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The Distribution And Comparative Biogeochemistry Of Silver With Other Selected Trace Metals In Coastal Waters Near Massachusetts, Usa, Christian F. Krahforst

Graduate Doctoral Dissertations

Water samples and hydrologic data were collected during 1994-1996 in New England coastal waters near Massachusetts, USA to examine the distribution of silver and other trace metals (Cu, Pb, Cd, Zn, and Fe) in the coastal systems of Massachusetts and Cape Cod Bays. These investigations were designed to test the hypothesis that silver could serve as a tracer of dispersion of municipal wastewater in Boston Harbor into Massachusetts and Cape Cod Bays and estimate the relative contribution of wastewater discharge to the overall silver budget of the Massachusetts Bays system. Silver concentrations in both particulate and filtered (<0.4 µm) fractions averaged 103 and 117 pmol kg-1 for Boston Harbor, 34 and 10 pmol kg-1 in western Massachusetts Bay, and 11 and 7 pmol kg-1 in the central portion of Massachusetts Bay, respectively. Average Ag concentrations in southern Gulf of Maine coastal waters were 10 and 2 pmol kg-1 for filtered and particulate fractions, respectively. While nearly half of the silver existed in particulate form in Boston Harbor, nearly 80% of the silver in Massachusetts and Cape Cod Bays occurred in the filterable fraction. Coastal water surveys revealed non-conservative Ag behavior and probably the result of incomplete mixing of three or more water masses with unique Ag signatures (e.g., Merrimack River, Boston Harbor, surface and intermediate Gulf of Maine waters). Quasi-steady state mass balance approaches estimate most of the silver entering into the Massachusetts Bays system during the study period was the result of municipal wastewater discharge to Boston Harbor (84-93%).

Multivariate analyses …

Effect Of Mica Content On Surface Infiltration Of Soils In Northwestern Kern County, California, Steven Keyes Stakland

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

A soils infiltration rate (IR) is the measured rate that soil is able to absorb water, either from precipitation or irrigation. A low IR can cause damage to crops if the necessary amount of water cannot penetrate to the plant roots in the time needed. The damage can be common in permanent plantings such as almond and pistachio orchards where regular tillage is avoided. This indicates a physical aspect to the problem because tillage increases IR. However, there is also an electrochemical side to infiltration problems because certain calcium surfactant treatments can increase IR. Various other methods have been used …

The Interaction Of Rock And Water During Shock Decompression: A Hybrid Model For Fluidized Ejecta Formation, Audrey Hughes Rager

UNLV Theses, Dissertations, Professional Papers, and Capstones

Crater and ejecta morphology provide insight into the composition and structure of the target material. Martian rampart craters, with their unusual single-layered (SLE), double-layered (DLE), and multi-layered ejecta (MLE), are the subject of particular interest among planetary geologists because these morphologies are thought to result from the presence of water in the target. Also of interest are radial lines extending from the crater rim to the distal rampart of DLE craters. Exactly how these layered ejecta morphologies and radial lines form is not known, but they are generally thought to result from interaction of the ejecta with the atmosphere, subsurface …

Carbon Isotopic Fractionation Across A Late Cambrian Carbonate Platform: A Regional Response To The Spice Event As Recorded In The Great Basin, Jonathan Lloyd Baker

UNLV Theses, Dissertations, Professional Papers, and Capstones

Geochemical models have suggested that the late Cambrian was characterized by a greenhouse climate with high pCO2. Furthermore, stableisotope analyses within the Great Basin have documented a large carbonate isotope (δ13Ccarb) excursion, known as the Steptoean Positive Carbon Isotope Excursion (SPICE). This event has been documented globally, and is interpreted as having resulted from enhanced organic carbon burial. Unless the size of carbon reservoirs in the Cambrian ocean was significantly different from those of the Cenozoic, this forcing should have resulted in a comparable carbon-isotope excursion in organic matter (δ13Corg). It is also predicted that increased organic carbon burial would …

Age And Petrogenesis Of The Roaring Mountain Rhyolites, Yellowstone Volcanic Field, Wyoming, Kathleen Marie Wooton

UNLV Theses, Dissertations, Professional Papers, and Capstones

Extracaldera rhyolites in the Norris-Mammoth Corridor of the Yellowstone Volcanic Field (YVF) appear to be unrelated to intracaldera volcanism, resulting instead from a new crustal magma source derived from northeastward propagation of the Yellowstone “melting anomaly.” The youngest extracaldera rhyolite unit, the Roaring Mountain Member (RM), is chemically distinct from the previous extracaldera lavas, reverting to more primitive compositions.

This study suggests that the majority of the RM rhyolites erupted from the same large-scale silicic magma system. Based on geochemistry and 40Ar/39Ar geochronology, the Crystal Spring mingled rhyolite and Obsidian Cliff rhyolite erupted concurrently at 59.1 ± 2.0 ka. The …

Characterization Of Unsaturated Flow In Dual-Porosity Granular Media, Jeevan A. Jayakodilage

UNLV Theses, Dissertations, Professional Papers, and Capstones

A geological medium made up of uncemented coarse porous rock fragments may be described as a “dual-porosity granular medium” due to the presence of two types of pores; small pores within individual fragments and large pores between the fragments. Crushed stone found in heap leach piles, mine waste, backfills, rock drains, and engineered capillary barrier systems fit this description. Unsaturated flow in a dualporosity granular medium will occur both through the fragments (matrix flow), and on the fragment surfaces (film flow). The relative influence of gravity and capillary forces on these two flow regimes will be largely different. Therefore, unsaturated …

Late Paleozoic Deformation In The Osgood Mountains And Dry Hills, Northern Nevada, Samuel A. Siebenaler

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pennsylvanian (IP) and Permian (P) deposits (Etchart Formation) and structures in the northern Osgood Mountains and Dry Hills are identified and interpreted to reconstruct a late Paleozoic tectonic history for the time between the Antler and Sonoma orogenies. Mapping, field observations, fusulinid-based unit ages, and structural analysis are used to identify three fold and fault sets, a fault set, a fold set, and at least two angular unconformities. The faults consist of N to S striking normal faults (fault set 1) that are cross cut by WSW-ENE striking thrust faults (fault set 2). Fault sets 1 and 2 are cross …

Effect Of Spatial And Temporal Variability Of Antecedent Moisture Content On Model-Generated Runoff From An Arid Watershed, William J. Meyer

UNLV Theses, Dissertations, Professional Papers, and Capstones

Streams in the arid southwest are typically ephemeral, and stream gages are not commonly available. Consequently, runoff data from storm events is not available, and flood control facility design or other water resource related decisions are based on synthetic hydrographs. In the Mojave Desert region of Southern Nevada, the duration of storm used to develop these synthetic hydrographs is the 6 hour storm. The 6 hour storm is used to simulate high intensity summer storms. Additionally, soils information used in the calculations for these synthetic hydrographs is taken from maps that are generally developed for a broad range of issues …

Sequence And Chemostratigraphy Of The Middle Cambrian Succession In Nevada And Utah, Robyn A. Howley

UNLV Theses, Dissertations, Professional Papers, and Capstones

The House Range Embayment of western Utah and eastern Nevada was a prominent topographic feature on the passive margin of western North America during the middle and late Cambrian. In this study, detailed documentation of sequence boundaries, and their intervening sequences across a platform-to-basin transect of the House Range Embayment was used to establish a sequence-stratigraphic framework from which the depositional history of the embayment was deciphered. This framework was then used to test the hypothesis that the House Range Embayment formed by tectonic subsidence. In addition, the chemostratigraphic (δ13Ccarb) record across the embayment was analyzed within this framework to …

Estimates Of The Hydraulic Parameters Of Aquifers In Cache Valley, Utah And Idaho, Paul C. Inkenbrandt

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Hydraulic parameters of aquifers in Cache Valley were compiled from existing but largely unpublished data, from specific capacity data reported in well drillers' records, and from aquifer tests conducted for this study. A GIS database was also created to organize this information.

A complete and thorough literature review was performed, which included obtaining unpublished aquifer test data from state and federal agencies, as well as reviewing Drinking Water Source Protection plans for each municipality in the valley.

Well drillers' records were obtained from the Utah Division of Water Rights website and examined for pertinent information. Screened unit intervals from 1,314 …

Identification Of Patterns And Controls Of The Distribution Of Groundwater Discharge To Streams, Curtis Gebhard

All Theses

Groundwater discharge is a key component in understanding the interaction between groundwater and surface water. It provides baseflow to streams and can transport nutrients and contaminants to related aquatic ecosystems. It can also influence fish behaviour, spawning, migration and provide areas of refuge during summer and winter months. There are a variety of techniques that are used to characterize the magnitude of groundwater discharge including seepage meters, field permeameters, and piezometers and manometers, however the controls for the magnitude and distribution of discharge remain poorly understood. The purpose of this study was to conduct field investigations complimented with numerical analysis …

Stable Isotopes Of Fossil Teeth Corroborate Key General Circulation Model Predictions For The Last Glacial Maximum In North America, Matthew J. Kohn, Moriah Mckay

Geosciences Faculty Publications and Presentations

Oxygen isotope data provide a key test of general circulation models (GCMs) for the Last Glacial Maximum (LGM) in North America, which have otherwise proved difficult to validate. High δ18O pedogenic carbonates in central Wyoming have been interpreted to indicate increased summer precipitation sourced from the Gulf of Mexico. Here we show that tooth enamel δ18O of large mammals, which is strongly correlated with local water and precipitation δ18O, is lower during the LGM in Wyoming, not higher. Similar data from Texas, California, Florida and Arizona indicate higher δ18O values than in the Holocene, which is also predicted by GCMs. …

Recent Uplift Of The Burica Peninsula, Panama And Costa Rica, Recorded By Marine Terraces, Daniel Davidson

Earth and Environmental Geosciences Student Honors Theses

Deformation and uplift of the Burica Peninsula along the Panama-Costa Rica border results from eastward migration of the Panama Triple Junction (PTJ); the boundary between three tectonic plates. As the triple junction migrates to the southeast at ~55 mm/yr along the Middle America Trench (MAT), the Panama Fracture Zone (PFZ), separating the Cocos and Nazca plates, subducts under the Panama microplate. Differences in the thickness of the plates across the PFZ, as well as the rate and angle of subduction between the Cocos and Nazca plates, cause the Panama microplate to step up and over the Cocos plate. A flight …

Testing Mechanisms Of Subduction Zone Segmentation And Seismogenesis With Slip Distributions From Recent Andean Earthquakes, John P. Loveless, M. E. Pritchard, K. Kukowski

Geosciences: Faculty Publications

A long-standing goal of subduction zone earthquake studies is to determine whether or not there are physical processes that control seismogenesis and the along-strike segmentation of the megathrust. Studies of individual earthquakes and global compilations of earthquakes find favorable comparison between coseismic interplate slip distributions and several different long-lived forearc characteristics, such as bathymetry, coastline morphology, crustal structure, and interplate frictional properties, but no single explanation seems to govern the location and slip distribution of all earthquakes. One possible reason for the lack of a unifying explanation is that the inferred earthquake parameters, most importantly the slip distribution, calculated in …

Shelf Edge Tide Correlated Eddies Along The Southeastern United States, Dana K. Savidge, Jonathan Norman, Colton Smith, Julie A. Amft, Trent Moore, Catherine Edwards, George Voulgaris

Faculty Publications

High frequency radar observations in the Southeastern United States have revealed sequences of small short‐lived cyclonic eddies along the shoreward edge of the Gulf Stream, that spin up as the local tide turns alongshelf antiparallel to the Stream. Eddies propagate equatorward along the shelf edge, sometimes progressing shoreward before dissipating one to three hours later. They are distinctly different from Gulf Stream meander eddies, which propagate poleward. In this article, radar and mooring data are used to establish three important aspects of these neweddies: they represent an instability process operating at a previously unidentified frequency, scale, and cross‐Stream position; they …

Morphological Specification Of Chinianella Scheympflugi Hofmann, 1994, A Late Jurassic (?Earliest Cretaceous) Dasycladalean Alga Of The Western Tethyan Domain, Felix Schlagintweit

Studia UBB Geologia

The dasycladalean alga Chinianella? scheympflugi was described by Hofmann (1994) from the Tithonian of the Ernstbrunn Limestone of Lower Austria. This alga, so far unreported besides its type-locality, is reported from the Late Jurassic of Poland, the Northern Calcareous Alps of Austria, Crimea (Ukraine), and Greece (Parnassos Zone). Facies are well-agitated outer platform habitats (peri-reefal and back-reefal facies). The cylindrical thallus consists of three parts: a sterile Salpingoporella-like basal part (stalk), a fertile Chinianella-type main portion and a short sterile top part. The transition from the stalk to the main thallus portion is well marked and abrupt. The stratigraphic range …

Modern Variation In Predation Intensity: Constraints On Assessing Predator-Prey Relationships In Paleoecologic Reconstructions, James Funderburk

USF Tampa Graduate Theses and Dissertations

The complex interaction between predators and their prey is rarely preserved in the fossil record. However, predation of marine mollusks by drilling gastropods leaves a diagnostic hole in the shell of the prey, possibly allowing for quantitative analysis of this ecological interaction. Drilling frequency, as measured in marine mollusks both in the Modern and fossil record, has been heralded as a potential opportunity to quantify these ecological interactions and use these values in the testing of hypotheses.

This study employed the collection, tallying, and analysis of bulk samples derived from shelly deposits on 45 Modern beaches along the contiguous coast …

Carbon Isotope Compositions Of Terrestrial C3 Plants As Indicators Of (Paleo)Ecology And (Paleo)Climate, Matthew J. Kohn

Geosciences Faculty Publications and Presentations

A broad compilation of modern carbon isotope compositions in all C3 plant types shows a monotonic increase in δ¹³C with decreasing mean annual precipitation (MAP) that differs from previous models. Corrections for temperature, altitude, or latitude are smaller than previously estimated. As corrected for altitude, latitude, and the δ¹³C of atmospheric CO₂, these data permit refined interpretation of MAP, paleodiet, and paleoecology of ecosystems dominated by C3 plants, either prior to 7–8 million years ago (Ma), or more recently at mid- to high latitudes. Twenty-nine published paleontological studies suggest preservational or scientific bias toward …

Subsurface Images Shed Light On Past Tsunamis In India, Rajesh R. Nair, Ilya Buynevich, Ronald J. Goble, P. Srinivasan, S. G. N. Murthy, S. C. Kandpal, C. S. Vijaya Lakshmi, D. Trivedi

Department of Earth and Atmospheric Sciences: Faculty Publications

The 2004 Indian Ocean tsunami caused massive devastation and left a lasting impact along many of the major coastal regions in South Asia, including the coast of Tamil Nadu, a state in the southeastern tip of India. Following the event, sand deposits draped the low-lying areas and buried the muddy sediments of the coastal plain [Babu et al., 2007; Srinivasalu et al., 2007]. In addition, erosional features related to the tsunami, such as channels and scarps, have been observed along many parts of the coast (Figure 1a). This tsunami, along with a recorded history of intense monsoons, …

Exhumation Mechanisms Of The Greater Himalayan Sequence, Garhwal Region, India, Christopher James Spencer

Theses and Dissertations

Geothermobarometric, micro- and macro-structural data indicate that peak metamorphic pressure and temperature of the Greater Himalayan Sequence (GHS) of the Garhwal Region of India increase dramatically across the Main Central Thrust (MCT). Metamorphic pressure and temperature increase from ~5 kbar and ~550 ºC in the Lesser Himalayan Crystalline Sequence (LHCS) in the footwall to ~14 kbar and ~850 ºC at ~3 km above the MCT in the hanging wall (GHS). Pressures decrease slightly upsection to ~8 kbar and temperatures remain nearly constant at ~850 ºC to the structurally overlying South Tibetan Detachment (STD). The LHCS exhibits a high temperature-depth gradient …

Algorithms For Remote Estimation Of Chlorophyll-[Alpha] In Coastal And Inland Waters Using Red And Near Infrared Bands, Alexander A. Gilerson, Anatoly Gitelson, Jing Zhou, Daniela Gurlin, Wesley Moses, Ioannis Ioannou, Samir A. Ahmed

Center for Advanced Land Management Information Technologies: Publications

Remote sensing algorithms that use red and NIR bands for the estimation of chlorophyll-a concentration [Chl] can be more effective in inland and coastal waters than algorithms that use blue and green bands. We tested such two-band and three-band red-NIR algorithms using comprehensive synthetic data sets of reflectance spectra and inherent optical properties related to various water parameters and a very consistent in situ data set from several lakes in Nebraska, USA. The two-band algorithms tested with MERIS bands were R_rs(708)/R_rs(665) and R_rs(753)/R_rs(665). The three-band algorithm with MERIS bands was in the …

Creation Of A Revised Site Specific Liquefaction Potential Map Utilizing Geographic Information Systems (Gis) Technology And Arcgis® Software, Michael S. Armstrong

Earth and Soil Sciences

No abstract provided.

Geosciences Newsletter - 2010, Department Of Geosciences

Geological and Environmental Sciences News

Vol. 4, No. 1

• Faculty Updates
• Publications
• MGRRE
• Grants
• Graduate News
• Awards
• Field Trips
• Alumni
• Advisory Board

Rare Earth And High Field Strength Element Partitioning Between Iron-Rich Clinopyroxenes And Felsic Liquids, Paul H. Olin, John A. Wolff

Geosciences Faculty Publications and Presentations

Rare earth elements are commonly assumed to substitute only for Ca in clinopyroxene because of the similarity of ionic radii for REE³⁺ and Ca²⁺ in 8-fold coordination. The assumption is valid for Mg-rich clinopyroxenes for which observed mineral/melt partition coefficients are readily predicted by the lattice strain model for substitution onto a single site (e.g. Wood and Blundy, 1997). We show that natural Fe-rich pyroxenes in both silica-undersaturated and -oversaturated magmatic systems deviate from this behavior. Salites (Mg# 48 to 59) in phonolites from Tenerife, ferrohedenbergites (Mg# 14.2 to 16.2) from the rhyolitic Bandelier Tuff, and ferroaugites (Mg# …

Loring-Greenough House, North Yard Archaeogeophysics, Jamaica Plain, Massachusetts, John M. Steinberg, Christa M. Beranek, John Schoenfelder, Kathryn A. Catlin

Andrew Fiske Memorial Center for Archaeological Research Publications

An archaeogeophysical survey was carried out in May 2010 using Geonics EM-38 RT and a Malå Ground Penetrating Radar (GPR) system with a 500 MHz antenna over an 28x26 m grid immediately northeast of the Loring-Greenough house in Jamaica Plain, MA. Three major anomalies were identified. These anomalies have not been ground truthed, but they appear to be archaeological features. First, we suggest that there is builders trench just north of the house. Second, we suggest that there could be three east-west garden paths or other landscape features about 30 cm below the surface crossing the entire length of the …

A New Carnosaur (Dinosauria: Theropoda) From The Upper Morrison Formation (Late Jurassic, Tithonian) Of Colorado, Sebastian Dalman

Master's Theses or Doctor of Nursing Practice

A disarticulated skeleton of a theropod from the Late Jurassic (Tithonian) strata of McElmo Canyon in Montezuma County, Colorado was discovered in 1953 by the late J. T. Gregory and D. Techter. For nearly 55 years the specimen remained unnoticed in the collection of the Yale Peabody Museum of Natural History in New Haven, Connecticut. Several cranial and postcranial elements are relatively well preserved and include the premaxilla, maxilla, dentary, teeth, quadratojugal, braincase, metacarpals, partial pubis and ischium, astragalus, partial tibia and fibula, metatarsals, pedal phalanges, and several partially preserved ribs. The specimen represents a new genus and species of …

Spatial Similarities And Differences Of Attributes Of Three Subwatersheds Within The Middle Smoky Hill River Watershed And Their Relationship To Instream Total Suspended Solids, Dustin Fross

Master's Theses or Doctor of Nursing Practice

The objective of this study was to spatially analyze the attributes of three subwatersheds, Hydrological Unit Code 12 (HUC 12), of the Middle Smoky Hill River Watershed in west-central Kansas and relate the variances of the attributes to the concentrations of total suspended solids (TSS) entering the Smoky Hill River during storm events. This was accomplished by comparing land cover, including cropland, grassland, and urban factors; agricultural practices, such as tillage methods, condition of terraces, and the presence of grass waterways; geomorphology, including soil types, topography, and visible erosion; and lastly, precipitation variance. The three HUC 12s that were studied …

Heavy Metal Concentrations In Water And Surface Sediments Of Wilgreen Lake, Madison County, Kentucky, Chad Von Gruenigen, Walter S. Borowski

EKU Faculty and Staff Scholarship

Heavy metal pollution remains a problem in natural waters, particularly for localities near plausible anthropogenic sources. We assayed the level of heavy metals in surface waters and within surface sediments of Wilgreen Lake, whose watershed drains industrial, urban, and residential areas near Richmond, Kentucky.

Water samples were treated according to Environmental Protection Agency (EPA) protocols and digested with trace-metal-grade nitric and hydrochloric acids. Sediment samples were collected with a grab sampler and digested using established EPA procedures with hydrogen peroxide and trace-metal-grade nitric acid. Both water samples and sediment samples were sent to Activation Laboratories for analysis, and were measured …

Patterns Of Heavy Metal Concentration In Core Sediments, Wilgreen Lake, Madison County, Kentucky, Clint Mcmaine, Walter S. Borowski

EKU Faculty and Staff Scholarship

Elevated levels of cadmium, copper, lead, and nickel were found within the waters of Wilgreen Lake during a preliminary survey in 2007. Accumulation of heavy metals in freshwater systems is a known problem. Heavy metals enter the lake in the dissolved phase or adsorbed onto sediment particles and may be linked to industries within the lake’s watershed. Under certain geochemical conditions such as anoxia, heavy metals may detach from sediment particles and diffuse into overlying lake waters, causing a renewed influx of heavy metals into the ecosystem. We hypothesize that heavy metals should decrease in concentration upcore as a result …

Book Review: Stars Above, Earth Below: A Guide To Astronomy In The National Parks, T. D. Oswalt

Publications

This document is Dr. Oswalt’s review of Stars Above, Earth Below : a Guide to Astronomy in the National Parks by Tyler Nordgren. Springer/Praxis, 2010 444p, 9781441916488 $29.95.