations are performed for effects of velocity shear layer turbulence on sharp temperature profiles. In particular, parameters are so chosen that the lighter species is turbulent while the heavier species is laminar-and so its vorticity layers would simply decay and diffuse in time. With species coupling, however, there is velocity equilibration followed by the final relaxation to one large co- and one large counter-rotating vortex. The temperature equilibration proceeds on a slower time scale and is in good agreement with the theoretical order of magnitude …

Advanced Atmospheric Water Vapor Dial Detection System, Tamer Refaat

Electrical & Computer Engineering Theses & Dissertations

Measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The remote sensing Differential Absorption Lidar (DIAL) technique is a powerful method to perform such measurement from aircraft and space. This thesis describes a new advanced detection system, which incorporates major improvements regarding sensitivity and size. These improvements include a low noise advanced avalanche photodiode detector, a custom analog circuit, a 14-bit digitizer, a microcontroller for on board averaging and finally a fast computer interface.

This thesis describes the design and validation of this new water vapor DIAL detection system which was integrated onto …

Routing Optimization Through Computer-Aided Simulation, Madhusudhan Akundi

Electrical & Computer Engineering Theses & Dissertations

Routing has always been a challenging field, and the various techniques of mathematics and operations research have been developed. For commercial organizations, routing has begun to receive extensive attention because of the savings gained in terms of time, money, personnel, and the transportation fleet by developing optimized routing networks. Until recently, it was difficult to develop optimized networks due to the computational difficulties of the problem. However, with the advancement in computer technology and processing speeds, it has become possible to simulate a large number of routing scenarios and determine optimal solutions for a given set of constraints. Not only …

The Fundamental Use And Extension Of Mode Stirred Chambers, Stephen A. Scearce

Electrical & Computer Engineering Theses & Dissertations

Mode stirred chambers are used to perform radiated susceptibility tests on equipment that is expected to operate normally when exposed to electromagnetic (EM) fields. These tests are useful in identifying failure events in airborne equipment and other electronic equipment that are exposed to EM fields. This thesis is focused on further defining the operating environment of mode stirred chambers and relating the electromagnetic environment in the chamber to the electromagnetic environment of an actual aircraft. The majority of mode stirred chamber tests are implemented by using mechanical mode stirring. Mechanical mode stirring is the process of varying boundary conditions in …

Role Of Laboratory Education In Power Engineering: Is The Virtual Laboratory Feasible? Part I, S. Iwamoto, G. G. Karady, Kraig J. Olejniczak, H. A. Mantooth, Mariesa Crow, Gerald T. Heydt

Electrical and Computer Engineering Faculty Research & Creative Works

IEEE PES sponsors a panel session in the summer power meeting in Seattle on laboratory education in power engineering. Six short papers and one full paper summarize the opinions of the panelist. This paper contains the summary of four of the presentations. The objective of the panel is to discuss the role of laboratory education in power engineering at both the graduate and undergraduate level. The question is what type of laboratory course is needed? Power electronics, electric machines, system simulation, etc? the second objective is to assess the status and value of computer based virtual laboratories. This includes the …

An Improved Statcom Model For Power Flow Analysis, Zhiping Yang, Chen Shen, Lingli Zhang, Mariesa Crow

Electrical and Computer Engineering Faculty Research & Creative Works

The StatCom is traditionally modeled for power flow analysis as a PV or PQ bus depending on its primary application. The active power is either set to zero (neglecting the StatCom losses) or calculated iteratively. The StatCom voltage and reactive power compensation are usually related through the magnetics of the StatCom. This traditional power flow model of the StatCom neglects the impact of the high-frequency effects and the switching characteristics of the power electronics on the active power losses and the reactive power injection (absorption). In this paper, the authors propose a new StatCom model appropriate for power flow analysis …

Resolution Of Overlapping Spectra By Wavelength Modulation Spectroscopy, Audra Michiele Bullock

Electrical & Computer Engineering Theses & Dissertations

Wavelength modulation absorption spectroscopy is a highly sensitive, non-intrusive technique for probing gaseous species, which employs the well-known principles of modulation spectroscopy in a novel way. With this technique, parameters such as velocity, density, and temperature can be measured with a high degree of precision. The research presented here shows that wavelength modulation is a convenient means of increasing the sensitivity of an absorption spectroscopy measurement because it allows for harmonic detection. The focus of the dissertation is resolution of overlapping spectra by harmonic detection and the advantages gained by performing detection at the higher harmonics, e.g., sixth and eighth. …

Signal Modeling With Non-Uniform Time Sampling Of Features For Automatic Speech Recognition, Montri Karnjanadecha

Electrical & Computer Engineering Theses & Dissertations

This dissertation presents an investigation of non-uniform time sampling methods for spectral/temporal feature extraction in speech. Frame-based features were computed based on an encoding of the global spectral shape using a Discrete Cosine Transform. In most current “standard” methods, trajectory (dynamic) features are determined from frame-based parameters using a fixed time sampling, i.e., fixed block length and fixed block spacing. In this research, new methods are proposed and investigated in which block length and/or block spacing are variable. The idea was initially tested with HMM-based isolated word recognition, and a significant performance improvement resulted when a variable block length and …

Simulation Studies Of Cellular Electroporation Due To Ultra-Fast Electric Pulses, Gayathri R. Barthaki

Electrical & Computer Engineering Theses & Dissertations

Biological systems, from cells to ecosystems, are intrinsically complex information-processing networks. It often becomes difficult to predict their behavior during an experimental investigation, as their behavior is fundamentally chaotic, Hence, building models that mimic the dynamics of such systems and performing computer simulations would help in understanding, predicting, controlling and optimizing these systems. This thesis is aimed at the development of a mathematical model for the process of electroporation in biological cells when they are subjected to ultra-fast electric pulses and at conducting simulations to understand its dynamic behavior with special emphasis on the physics of ultra-short time scales.

With …

Bit Allocation Considering Mean Absolute Error For Image Compression, Hemen Goswami, Samuel Peter Kozaitis

Electrical Engineering and Computer Science Faculty Publications

In lossy image compression schemes, often some distortion measure is minimized to arrive at a desired target bit rate. The distortion measure that has been most studied is the mean-squared-error (MSE). However, perceptual quality often does not agree with the notion of minimization of mean square error1 . Since MSE can not guarantee the optimality of perceptual quality, others error measures have been investigated. Others have found strong mathematical and practical perspective to choose a different error measure other than MSE, especially for image compression2. In Ref. 2 it is argued that the mean absolute error (MAE) measure is a …

Wavelet-Based Image Compression Using Randomized Quantization, Samuel Peter Kozaitis, Hemen Goswami

Electrical Engineering and Computer Science Faculty Publications

We applied dithered quantization to image compression using a wavelet transform, scalar quantization method. The results indicate that dithered quantization could change the noise characteristics ofthe reconstructed image.

Rate-Distortion Adaptive Vector Quantization For Wavelet Imagecoding, Qun Gu, Scott E. Budge

Electrical and Computer Engineering Faculty Publications

We propose a wavelet image coding scheme using rate-distortion adaptive tree-structured residual vector quantization. Wavelet transform coefficient coding is based on the pyramid hierarchy (zero-tree), but rather than determining the zero-tree relation from the coarsest subband to the finest by hard thresholding, the prediction in our scheme is achieved by rate-distortion optimization with adaptive vector quantization on the wavelet coefficients from the finest subband to the coarsest. The proposed method involves only integer operations and can be implemented with very low computational complexity. The preliminary experiments have shown some encouraging results: a PSNR of 30.93 dB is obtained at 0.174 …

Planar Approximation For The Least Reliable Bit Log-Likelihood Ratio Of 8-Psk Modulation, William H. Thesling, Fuqin Xiong, M. J. Vanderaar

Electrical and Computer Engineering Faculty Publications

The optimum decoding of component codes in block coded modulation (BCM) schemes requires the use of the log-likelihood ratio (LLR) as the signal metric. An approximation to the LLR for the least reliable bit (LRB) in an 8-PSK modulation based on planar equations with fixed-point arithmetic is developed that is both accurate and easily realisable for practical BCM schemes. Through an error power analysis and an example simulation it is shown that the approximation results in less than 0.06 dB in degradation over the exact expression at an E_s/N₀ of 10 dB. It is also shown that …

Gaussian Beams In Hollow Metal Waveguides, Lee W. Casperson

Electrical and Computer Engineering Faculty Publications and Presentations

Various families of Gaussian beams have been explored previously to represent the propagation of nearly plane electromagnetic waves in media having at most quadratic transverse variations of the index of refraction and the gain or loss in the vicinity of the beam. However, such beams cannot directly represent the wave solutions for propagation in planar or rectangular waveguides, and sinusoidal mode functions are more commonly used for such waveguides. On the other hand, it is also useful to consider the possibility of recurring Gaussian beams that have an approximately Gaussian transverse profile at certain distinct planes along the propagation path. …

Bounded Beam Wave Pulse Propagation And Scattering In Random Media Based On The Radiative Transfer Theory Using 2-D Gauss Quadrature Formula, Sheng-Kai Hu

Theses

The scalar time-dependent equation of radiative transfer is used to develop a theory of bounded beam wave narrow band pulse propagation and scattering in a medium characterized by many random discrete scatters, which scatters energy strongly in the forward scattering direction. Applications include the scattering of highly collimated millimeter waves in vegetation and optical beams in the atmosphere. The specific problem analyzed is that of a periodic sequence of Gaussian shaped pulses normally incident from free space onto the planar boundary surface of a random medium half-space, such as a forest, that possesses a scatter (phase) function consisting of a …

V-I Converters With Transconductance Proportional To Bias Current In Any Technology, Vladimir I. Prodanov

Electrical Engineering

In this paper we discuss circuits comprised of multiple differential pairs driven in parallel. We show that high linearity and linear with bias current tunability are intrinsic properties of any equidistant-offset multi-pair circuit. We argue that these two properties could potentially allow us to implement designs of analog filters, multipliers and other circuits that are (in first-order) technology independent. Simulations results are provided in support of presented simple intuitive explanation.

Study On The Effect Of Sodium Ion On Cycle Performance Of Lithium/Improved Graphite Lithium Ion Cell, Wen-Huang Huang, Yu-Shun Yan, Chun-Rong Wan, Chang-Yin Jiang

Journal of Electrochemistry

The different concentration of Na⁺ was introduced into the non-aqueous eletrolyte system EC/DEC/LiClO 4 with 4A molecular sieve and lithiated 4A molecular sieve, by which the trace amount of water was removed. The concentrations of Na⁺ and Li⁺ were determined by atomic adsorption spectrometry. The cycle performance of lithium/improved graphite cells was then examined by charging and discharging under the constant electric current. The results demonstrated that the cycle performance of the cells was destroyed by the high concentration of Na⁺ under the small electric current. With the increase of electric current the cell became less …

The Studies On Nanosized Materials For Lithium Ion Batteries, Hong Li, Jing-Ze Li, Li-Hong Shi, Guang-Yan Zhu, Qing Chen, Wei Lu, Xue-Jie Huang, Li-Quan Chen

Journal of Electrochemistry

Our recent works about nanosized materials for lithium ion batteries are reported, including the synthesis of nanosized Sb, SnSb, CuSn_x, Si and CuS, their electrochemical performance as anode or cathode active materials, the variation of crystal structure and morphology during discharge and charge cycling. In addition, the self-plasticization of lithium salt with nanosized anion ion in polymer electrolyte, the influence of the electrochemical Li-doping on the Raman spectra and photoluminescence of nano-Si are also introduced. Furthermore, the relationship between intrinsic properties of nanosized materials and their electrochemical behaviors are discussed. The prospect of nanosized materials for lithium ion …

Powder Microelectrode Modified With Nafion-Os(Bpy)3Â 2+ And Pvp Composite And Its Catalysis For No2- Reduction, Pei-Fang Liu, Jia-Wei Yan

Journal of Electrochemistry

The modified powder microelectrode was prepared by etching a Pt (0.1 mm diameter) disk microelectrode and filling in thus formed cavity with Nation-Os(bpy)₃²⁺/PVP composite modified carbon powder. The composite modified powder microelectrode showed cyclic voltammetric behaviors changing with the mole ratio (denoted X) of SO₃^- to Os(bpy)₃²⁺ in Nafion. When X=3, a single pair of current peaks appeared near 0.6V (vs. SCE) due to Os(bpy)₃^2+/3+ redox couple. In contrast, for X=20, a pair of additional current peaks occurred near 0.4V. Both X=3 and X=20 modified powder microelectrodes strongly catalyzed the first …

Technical Investigaton Of Thin-Film Plasticizing Lithium Ion Battery, Xin-Ping Ai, Xin-Lin Hong, Quan-Feng Dong, Sheng-Xian Li, Han-Xi Yang

Journal of Electrochemistry

A number of polymer materials as candidates of host matrix of plastic polymer electrolyte were examined and techniques for preparation of thin-film electrolyte were reported. The results showed that the polymer electrolyte prepared with P(VDF-HFP) copolymer as host matrix and DBP as plasticizer exhibit the satisfactory mechanical strength and ionic conductivity. In comprison with liquid electrolyte systems, thin-film lithium ion battery has almost similar charge-discharge capacity and cycleability. The manufacture methods and the technical factors in making plasticizing lithium ion battery were also described in details.

Study On Carbon From Pyrolyzing Phenol-Formaldehyde Resin For The Negative Electrode Of Li-Ion Secondary Battery, Zhi-Yuan Tang, Xin-Guo Zhuang, Yu-Mei Zhai, Jian-Gang Li, Jian-Jun Xue, Chun-Yan Liu

Journal of Electrochemistry

Li-ion secondary batteries negative electrodes were prepared by low temperature (<1 000 ℃) pyrolysis of commercial phenol-formaldhyde resin. A thermogravimetric analysis (TGA) and an X-ray diffraction (XRD) studies were peoformed for the pyrolytic carbonaceous materials. The results indicated that these samples are amorphous polyacenic structure materials. With increasing pyrolytic temperature, these materials become structurally order, and the first charge-discharge special capacities reduce. The specific capacities base on pyrolytic temperature, involving lithium storage nanometer cavities.

Template Synthesis And Uv-Vis Absorption Spectra Of The Nanowire Arrays Of Cadmium Chalcogenides, Shi-Min Xu, Kuan-Hong Xue, Jing-Lin Kong, Dong-Mei Sun, Yu-Ying Feng, Hai-Yan Lu, Guang-Hou Wang

Journal of Electrochemistry

The porous alumina membrane formed in the anodic oxidation of highly pure aluminum foil has attracted a great deal of attention in recent years. It can be served as a desired template to prepare nanometer scale materials due to its unique structure of discrete and cylindrical nanopores, paralleled one another, with the homogeneous size and distribution. Chalcogenide semiconductors have promising prospect in the applications of photovoltaic and photoconducting devices and have been extensively exploited for many years. Olbright and his co-workers studied experimentally and theoretically the optical nonlinearties of CdS_xSe_1-x-doped glass; Britt and Ferekides reported that …

Effects Of Temperature On The Proton Diffusion Of Doped Ni(Oh)2, Jian-Hua Liu, Jing-Wu Yang, Zhi-Yuan Tang

Journal of Electrochemistry

The Chronoamperometry of powder spherical Ni(OH)₂ microelectrode was used to study the proton diffusion coefficients of Ni(OH)₂. The proton diffusion coeefficients and the apparent diffusion active energy in anode and cathode processes at different temperature were obtained. Compared with pure Ni(OH)₂, the apparent diffusion active energy (E_a) of Ni(OH)₂ doped with Co and Co + Zn was decreased and the diffusion constant (D_o) was increased in the anode and the cathode processes, respectively, the effect of Co was greater. In contrast, for Ni(OH)₂ doped with Zn, its E_{a …}