Digital Commons Network^™

Atr-Ftir Spectroscopic Analysis Of Sorption Of Aqueous Analytes Into Polymer Coatings Used With Guided Sh-Saw Sensors, Yolanda K. Jones, Zhonghui Li, Michael M. Johnson, Fabien Josse, Jeanne Hossenlopp

Chemistry Faculty Research and Publications

Attenuated total internal reflectance Fourier transform infrared (ATR-FTIR) spectroscopy was used for the investigation of sorption of aqueous solutions of analytes into polymer coatings. A series of simple model polymers, such as poly(dimethylsiloxane), poly(epichlorhydrin), and poly(isobutylene), and films and analytes, such as aqueous solutions of ethylbenzene, xylenes, toluene, and nitrobenzene, were used to evaluate the use of ATR-FTIR spectroscopy as a screening tool for sensor development. The ratios of integrated infrared absorption bands provided a simple and efficient method for predicting trends in partition coefficients. Responses of polymer-coated guided shear horizontal surface acoustic wave (SH-SAW) sensor platforms to the series …

Characterization Of Binary Offset Carrier (Boc) Systems Coexisting With Other Wideband Signals, John M. Hedenberg

Theses and Dissertations

Results for modeling, simulation, and analysis of interference effects that modern interfering signals have on the system performance of the Binary Offset Carrier (BOC) signals, such as the Global Positioning System (GPS) Military System (M-Code signal) are addressed in this work. Three signals are addressed as potential interferers. These include the current GPS clear/acquisition code (C/A-Code) signal, the current GPS precision code (P-Code) signal, and an Orthogonal Frequency Division Multiplexed (OFDM) signal. All of these potential interferers are modeled as coexisting within the same bandwidth as the M-Code signal. Interference effects are characterized by comparing the bit error performance of …

Gaussian Mixture Reduction For Bayesian Target Tracking In Clutter, David J. Petrucci

Theses and Dissertations

The Bayesian solution for tracking a target in clutter results naturally in a target state Gaussian mixture probability density function (pdf) which is a sum of weighted Gaussian pdf's, or mixture components. As new tracking measurements are received, the number of mixture components increases without bound, and eventually a reduced-component approximation of the original Gaussian mixture pdf is necessary to evaluate the target state pdf efficiently while maintaining good tracking performance. Many approximation methods exist, but these methods are either ad hoc or use rather crude approximation techniques. Recent studies have shown that a measure-function-based mixture reduction algorithm (MRA) may …

Moving And Stationary Target Acquisition Radar Image Enhancement Through Polynomial Windows, Rajarajeswari Devarajulu

Theses and Dissertations - UTB/UTPA

The Fourier transform involved in synthetic aperture radar (SAR) imaging causes undesired sidelobes which obscure weak backscatters and affect the image clarity. These sidelobes can be suppressed without deteriorating the image resolution by smoothing functions known as windowing or apodization. Recently, the theory of orthogonal polynomials has gained considerable attention in signal processing applications. The window functions that are derived from the orthogonal polynomials have interesting sidelobe roll-off properties for better sidelobe apodization, hence it can be used for radar image enhancement. In this work, a new window is constructed from Jacobi orthogonal polynomials and its performance in SAR imaging …

Inertial Navigation System, Michael Calabrese Jr., David Engblom, Aaron Fleckenstein

Honors Theses

Accelerometer-based inertial navigation systems present an inexpensive alternative to gyroscope and global positioning navigation systems. An array of accelerometers comprises the basic design of the inertial navigation system. The position of the device can be continuously updated based on the previous device location and measurements of the device acceleration. There are fewer moving parts in an accelerometer-based system than in a gyroscopic device, and it is free of the earth bound constraints of a global positioning system. The prototype wirelessly interfaces with a data-collection system, which processes the data and provides a graphical display of the trajectory traveled.

Two accelerometer …

Solid Oxide Fuel Cells-Materials And Prospects, Molenda Janina, Marzec Jacek

Journal of Electrochemistry

The paper summarizes and discusses the basic properties of solid oxide fuel cell (SOFC) components (electrode materials and electrolyte) from the point of view of their essential functional parameters suck as chemicalstability, transport, catalytic and thermomechanical properties under operational conditions in a SOFC. An interrela-tion between the defect structure of these materials related to oxygen nonstoichiometry and their electronic propertiesand catalytic activity was shown. Single-chamber fuel cell concept was also presented.

The Optimal Sulfonation Conditions Of Self-Doped Polyaniline Obtained By Using Experimental Strategies, Wen-Yar Li, Chi-Chang Hu

Journal of Electrochemistry

The optimal sulfonation condition of self-doped sulfonated polyaniline (prepared from leucoemeraldinebase; denoted as LEB-SPANI) with a high electronic conductivity was obtained by experimental strategies, includingthe fractional factorial design (FFD) and central composite design (CCD). From the FFD experiment, the self-doped LEB-SPANI prepared at a lowtemperature (4℃), a short reaction time (1 h), and a small volume of fumingsulfuric acid (10 mL) showed a better conductivity (ca.127 mS/cm). In the CCD study coupled with a confirmationtest, the highest conductivity (ca.141 mS/cm) of the LEB-SPANI film was obtained under a sulfonation temperatureof 4℃, a sulfonation time of 75 minutes, and a volume …

The Deactivation Mechanism Of Metal Oxide Anodes Under Alternative Current Electrolysis Condition, Jun-Tao Wang, Yan Han, Guang-Zhang Chen, Wen-Fa Liu

Journal of Electrochemistry

The metal oxide anodes coated on titanium used in seawater electrolysis were prepared by thermal decomposition. Their morphologies, compositions and phase structures were determined by scanning electron microscope(SEM), energy dispersive X-ray detector(EDX) and X-ray diffraction(XRD). The electrochemical properties of the anodes were characterized by accelerated life test, cyclic voltammetry and electrochemical impedance spectroscopy. SEM, EDX and XRD showed that solid solution structures of (Ru, Ir, Ti)O₂ and (Ir, Ti)O₂ were formed after pyrolysis, the solid solution structures and active components were disappeared after the deactivation of the anodes. Electrochemical results indicated that the active area decreased and the …

Silicides And Composites Materials As Anodes For Lithium Ion Batteries, Jun-Mei Yan, Hui-Zhen Huang, Jing Zhang, Yong Yang

Journal of Electrochemistry

The anode materials of Mg₂Si and MnSi were synthesized by mechanically activated annealing(MAA) techniques in this work and the in electrochemical performances were also studied.A series of composite materials of Mg₂Si and CNTs or CMS were prepared by ball-milling method respectively. The reversible capacities of the composites were higher than that of the pure Mg₂Si and pure carbon materials.The cyclic performances have been improved greatly by ball-milling of the Mg₂Si and carbon materials. Results show that ball-milling method is one kind of method to make alloy materials into practical use.

A Continuous Operation For Electroreduction Of Oxalic Acid To Glyoxylic Acid, Xiao-Hui Hu, Xiang-Fei Yan, Yu-Zhong Su, Jun Li, Qing-Biao Li

Journal of Electrochemistry

A simulative-continuous-operation approach was proposed to study the continuous operation for electroreduction of oxalic acid to gloxylic acid using a packed bed reactor and a parallel reactor with cooled cathode in order to solve the low productivity problem in current state by using traditional reactor. The effects of the concentration of oxalic acid and temperature on this process were also studied. Results showed that,after 30min of the reaction(residence time), the mass fraction of the produced glyoxylic acid in the catholic solution could reach 3.76% and 3.66% with respect to a saturated oxalic acid method and a step-temperature decreasing method. From …

The Electrocatalystic Investigation Of 3,4-Dihydroxybenzoic Acid On The Modified Multiply Wall Carbon Nanotubes, Ming-Qi Li, Duo-Chang Cai, Xiao-Ying He

Journal of Electrochemistry

The electrochemical behavior of 3,4-Dihydroxybenzoic acid(DHBA) on modified multiply wall carbon nanotubes electrode was investigated by cyclic voltammetry(CV) and square wave voltammetry(SWV). Results show that in 0.1 mol/L HCl solutions the modified carbon nanotube electrode has an obvious electrocatalytic effect on the oxidation and deoxidization of DHBA. The oxidation current of DHBA is linear to it's concentration in the range of 4.0×10^-6～1.0×10^-4 mol/L and 2.0×10^-4～8.0×10^-4 1mol/L with correlation coefficient of 0.9995 and 0.9992. The detection limit is 1.0×10^-6 mol/L.

A Study Of Overcharge Characteristic Of Lithium-Ion Cells, Jing Pang, Shi-Gang Lu, Sha Liu

Journal of Electrochemistry

The overcharge characteristics and effect factors of lithium-ion cells containing LiMn₂O₄ cathodes were studied in detail. Overcharge testing of Lithium-ion cells with a systematic variation in the cell balance demonstrated that the overcharge characteristics of Lithium-ion cells was affected by the amount of cathode in the cells, which is independent of the amount of anode material. The rate of charge was found to be an important parameter, as electrolyte complete decomposition at low charge rates caused the end of overcharge testing, while high charge rates accelerated the rate of heat generation in the cells and the cell …

Electrochemical Oxidation Of Organic Additives In Tin Plating Electrolytes, Yin-Mei Cheng, Lan-Kun Cai, Qiang Song

Journal of Electrochemistry

Cyclic voltammetry(CV) was used to characterize the voltammetric behaviours of organic additives, e.g. PSA(phenolsulfonic acid) EN(ethoxylatedα-naphthol) and ENSA(ethoxylatedα-naphthol sulfonic acid), on the anode surface. In PSA solutions, an anodic peak was obtained and the peak potential was about 1.2V. In EN and ENSA solutions, two anodic peaks were obtained and the peak potentials were about(0.95V) and 1.3V. The products of galvanostatic electrolysis were separated by HPLC(high performance liquid chromatography) and analyzed by EI/MS(electron ionizing mass spectrometry). The mechnism of the electrochemical oxidation was also disussed.

A Provacative Test To Determine Brain Compliance In The Management Of Patients With Hydrocephalus, Preston K. Manwaring

Theses and Dissertations

Non-invasive techniques to explore intracranial compliance and pressure have been extensively explored in recent years. Previous techniques have used expensive technologies to make these measurements, often with difficulty. We present a novel, inexpensive provocative test to observe trends in intracranial compliance measurement targeted towards the treatment and management of hydrocephalus. Two techniques are proposed which derive data from the digital and supraorbital arteries as well as tympanic membrane displacement. This requires the use of two photo-plethysmographic sensors and a TMD sensor. A common tilt table apparatus is used to methodically and artificially increase intracranial pressure to stress the cranial system …

Array Analysis Of Radio Frequency Interference Cancelation Requirements For A Land Mine Detection System, Devin Baker Pratt

Theses and Dissertations

Land mines are a major humanitarian problem with millions of active mines in place around the world. Since these mines can have little metal in them, novel detection techniques are needed. Nuclear Quadrupole Resonance (NQR) is one such technique. Unfortunately, NQR is highly succeptible to radio frequency interference (RFI). A significant contribution of this thesis is the development of a custom, experimental data acquisition system designed and built specifically for capturing RFI at frequencies significant to NQR land mine detection systems. Another major contribution is the development of data analysis techniques for determining the number of reference antennas required to …

Using Ultrasonic Atomization To Produce An Aerosol Of Micron-Scale Particles, Thomas D. Donnelly, J. Hogan '03, A. Mugler '04, M. Schubmehl '02, N. Schommer '04, Andrew J. Bernoff, S. Dasnurkar, T. Ditmire

All HMC Faculty Publications and Research

A device that uses ultrasonic atomization of a liquid to produce an aerosol of micron-scale droplets is described. This device represents a new approach to producing targets relevant to laser-driven fusion studies, and to rare studies of nonlinear optics in which wavelength-scale targets are irradiated. The device has also made possible tests of fluid dynamics models in a novel phase space. The distribution of droplet sizes produced by the device and the threshold power required for droplet production are shown to follow scaling laws predicted by fluid dynamics.

Asynchronous Ds-Ss Cdma Random Spreading Code Correlation Statistics In The Presence Of Timing Error, David W. Matolak

Faculty Publications

We quantify the effect of timing tracking errors upon 2nd order correlation statistics of random binary spreading codes and, in so doing, fill a gap in the literature. Using a Gaussian model for timing tracking error, new expressions for autocorrelation statistics are derived. For crosscorrelations, we show that a zero mean Gaussian timing error has no effect upon 2nd order crosscorrelation statistics.

H-Infinity Estimation For Fuzzy Membership Function Optimization, Daniel J. Simon

Electrical and Computer Engineering Faculty Publications

Given a fuzzy logic system, how can we determine the membership functions that will result in the best performance? If we constrain the membership functions to a specific shape (e.g., triangles or trapezoids) then each membership function can be parameterized by a few variables and the membership optimization problem can be reduced to a parameter optimization problem. The parameter optimization problem can then be formulated as a nonlinear filtering problem. In this paper we solve the nonlinear filtering problem using H_∞ state estimation theory. However, the membership functions that result from this approach are not (in general) sum normal. …

Social Utility Functions-Part I: Theory, Wynn C. Stirling

Faculty Publications

The dominant approaches to utility-based multiagent decision theory rely on the premise of individual rationality-the doctrine that each individual is committed to achieving the best outcome for itself, regardless of the effect doing so has on others. This fundamentally asocial concept is the basis of conventional von Neumann-Morgenstern (vN-M) utilities but is inadequate to characterize truly cooperative artificial systems. Social utility functions differ from conventional vN-M utilities in that they are functions of multiple decision-maker preferences, rather than actions, and thus permit individuals to expand their spheres of interest beyond the self. A logical basis for coherent reasoning in multiagent …

Social Utility Functions-Part Ii: Applications, Wynn C. Stirling, Richard L. Frost

Faculty Publications

Social utilities account for agent preferences and, thus, can characterize complex interrelationships, such as cooperation, compromise, negotiation, and altruism, that can exist between agents. Satisficing game theory, which is based on social utilities, offers a framework within which to design sophisticated multiagent systems. Key features of this approach are: a) an N-agent system may be represented by a 2N-dimensional Bayesian network, called a praxeic network; b) the theory accommodates a notion of situational altruism (a willingness to defer to others in a controlled way if so doing would actually benefit others under the condition that others wish to take advantage …

Terahertz Studies Of The Dielectric Response And Second-Order Phonons In A Gase Crystal, B. L. Yu, F. Zeng, V. Kartazayev, R. R. Alfano, K. C. Mandal

Faculty Publications

No abstract provided.

Partition-Based Interpolation For Color Filter Array Demosaicking And Super-Resolution Reconstruction, Min Shao, Kenneth E. Barner, Russell C. Hardie

Electrical and Computer Engineering Faculty Publications

A class of partition-based interpolators that addresses a variety of image interpolation applications are proposed. The proposed interpolators first partition an image into a finite set of partitions that capture local image structures. Missing high resolution pixels are then obtained through linear operations on neighboring pixels that exploit the captured image structure. By exploiting the local image structure, the proposed algorithm produces excellent performance on both edge and uniform regions. The presented results demonstrate that partition-based interpolation yields results superior to traditional and advanced algorithms in the applications of color filter array (CFA) demosaicking and super-resolution reconstruction.

Complex Power Distribution Network Investigation Using Spice Based Extraction From First Principle Formulations, Giuseppe Selli, James L. Drewniak, Richard E. Dubroff, Jun Fan, James L. Knighten, Norman W. Smith, Dean Mccoy, Bruce Archambeault, Stefano Grivet-Talocia, Flavio G. Canavero

Electrical and Computer Engineering Faculty Research & Creative Works

The modeling and the analysis of the power distribution networks (PDN) within multi-layer printed circuit board is crucial for the investigation of the performance of PCB systems. Carrying out such analyses in SPICE based tools has the advantage of being faster than the corresponding full-wave modeling and it allows obtaining both frequency and time domain results.

Evaluation Of Microwave Reflection Properties Of Cyclically Soaked Mortar Based On A Semiempirical Electromagnetic Model, Shanup Peer, K. E. Kurtis, R. Zoughi

Electrical and Computer Engineering Faculty Research & Creative Works

Detection of chloride ingress and evaluation of its distribution and temporal movement in reinforced concrete structures is an important practical issue. Steel reinforcing bars embedded in good quality concrete are normally protected from corrosion. However, the presence of a sufficient concentration of free chloride ions in the region of the reinforcing steel can initiate the process of corrosion. Therefore, it is important to be able to detect ingress of chloride ions and their distribution in cement-based materials. Moreover, it is important to obtain this information nondestructively. In recent years, near-field microwave nondestructive evaluation methods, using open-ended rectangular waveguide probes, have …

Qca-Based Majority Gate Design Under Radius Of Effect-Induced Faults, Zachary D. Patitz, Nohpill Park, Minsu Choi, Fred J. Meyer

Electrical and Computer Engineering Faculty Research & Creative Works

This paper presents reliable QCA cell structures for designing single clock-controlled majority gates with a tolerance to radius of effect-induced faults, for use as a basic building component for carry look-ahead adder. Realizable quantum computing is still well in the future due to the complexity of the quantum mechanics that govern them. In this regard, QCA-based system design is a challenging task since each cell''s state must interact with all the cells that are in its energy-effective range in its clocking zone, referred to as its radius of effect. This paper proposes a design approach for majority gates to overcome …

Ozone Concentration In An Atmospheric Pressure Air Plasma Jet, Srinivas Reddy Suddala

Electrical & Computer Engineering Theses & Dissertations

A stable micro-plasma jet in air was generated from a direct current discharge between two molybdenum electrodes (0.25 mm thick) that were separated by an alumina insulator of the same thickness. The after-glow plasma jet was generated by blowing air through the space between the electrodes. A change from laminar to turbulent flow was observed at a gas flow rate of 140 ml/min. The length of the plasma jet increased with flow rate in the laminar mode to approximately 15 mm and decreased in the turbulent mode.

Increasing the gas flow rate up to 200 ml/min at a constant discharge …

A Dsp-Based Active Disturbance Rejection Control Design For A 1-Kw H-Bridge Dc-Dc Power Converter, Bosheng Sun, Zhiqiang Gao

Electrical and Computer Engineering Faculty Publications

This paper presents the design and implementation of an advanced digital controller for a 1-kW H-bridge dc-dc power converter. A new control algorithm based on the active disturbance rejection concept is developed to cope with the highly nonlinear dynamics of the converter and the disturbances. An experimental digital control system is used to implement the new control strategy. It consists of a digital control board based on the TMS320C6711 digital signal processor chip, an analogy I/O board, and a complex programmable logic device pulsewidth-modulation generation board. Using a newly developed bandwidth-parametrization technique, an autotuning method based on noise quantification is …

Fourier Transform Analysis Of Terahertz Radiation, Chikaodira N. Okpo

Electrical & Computer Engineering Theses & Dissertations

Advances in terahertz radiation (T-rays) technology have great promise in various technological areas ranging from medical technology, imaging technology and accelerator technology. At Thomas Jefferson Laboratory, the Free Electron Laser division (FEL) produces very powerful beam of laser light by accelerating electrons in bunches along a beamline. This laser light absorbs and releases energy at various wavelengths. The new FEL upgrade led to the production of very bright terahertz (THz) radiation with an average power of 1 00watts which is about 100,000 times brighter than those produced elsewhere. These T-rays have very significant applications in the Laboratory. The most significant …

Structured Object-Oriented Co-Analysis/Co-Design Of Hardware/Software For The Facts Powers System, Matt Ryan, Sojan Markose, Xiaoqing Frank Liu, Bruce M. Mcmillin

Computer Science Faculty Research & Creative Works

There are several approaches to the hardware/software design in embedded systems, ranging from the traditional sequential methods which focus on the determination of the hardware architecture prior to software design, to newer object-oriented approaches that attempt to apply software engineering methods to hardware design without a systematic process. This paper discusses a structured object-oriented methodology for the integrated co-analysis and co-design of hardware/software systems using an extended high order object-oriented modeling technique (HOOMT). This methodology offers a uniform method for hardware and software developers to jointly develop the specifications for and partitioning of the hardware and software components of a …

Applicationofspectroscopic Ellipsometry To In-Stu. Real-Time Fabrication Of Multiple Layer Alternating High/Low Refractive Index Filters, Blaine D. Johs, Jeffery S. Hale, John A. Woollam, Craig M. Herzinger

Department of Electrical and Computer Engineering: Faculty Publications

Disclosed is application of oblique angle of incidence, reflection and/or transmission mode spectroscopic ellipsometry PSI and/or DELTA, (including combinations thereof and/or mathematical equivalents), vs. wavelength data to monitor and/or control fabrication of multiple layer high/low refractive index band-pass, band-reject and varied attenuation vs. wavelength filters, either alone or in combination with transmissive non-ellipsometric electromagnetic beam turning point vs. layer data obtained at an essentially normal angle of incidence.