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Quantifying Uncertainty In Landscape Evolution And Provenance Analysis: Insights From Statistical And Numerical Modelling, Vivian Carmello Grom Jan 2026

Quantifying Uncertainty In Landscape Evolution And Provenance Analysis: Insights From Statistical And Numerical Modelling, Vivian Carmello Grom

LSU Doctoral Dissertations

Landscape evolution models (LEMs) and detrital zircon provenance are widely used to investigate Earth surface processes, yet both face challenges related to quantifying model behavior and interpreting sedimentary signals under realistic, heterogeneous conditions. This thesis addresses these challenges through analysis and case studies that develop and apply new approaches for analyzing landscape dynamics and assessing uncertainties in sediment provenance.

Chapter 1 introduces a quantitative framework for evaluating LEM outputs using Shannon Entropy, Moran’s I, and Geary’s C. Applied to simulations with steady uplift, periodic uplift, spatially variable uplift, and a timeseries of DEMs, these metrics capture spatial organization and information …


The Shoreline Protection Potential Of Oyster Reefs: A Systematic Review And Meta-Analysis, Jessica R. Fergel, Robert E. Isdell, Gabriella Dipetto, Karinna Nunnez, Sean T. Gregory, Evan Hill, Donna Marie Bilkovic Jan 2026

The Shoreline Protection Potential Of Oyster Reefs: A Systematic Review And Meta-Analysis, Jessica R. Fergel, Robert E. Isdell, Gabriella Dipetto, Karinna Nunnez, Sean T. Gregory, Evan Hill, Donna Marie Bilkovic

Biological Sciences Faculty Publications

Nature-based solutions for erosion control that incorporate oyster reefs, alone or in combination with other habitats, are an increasingly popular approach due to their potential to protect shorelines and enhance oyster production. However, the extent to which natural or constructed oyster reefs provide shoreline protection remains unclear. We conducted a global systematic literature review and meta-analysis to summarize and evaluate the potential of oyster reefs in attenuating waves, promoting sediment accretion, and/or reducing shoreline erosion. Factors extracted from studies included shoreline protective measures examined, oyster reef structure type, and oyster reef tidal location. The results of the meta-analysis showed generally …


Hydrogeochemical And Redox Controls On Nitrate And Arsenic Co-Occurrence In The Western Kansas High Plains Aquifer (Usa): A Composite Health Risk Assessment And The Case For Risk-Informed Private Well Governance, Jonathan Kuffour Owusu Jan 2026

Hydrogeochemical And Redox Controls On Nitrate And Arsenic Co-Occurrence In The Western Kansas High Plains Aquifer (Usa): A Composite Health Risk Assessment And The Case For Risk-Informed Private Well Governance, Jonathan Kuffour Owusu

Master's Theses or Doctor of Nursing Practice

Fifty-one private domestic wells across western Kansas were sampled to quantify nitrate and arsenic occurrence, identify geochemical controls, and evaluate carcinogenic and non-carcinogenic health risks for adult and child receptors in a region where groundwater serves as the primary drinking water source with no routine regulatory oversight. Samples were analyzed for major ions, nutrients, and trace elements by ICP-MS, ion chromatography, and UV-Vis spectrophotometry. Shapiro-Wilk testing confirmed non-normal distributions for both contaminants; inter-county comparisons were therefore conducted using Kruskal-Wallis tests with Dunn's post-hoc correction. Health risk was quantified via chronic daily intake (CDI), hazard quotient (HQ), HQ-based Water Quality Index …


An Introduction To Field Excursions For The 2026 Geological Society Of America Cordilleran Section Meeting In Loreto, Baja California Sur, México, Scott E.K. Bennett, Michael H. Darin, Genaro Martínez Gutiérrez Jan 2026

An Introduction To Field Excursions For The 2026 Geological Society Of America Cordilleran Section Meeting In Loreto, Baja California Sur, México, Scott E.K. Bennett, Michael H. Darin, Genaro Martínez Gutiérrez

Geology Faculty Publications and Presentations

The 122nd annual meeting of the Geological Society of America (GSA) Cordilleran Section will be held in Loreto, Baja California Sur, México, an idyllic and historic Sonoran Desert city nestled on the eastern shore of the Baja California peninsula. The 2026 Loreto meeting marks a milestone for GSA as it is the first time in the Section’s century-plus history that the meeting has been held on the Baja California peninsula and only the third time that the meeting has been held in México. Thus, the 2026 Loreto meeting and related field trips represent a meaningful expansion of the Section’s engagement …


Using Remote Sensing Technology To Develop A Framework For Improving Hydrologic Models, Marissa Cook Jan 2026

Using Remote Sensing Technology To Develop A Framework For Improving Hydrologic Models, Marissa Cook

Theses, Dissertations and Capstones

With increased storm intensity due to climate change and urbanization, flash flooding has become an increasingly significant issue globally and regionally. Although the factors influencing urban flash flooding are well-known, there is a growing need for technology to accurately and remotely predict the chance of a flash flood occurring from any given rain event to give people time to prepare. This study aims to use multispectral satellite imagery to provide a framework for improving near real-time flood predictions in an urban area of a high gradient, fourth order stream impacted by flooding. Specifically, we utilize satellite imagery to create the …


Sedimentology, Paleontology, And Depositional Environments Of The Upper Devonian Lock Haven Formation In West Burlington Quarry, North-Central Pa, Michael Harman Jan 2026

Sedimentology, Paleontology, And Depositional Environments Of The Upper Devonian Lock Haven Formation In West Burlington Quarry, North-Central Pa, Michael Harman

Honors Theses

The Upper Devonian Lock Haven Formation in north-central Pennsylvania preserves evidence of significant climactic and evolutionary transitions, including the fin-to-limb transition and initial arborescence. The formation contains abundant sedimentary features, palynomorphs, trace fossils, and fish body fossils, making it crucial for reconstructing these paleoenvironments. However, integrated studies on the Lock Haven Formation are rare. This study characterizes the depositional environments, ichnology, paleontology, and age of the Lock Haven Formation. A recent exposure at the Insinger-Ward West Burlington Quarry reveals three middle to early late Famennian lithofacies associations (FAs). FA1 consists of red sandstone, shale, and mudstone containing rhizoliths (deeply penetrating …


Paleoflood Chronology For The West Branch Of The Susquehanna River Using Abandoned Chute Channel Sediments, Pennsylvania, Usa, Juliette A. Vanluven Jan 2026

Paleoflood Chronology For The West Branch Of The Susquehanna River Using Abandoned Chute Channel Sediments, Pennsylvania, Usa, Juliette A. Vanluven

Honors Theses

Anthropogenic climate change is altering the hydrologic cycle, increasing flood frequency and severity, with associated increased risks in population exposure. This is associated with increasing risks to the population of the Susquehanna River Valley, which supports over 600,000 people today. However, our understanding of the frequencies of large floods is limited by relatively short instrumental records. By studying sediments from an abandoned chute channel in the Robert Allen Natural Area near Williamsport, PA, we can extend the existing flood records using paleoflood slackwater sediments along the West Branch of the Susquehanna River.  Sylvan Dell is an abandoned chute channel that …


Sedimentological Characterization Of Main And Chute Channel Scroll Bars Along The Kantishna River, Alaska, Cooper Sentz Jan 2026

Sedimentological Characterization Of Main And Chute Channel Scroll Bars Along The Kantishna River, Alaska, Cooper Sentz

Honors Theses

Scroll bars, arcuate sediment ridges found along the inner banks of river bends, are common floodplain features in meandering river systems that form during lateral channel migration. Two hypothesized formation mechanisms described in prior studies are the aggradation of suspended load onto abandoned inner bank levee (IBL) deposits during overbank flow and the migration of transverse bar packages from the channel bed up onto the point bar during flooding events. To study the sedimentology and geometry of these features, we conduct remote sensing and field analysis on a 60 km portion of the Kantishna River, AK: a highly sinuous, pro-glacial …


Deep Crustal Boundaries As Fluid Conduits: A Geochemical Investigation Of Mvt Mineralization In Kentucky And Beyond, Dairian Boddy M. Boddy Jan 2026

Deep Crustal Boundaries As Fluid Conduits: A Geochemical Investigation Of Mvt Mineralization In Kentucky And Beyond, Dairian Boddy M. Boddy

Theses and Dissertations--Earth and Environmental Sciences

Critical minerals are vital to the United States economy and national security, yet their supply chains are at risk. Common minerals in Mississippi Valley-type (MVT) deposits, such as sphalerite, galena, fluorite, and barite, host critical metals such as barium, gallium, germanium, and zinc, which are essential for energy technologies. An investigation of three MVT mineral districts in Kentucky elucidated previously unrecognized systematics, genetic relationships, and sources of ore components using stable and radiogenic isotope geochemistry, particularly from galena, sphalerite, barite, and gangue minerals (e.g., carbonates). The localization and dominant type of mineralization in each district are potentially influenced by deep …


Paleo-Environmental Change In Deer Lagoon, Whidbey Island Interpreted From Diatoms And Lithology, Lourdes Garcia Jan 2026

Paleo-Environmental Change In Deer Lagoon, Whidbey Island Interpreted From Diatoms And Lithology, Lourdes Garcia

All Master's Theses

Puget Sound is a densely populated, tectonically active area that can be affected by earthquakes from local crustal faults and the Cascadia subduction zone capable of producing abrupt coseismic subsidence. Tidal wetlands are particularly sensitive to abrupt changes because they are depositional environments that reside at sea-level and their lithology and ecological communities are strongly controlled by elevation within the tidal frame. As a result, coseismic subsidence can disrupt established environmental gradients and leave distinguishable signatures preserved within the stratigraphy, like tidal mud directly over peat deposits. These preserved records provide an opportunity to reconstruct past earthquakes and associated relative …


Using Grounded Iceberg Wake Patterns To Interpret Catastrophic Flood Events In Southcentral Alaska, Jana K. Macinnis Jan 2026

Using Grounded Iceberg Wake Patterns To Interpret Catastrophic Flood Events In Southcentral Alaska, Jana K. Macinnis

All Master's Theses

Catastrophic flood events such as landslide tsunamis and jökulhlaups in glaciated areas can transport and strand icebergs, which obstruct the flow of floodwaters and leave a unique and recognizable grounded iceberg wake pattern in the sediment surface. Grounded iceberg wake patterns (GIWs) were identified at the two study areas in Southcentral Alaska; the outwash plain of a 1967 landslide tsunami at the Grewingk Glacier and proglacial lake, and the Matanuska River valley which experienced an unrecorded jökulhlaup in recent geological times. From these sites, 110 GIWs were identified through visual interpretation of lidar imagery and characterized by measuring their geometry, …


Spatial Patterns And Morphometric Evolution Of Sinkholes In Response To Watershed Hydrogeomorphology: Examples From A Karst Landscape In The Missouri Ozarks, Usa, Marcell Tóth Jan 2026

Spatial Patterns And Morphometric Evolution Of Sinkholes In Response To Watershed Hydrogeomorphology: Examples From A Karst Landscape In The Missouri Ozarks, Usa, Marcell Tóth

Graduate Theses/Dissertations

Sinkholes are characteristic enclosed depressions with internal drainage connecting the surface and subsurface karst hydrologic system. Their morphological evolution involves gradual subsidence of the ground surface and hazardous collapses. Therefore, understanding sinkhole morphometry and linked spatial distribution is critical for managing geohazards in karst watersheds. Sinkhole occurrence shows spatial variability based on watershed geomorphological attributes, surficial hydrological patterns, hydrogeological and geological settings. The aim of this research is to investigate morphometric properties and distribution of sinkholes in the carbonate karst-dominated lands of Mark Twain National Forest in Missouri, USA. The specific objectives were to (1) identify sinkhole clusters based on …


Applied Machine Learning In Mineral Prospectivity Mapping In The South Pass-Granite Mountains Of Wyoming, Carl D. York Jan 2026

Applied Machine Learning In Mineral Prospectivity Mapping In The South Pass-Granite Mountains Of Wyoming, Carl D. York

Graduate Theses/Dissertations

The South Pass-Granite Mountains, comprised of Archean to Tertiary rocks embedded with an Archean greenstone belt in Central Wyoming, have historically been mined for gold, iron, steel, and silver. Rare earth elements have been of increasing interest in the region and thus, several datasets have become available. Knowledge driven and data driven models are used in mineral prospectivity mapping with input data including geological mapping, geochemical data, geophysical (USGS Critical Mineral magnetic and gravity data), radiometric (U, Th, K) data and multispectral remote sensing data. Mineral prospectivity has seen a rapid improvement in recent years using advancements in machine learning …


Flow Regime Shifts And Channel Morphological Adjustments In Response To Changing Climate Patterns: Examples From Gasconade River, Missouri, Usa, Katherine E. Brand Jan 2026

Flow Regime Shifts And Channel Morphological Adjustments In Response To Changing Climate Patterns: Examples From Gasconade River, Missouri, Usa, Katherine E. Brand

Graduate Theses/Dissertations

Recent changes in climate patterns due to anthropogenic inputs (i.e. greenhouse gases/CO₂) have caused alterations to precipitation events leading to altered flow regimes. Changes in the magnitude and frequency of flood events results in physical adjustments to river morphology, including changes in width and depth. As rivers experience more frequent and larger flood events, they accommodate by changing their morphological characteristics. The Gasconade River, a tributary of the Missouri River located in southcentral Missouri, USA, has exhibited recent patterns of acute bank erosion with limited understanding of its causes and effects on the river. This study aims to understand how …


Field-Scale Evaluation Of Satellite- Derived Vegetation Indices And Image Timing For In-Season Nitrogen Management In Corn, Ana Morales-Ona, Katsutoshi Mizuta, James J. Camberato, Robert Nielsen, Yuxin Miao, Davide Cammarano, German Mandrini, Daniel Quinn Jan 2026

Field-Scale Evaluation Of Satellite- Derived Vegetation Indices And Image Timing For In-Season Nitrogen Management In Corn, Ana Morales-Ona, Katsutoshi Mizuta, James J. Camberato, Robert Nielsen, Yuxin Miao, Davide Cammarano, German Mandrini, Daniel Quinn

Plant and Soil Sciences Faculty Publications

Introduction: Traditional methods to determine the agronomic optimum nitrogen rate (AONR) for corn (Zea mays L.) rely on grain yield data, limiting in-season decision-making for nitrogen (N) management. Vegetation indices (VIs) derived from satellite imagery can serve as proxies for grain yield and help estimate in-season AONR, enabling timely sidedress applications. This study aimed to (1) quantify how VI–yield relationships vary during the vegetative period across fields with different tillage systems and crop residue; (2) determine whether VI–N response curves can be used to estimate AONR (AONRvi); and (3) assess the accuracy of AONRvi relative to yield-based AONR (AONRy). …


Spatiotemporal Dynamics Of Mountain Front Recharge Flow Paths And Their Contribution To Alluvial Aquifer Water Supply, Mikaela Bollag-Miller Jan 2026

Spatiotemporal Dynamics Of Mountain Front Recharge Flow Paths And Their Contribution To Alluvial Aquifer Water Supply, Mikaela Bollag-Miller

Graduate Student Theses, Dissertations, & Professional Papers

Mountain Front Recharge (MFR) is a critical recharge source for alluvial basin aquifers throughout the Intermountain West, yet the spatial and temporal dynamics of distinct recharge pathways remain poorly constrained. This study investigates the seasonal and spatial dynamics of MFR pathways and evaluates their impact on the Missoula Aquifer, a sole-source alluvial aquifer in western Montana, USA. MFR includes both surface-water inflows from mountain areas and Mountain Block Recharge (MBR), the groundwater contribution to the basin aquifer. A valley-scale water balance was employed to estimate first-order contributions and temporal fluctuations of MBR flow paths. A three-layer steady-state MODFLOW groundwater model …


Application Of Organic Geochemistry To The Characterization Of Hydrochar And Biochar: Insights Into Composition And Optimization, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Rubén Forján, José Luis Gallego Jan 2026

Application Of Organic Geochemistry To The Characterization Of Hydrochar And Biochar: Insights Into Composition And Optimization, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Rubén Forján, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Hydrothermal carbonization has garnered significant attention in recent studies due to potential applications of the hydrochar produced, which overlap with those of torrefied biochar, including soil improvement, carbon sequestration, and energy production. However, unlike the relatively uniform properties of biochar, hydrochar characteristics can vary greatly depending on the feedstock used. Advanced characterization techniques are essential to better understand these materials and enhance their practical applications. Research on hydrochar requires a multi-faceted approach, including molecular-level studies, to optimize production processes and identify specific applications.

In this regard, analytical methods commonly used in organic geochemistry could play a crucial role in deepening …


A Hybrid Cnn-Lstm Surrogate Model For Hyper-Resolution Spatiotemporal Flood Forecasting In Norfolk, Virginia, Yidi Wang, Jonathan L. Goodall, Chetan Kumar, Diana Mcspadden, Sergio A. Barbosa, Binata Roy, Ali Shahabi, Navid Tahvildari Jan 2026

A Hybrid Cnn-Lstm Surrogate Model For Hyper-Resolution Spatiotemporal Flood Forecasting In Norfolk, Virginia, Yidi Wang, Jonathan L. Goodall, Chetan Kumar, Diana Mcspadden, Sergio A. Barbosa, Binata Roy, Ali Shahabi, Navid Tahvildari

Data Science Faculty Publications

Study region

Norfolk, Virginia, United States

Study focus

Accurate and timely flood forecasting is essential for enhancing resilience in coastal urban areas in the context of increasing frequency and intensity of rainfall, sea level rise and urbanization. This study presents a hybrid deep learning-based surrogate model that integrates Convolutional Neural Networks (CNN) and Long Short-Term Memory (LSTM) networks to enable real-time spatiotemporal flood forecasting. The model leverages CNN to capture spatial features from inputs such as elevation and Topographic Wetness Index (TWI), while LSTM processes time-series inputs of rainfall and tide data to capture temporal features.

New hydrologic insights for …


Forecasting Precipitation In Cuba Using Graph Based Deep Learning, Taufiqul Islam Jan 2026

Forecasting Precipitation In Cuba Using Graph Based Deep Learning, Taufiqul Islam

Earth & Environmental Sciences Theses

Daily precipitation forecasting remained a challenging problem in regions characterized by strong spatial heterogeneity, nonlinear atmospheric dynamics, and intermittent rainfall behavior. Cuba represented a particularly complex case due to the combined influence of tropical cyclones, easterly waves, mesoscale convective systems, and orographic effects, which produced highly variable rainfall patterns in both space and time. Conventional statistical and machine-learning models typically treated stations independently and therefore overlooked spatial dependencies that strongly influenced rainfall variability across the island.

This study developed a spatiotemporal deep-learning framework for daily precipitation forecasting across 40 spatial nodes in Cuba using data from 1979 to 2023. The …


Investigation Of Reey Concentrations In Argillaceous Rocks Associated With Coal Beds In Southwestern West Virginia, Alyssa Cameron Long Jan 2026

Investigation Of Reey Concentrations In Argillaceous Rocks Associated With Coal Beds In Southwestern West Virginia, Alyssa Cameron Long

Theses, Dissertations and Capstones

Rare earth elements (REEs) and Yttrium are classified as “critical minerals” that are used in many industries and are typically extracted from carbonatites and related alkaline plutonic rocks. The limited availability of REE+Y requires finding alternate sources such as coal fly ash, tonstein, fireclays, and shales. This study investigates the potential enrichment of shales, fireclays, and siltstones interbedded with coal from southwestern WV in REEY, and the mechanisms of such enrichment. Using ICP-AES analysis of various rock types shows that shales, silty shales, and siderite nodules interbedded with Fire Clay and Chilton Coal beds in the Kanawha Formation record the …


Geospatial Analysis Of Sinkhole Density And Characteristics In West Virginia, Marissa Shannon Loftus Jan 2026

Geospatial Analysis Of Sinkhole Density And Characteristics In West Virginia, Marissa Shannon Loftus

Graduate Theses, Dissertations, and Problem Reports (ETD)

Creation of a sinkhole map of West Virginia provides useful data to help identify areas susceptible to sinkhole related hazards, as well as allowing for detailed analysis of factors controlling karst development. Newly available, statewide LiDAR-derived digital elevation data have made mapping sinkholes over larger spatial extents feasible. For this study, sinkholes were mapped for all areas of West Virginia that are underlain by carbonate rocks; then the distribution and characteristics were evaluated overall and in four focus areas (Berkeley and Jefferson counties, Pendleton County, Greenbrier County, and Monroe County). These areas correspond to broader physiographic regions, with Berkeley, Jefferson, …


Constraining The Tectono-Climatic Evolution Of The Northern Rocky Mountains: Insights From Volcanic Glass, Leaf Water, And Leaf Wax Hydrogen Isotopes, Rijumon Nandy Jan 2026

Constraining The Tectono-Climatic Evolution Of The Northern Rocky Mountains: Insights From Volcanic Glass, Leaf Water, And Leaf Wax Hydrogen Isotopes, Rijumon Nandy

Earth & Environmental Sciences Dissertations

The Eocene-Oligocene period in the North American Cordillera represents a period of great intrigue with complex interactions among tectonics, climate, and surface processes. Although this period is generally associated with synorogenic extension associated with gravitational collapse of the Cordillera, the paleotopographic history remains debated. Existing studies offer conflicting interpretations, suggesting either sustained elevations or modest uplift during this time. Notably, recent reconstructions based on volcanic glass δD values have proposed renewed uplift during the early Oligocene, which needs to be tested with a more extensive and robust dataset. Concurrently, global cooling and aridification during this interval may have been amplified …


Nonstationary Spatial Correlation Of Earthquake Ground Motions In California, Pengfei Wang, Busra Bocekli, Junhui Yang, Scott J. Brandenberg, Jonathan P. Stewart Jan 2026

Nonstationary Spatial Correlation Of Earthquake Ground Motions In California, Pengfei Wang, Busra Bocekli, Junhui Yang, Scott J. Brandenberg, Jonathan P. Stewart

Civil & Environmental Engineering Faculty Publications

Assessing seismic risk to spatially distributed infrastructure systems requires realistic representations of spatially correlated ground motions. Existing models for the spatial correlations of ground motions rely on strong second-order stationarity assumptions, under which the correlation structure is assumed to be invariant across space, potentially masking regional variations. Because repeatable site and path effects can vary spatially, the resulting correlation structure is likely to be nonstationary. We propose a nonstationary spatial correlation method that captures geographically varying correlation decay behavior. We compute site-to-site Pearson correlations of within-event residuals using earthquakes recorded at both sites in each site pair and model the …


Characterization Of Phytoplankton-Excreted Metabolites Mediating Carbon Flux Through The Surface Ocean, Yuting Zhu, Hanna S. Anderson, Eli Salcedo, Samuel E. Miller, Krista Longnecker, Melissa C. Kido Soule, Sheean T. Haley, Gretchen J. Swarr, Rogier Braakman, Sonya T. Dyhrman, Elizabeth B. Kujawinski Jan 2026

Characterization Of Phytoplankton-Excreted Metabolites Mediating Carbon Flux Through The Surface Ocean, Yuting Zhu, Hanna S. Anderson, Eli Salcedo, Samuel E. Miller, Krista Longnecker, Melissa C. Kido Soule, Sheean T. Haley, Gretchen J. Swarr, Rogier Braakman, Sonya T. Dyhrman, Elizabeth B. Kujawinski

Chemistry & Biochemistry Faculty Publications

The marine labile dissolved organic carbon (DOC) pool is a dynamic reservoir of thousands of molecules that cycles approximately one-quarter of Earth’s primary production within days to weeks. After excretion by phytoplankton and other microbes, metabolites are rapidly consumed, resulting in low standing concentrations (picomolar to low nanomolar). Despite the decades-long search for labile DOC sources and molecular identities, marine phytoplankton exometabolomes are not well characterized, largely due to difficulties in measuring small polar molecules in saline water. Here, we profiled the exometabolomes of six axenic phytoplankton species representing key functional groups including a diatom (Thalassiosira pseudonana CCMP1335), a …


Nonpyrogenic "Black" Nitrogen Likely Plays A Major Yet Underrecognized Role In The Global Nitrogen Cycle, João Vitor Dos Santos, Aleksandar I. Goranov, Kyle M. Lambert, Theodoro Da Rosa Salles, Susan J. Carter, Ann Pearson, Patrick G. Hatcher Jan 2026

Nonpyrogenic "Black" Nitrogen Likely Plays A Major Yet Underrecognized Role In The Global Nitrogen Cycle, João Vitor Dos Santos, Aleksandar I. Goranov, Kyle M. Lambert, Theodoro Da Rosa Salles, Susan J. Carter, Ann Pearson, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Condensed aromatic nitrogen (ConAN) is commonly found in soil and aquatic environments. ConAN is broadly viewed by the biogeochemistry community as a combustion-derived product leading to its frequent designation as pyrogenic “black” nitrogen. Here, we provide evidence that ConAN can also form through nonpyrogenic pathways. In an experiment simulating biomass oxidation, pine wood boards assembled with iron nails were exposed to 12 years of natural environmental conditions. Nitrogen concentrations increased from 0.2 to 1.2 wt % with increasing proximity to the nail. Ultrahigh resolution mass spectrometry showed enrichment of nitrogen-containing compounds within the lignin and condensed aromatic domains. X-ray spectroscopic …


Land Use Influences Dissolved Organic Matter Composition In The U.S. Coastal Critical Zone Network, Aleksandar I. Goranov, Elizabeth V. Whitney, Brian R. Moyer, Katherine L. Tully, Patrick G. Hatcher, Yu-Ping Chhin Jan 2026

Land Use Influences Dissolved Organic Matter Composition In The U.S. Coastal Critical Zone Network, Aleksandar I. Goranov, Elizabeth V. Whitney, Brian R. Moyer, Katherine L. Tully, Patrick G. Hatcher, Yu-Ping Chhin

Chemistry & Biochemistry Faculty Publications

Coastal watersheds are highly productive biogeochemical systems supporting robust coastal fisheries and contributing significantly to the marine gross primary production flux. These ecosystems are comprised of civil infrastructure, farms, forests, and marshes, and their diversity is reflected in the quantity and quality of dissolved organic matter (DOM). Here, we assess the role of farming in influencing DOM from surface waters of six coastal tidal creeks adjacent to forest and farm sites in the US Critical Zone Network. Molecular fingerprinting using electrospray ionization - Fourier transform - ion cyclotron resonance - mass spectrometry revealed that farm-influenced DOM was enriched in nitrogen-, …


Overview And Methods Of Molecular Paleontology: A Review, Shelby Touchstone Jan 2026

Overview And Methods Of Molecular Paleontology: A Review, Shelby Touchstone

Williams Honors College, Honors Research Projects

Molecular paleontology—the study of ancient biomolecules preserved in fossils and sediments, including ancient DNA, lipids, and proteins—has motivated researchers since the 1950s, inspiring both scientific inquiry and broader cultural imagination. Think Jurassic Park. This honors thesis presents a comprehensive review of the history, current state, and methods of the field of molecular paleontology. Drawing on peer-reviewed literature and scholarly resources accessed through databases such as EBSCO and Bierce library, this review examines key techniques such as Next Generation Sequencing and amino acid racemization and will go over limitations and controversies in the field. It will also explore potential new …


Preliminary Analysis Of The Spatial Distribution Of Microplastics Along The Cuyahoga River, Northeast, Ohio, Ella Pitz Jan 2026

Preliminary Analysis Of The Spatial Distribution Of Microplastics Along The Cuyahoga River, Northeast, Ohio, Ella Pitz

Williams Honors College, Honors Research Projects

Plastics are nearly ubiquitous throughout modern society, and when left in the natural environment, they degrade into microplastics. Microplastics are particles that range in diameter from 5 millimeters down to nanometers, and microplastics pose many potential environmental and health risks due to their small size and ease of ingestion. While the study of microplastics in the environment has become more common over the past ten years, microplastic concentrations remain unexplored in many regions throughout the country. Here I present a method for separating microplastics from organic matter and clastic sediment as well as preliminary measurements of microplastic concentrations in sediment …


Assessing And Understanding Soil Characteristics, Amy Papineau Jan 2026

Assessing And Understanding Soil Characteristics, Amy Papineau

UNH Cooperative Extension

No abstract provided.


Investigating Netarts Bay, Oregon Coastal Landscape Change From Tectonic Subsidence Through Isotopic, Stratigraphic Records And Quantifying Dune Influence On Salt Marsh Morphodynamics, Emily Hall Jan 2026

Investigating Netarts Bay, Oregon Coastal Landscape Change From Tectonic Subsidence Through Isotopic, Stratigraphic Records And Quantifying Dune Influence On Salt Marsh Morphodynamics, Emily Hall

Open Access Master's Theses

Coastal salt marshes on tectonically active margins face dual pressures from episodic seismic events and anthropogenic modifications. This study investigated how the 1700 CE Cascadia Subduction Zone earthquake and the 1900 CE introduction of invasive dune grass influenced back-barrier salt marsh morphodynamics at Netarts Bay, Oregon. It was hypothesized that (1) salt marsh habitats and elevation transitions would be detectable in geochemical proxies preserved in stratigraphy, (2) modern dune stabilization significantly limits mineral sediment delivery to the salt marsh, and (3) this reduction would be preserved in the stratigraphic record. Stratigraphic and isotopic analyses of sediment cores incorporating CT scans, …