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Biomarkers In The Lower Huron Shale (Upper Devonain) As Indicators Of Organic Matter Source, Depositional Environment, And Thermal Maturity, John Kroon

All Theses

The Lower Huron Shale (Upper Devonian) is considered the largest shale gas reservoir in the Big Sandy Field in Kentucky and West Virginia. The potential for gas shales, such as the Lower Huron, to produce natural gas is a function of type, amount, and thermal maturation of their organic matter. Twenty-one Lower Huron Shale samples from eight wells located in eastern Kentucky and southern West Virginia were analyzed for biomarker content to interpret biological source of organic matter, depositional environment conditions, and thermal maturity. The following biomarkers were identified: n-alkanes (C15 to C31), pristane (Pr), phytane (Ph), steranes (αααR, (αααS, …

No-Net-Loss Not Met For Nutrient Function In Freshwater Marshes: Recommendations For Wetland Mitigation Policies, Katie Hossler, Virginie Bouchard, M. Siobhan Fennessy, Serita D. Frey, Evelyn Anemaet, Ellen Herbert

Faculty Publications

Wetlands provide many important services throughout the world, with an estimated economic value that, in comparison to other ecosystems, far exceeds their relatively small global extent. In recognition of their importance, both national and international regulations exist to protect the world's remaining wetlands. Of growing interest is the “no-net-loss” policy which permits unavoidable destruction of wetlands if compensated by restoration of degraded wetlands or creation of new wetlands. The fundamental assumption of no-net-loss is that wetlands can be created which function equivalently to natural wetlands. One integral function that wetlands perform is cycling of carbon, nitrogen and phosphorus. Here we …

Solving The Mystery Of The Atacama Nitrate Deposits: The Use Of Stable Oxygen Isotope Analysis And Geochemistry, Ji-Hye Seo

The Journal of Purdue Undergraduate Research

The Atacama Desert, Chile, one of the oldest and driest deserts on Earth, is unique because it contains the largest known nitrate deposits in the world. The origin of these nitrate deposits has been a mystery since their discovery in the 1800s. There are two possible sources of natural nitrate: microbiological processes and photochemical reactions. The majority of material on Earth follows mass-dependent fractionation between stable oxygen isotopes with the abundance of ¹⁷Ο (denoted by δ) as half that of ¹⁸O. This relationship is quantified by Δ¹⁷O = δ¹⁷O – ½ δ¹⁸O, …

Outdoor Classroom And Wildlife Habitat Development, Patricia Sowell, Deborah Sherfey, Kandy Fear

Education for Sustainability Summer Institute

No abstract provided.

Taxonomy And Geochemistry Of The Globigerinoides Ruber-Elongatus Plexus, With Paleontological Implications, Elizabeth Ann Brown

USF Tampa Graduate Theses and Dissertations

The reliability of foraminifera as stratigraphic index fossils, and as isotopic proxies of marine environments, is based on the assumption that the fossil concepts represent uniform species, responding consistently to their ambient environments. Understanding sources of uncertainty is, therefore, critical. In this dissertation, I explore a potential bias in the application of planktonic foraminifera utilized extensively for Cenozoic paleo-reconstruction and, to a lesser extent, biostratigraphy: the Globigerinoides ruber-elongatus plexus (‘plexus’ meaning a complex network of interconnected members). Taxonomic revisions since 1826 have resulted in the merging of multiple Globigerinoides species names under one general designation (“Globigerinoides ruber”), the implications of …

The Nature, Origin And Preservation Of Amide Organic Nitrogen In Organic Matter, Georgina Anne Mckee

Chemistry & Biochemistry Theses & Dissertations

Past studies have found much of nonliving sedimentary/aqueous nitrogen-containing organic matter (NCOM) is composed of amides, assumed to be peptides/proteins. Their lability calls into question their survival, and several hypotheses have been suggested to explain this. Using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) and nuclear magnetic resonance (NMR) spectroscopy I investigated the molecular amide composition in sedimentary/aqueous systems while reassessing their preservation and formation routes.

Development of a suitable methodology is essential for successful NCOM study due to electrospray ionisation source requirements: sediment samples need to be rendered into solution. Based on NMR and FT-ICR-MS analysis, I determined …

Model-Based Analyses Of Nitrogen On The Mid-Atlantic Bight Continental Shelf, Tian Tian

OES Theses and Dissertations

The biogeochemistry of continental shelf systems is an important, but poorly quantified, component of the global cycling of nitrogen and carbon. In this study, simulations obtained from a one-dimensional (ID) biogeochemical model developed for the Middle Atlantic Bight (MAB) portion of the U.S. eastern continental shelf were analyzed to investigate nitrogen cycling processes. The 1D model included lower trophic level interactions and was forced by advective fields obtained from a corresponding three-dimensional biogeochemical model. Taylor and target diagram analyses, which compared in situ measurements of sea surface temperature (SST) and salinity, and chlorophyll and particulate organic carbon (POC) derived from …

Identifying Changes In Climatic Trends And The Fingerprints Of Landuse And Landcover Changes In The High Plains Of The Usa, Denis Mutiibwa

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Human activities such as conversion of natural ecosystem to croplands and urban-centers, deforestation and afforestation impact biophysical properties of land surface such as albedo, energy balance, and surface roughness. Alterations in these properties affect the heat and moisture exchanges between the land surface and atmospheric boundary layer. The objectives of this research were; (i) to quantitatively identify the High plains’ regional climate change in temperatures over the period 1895 to 2006, (ii) detect the signatures of anthropogenic forcing of LULC changes on the regional climate change of the High Plains, and (iii) examine the trends in evolving regional latent heat …

Comparison Of Soil Chemistry And Microbial Communities That Inhabit The Rhizosphere Of Native And Non-Native Grasses Of The Lower Rio Grande Valley, Jacqueline Valencia

Theses and Dissertations - UTB/UTPA

Non-native grasses can modify the soils they invade. This study investigated microbial variation among native and non-native grasses in the Lower Rio Grande Valley. We hypothesized that rhizospheres of non-native grasses would support a higher density of microorganisms; therefore microbial communities of invasive plants would exploit more carbon sources than those of native plants. A second hypothesis stated that Streptomyces bacteria from the rhizosphere of non-native grasses would be better competitors. Samples of grasses, and soil from their respective rhizospheres were obtained in Arroyo City, TX. Results indicated a higher bacterial colony density, total activity and number of substrates utilized …

Environmental History Of A Closed-Basin Lake In The Us Great Plains: Diatom Response To Variations In Groundwater Flow Regimes Over The Last 8500 Cal. Yr Bp, William O. Hobbs, Sherilyn C. Fritz, Jeffery R. Stone, Joseph J. Donovan, Eric C. Grimm, James E. Almendinger

Department of Earth and Atmospheric Sciences: Faculty Publications

Sediment records from closed-basin lakes in the Northern Great Plains (NGP) of North America have contributed significantly to our understanding of regional paleoclimatology. A high-resolution (near decadal) fossil diatom record from Kettle Lake, ND, USA that spans the last 8500 cal. yr BP is interpreted in concert with percent abundance of aragonite in the sediment as an independent proxy of groundwater flow to the lake (and thus lake water level). Kettle Lake has been relatively fresh for the majority of the Holocene, likely because of the coarse substrata and a strong connection to the underlying aquifer. Interpretation of diatom assemblages …

The Collaborative Colorado– Nebraska Unmanned Aircraft System Experiment, Adam L. Houston, Brian Argrow, Jack Elston, Jamie Lahowetz, Eric W. Frew, Patrick C. Kennedy

Department of Earth and Atmospheric Sciences: Faculty Publications

Unmanned aircraft (UA) can provide observations of atmospheric phenomena that are either difficult or impossible to obtain with existing platforms. It is for this reason that facilitating the maturation of this relatively new technology has become a high priority in the atmospheric sciences. This position is reflected in the 2007 National Research Council Decadal Survey, which states that unmanned aircraft technology “should be increasingly factored into the nation’s strategic plan for Earth science” (National Research Council 2007, p. 14). Moreover, the fiscal year 2008 budget for the National Oceanic and Atmospheric Administration (NOAA) featured an increased investment in unmanned aircraft …

Techniques To Promote Garry Oak Seedling Growth And Survival In Areas With High Levels Of Herbivory And Competition, David R. Clements, Seth Luginbill, David A. Jordan, Randall Dragt

University Faculty Publications and Creative Works

Though regeneration of Garry oak (Quercus garryana) seedlings within Garry oak ecosystems is important to maintain this threatened habitat, seedling regeneration is often poor. Two independent studies were initiated in the early 2000s to examine questions surrounding Garry oak recruitment: one at the Crow's Nest Ecological Research Area (CNERA) on Salt Spring Island, BC, and another at the Pacific Rim Institute for Environmental Stewardship (PRI) on Whidbey Island, WA. In both areas, Garry oak seedlings were caged and monitored for growth and relative health. Over 8 years at CNERA, growth of caged plants outpaced growth of controls, which was indicative …

Abrupt Holocene Climate Change As An Important Factor For Human Migration In West Greenland, William J. D'Andrea, Yongsong Huang, Sherilyn C. Fritz, N. John Anderson

Department of Earth and Atmospheric Sciences: Faculty Publications

West Greenland has had multiple episodes of human colonization and cultural transitions over the past 4,500 y. However, the explanations for these large-scale human migrations are varied, including climatic factors, resistance to adaptation, economic marginalization, mercantile exploration, and hostile neighborhood interactions. Evaluating the potential role of climate change is complicated by the lack of quantitative paleoclimate reconstructions near settlement areas and by the relative stability of Holocene temperature derived from ice cores atop the Greenland ice sheet. Here we present high-resolution records of temperature over the past 5,600 y based on alkenone unsaturation in sediments of two lakes in West …

Filling The Gap: Commonsense Solutions For Meeting Front Range Water Needs: Executive Summary, Western Resource Advocates, Trout Unlimited, Colorado Environmental Coalition (U.S.)

Navigating the Future of the Colorado River (Martz Summer Conference, June 8-10)

8 pages.

"February 2011"

Presented by Drew Beckwith, Water Policy Manager, Western Resource Advocates, on June 10th at Clyde O. Martz Summer Conference 2011, Navigating the Future of the Colorado River Basin

Full report available at: http://www.westernresourceadvocates.org/gap

Soil Development Processes On The Western Slope Of The Southern Sierra Nevada Mountains: A Geographic Study, Kristopher (Kris) Osterloh

Earth and Soil Sciences

No abstract provided.

From Sink To Resurgence: The Buffering Capacity Of A Cave System In The Tongass National Forest, Usa, Chris Groves, Melissa Hendrikson

Earth, Environmental, and Atmospheric Sciences Faculty Publications

The Tongass National Forest of Southeast Alaska, USA, provides a unique environment for monitoring the impact of the cave system on water quality and biological productivity. The accretionary terrane setting of the area has developed into a complex and heterogeneous geologic landscape which includes numerous blocks of limestone with intense karstification. During the Wisconsian glaciation, there were areas of compacted glacial sediments and silts deposited over the bedrock. Muskeg peatlands developed over these poorly drained areas. The dominant plants of the muskeg ecosystem are Sphagnum mosses, whose decomposition leads to highly acidic waters with pH as low as 2.4. These …

Go Farm, Goleta: Urban Agriculture Protection For Eastern Goleta Valley, Eli M. Krispi

Master's Theses

This paper explores two potential land use planning strategies that can be used to preserve and enhance the economic viability of agricultural operations surrounded by suburban development in Santa Barbara County’s Eastern Goleta Valley: buffers between agriculture and other land uses, and agritourism. In the case of buffers, academic literature is examined to determine how effective buffers are at various tasks (filtering runoff, mitigating dust and wind, providing habitat, etc.) and how to construct buffers to maximize their effectiveness. Land use plans and codes from several California jurisdictions are studied to see how buffers are put to use. Academic literature …

The Impact Of Modern Weathering On The Geochemistry Of A Marine Permo-Triassic Boundary Section, Jeremy Christopher Williams

Graduate Masters Theses

The Permian-Triassic Boundary (PTB) marks the end-Permian extinction, the greatest mass extinction recorded in Earth's history. The Attargoo PTB section located in Spiti Valley, Himachal Pradesh, India was situated along the north continental margin of Gondwana-land in the Neo-Tethys Ocean during the end-Permian extinction. In Spiti Valley, PTB sections such as Attargoo are exposed by a thin (~ 2cm) ferruginous layer separating the Permian black shale from Triassic Limestone. Studies that have presented geochemical data to support a theory of the end-Permian extinction lack any interpretation of post-depositional effects on Spiti Valley PTB sections. In order to accurately present a …

Taxonomic Composition, Paleoecology And Biostratigraphy Of Late Cretaceous Diatoms From Devon Island, Nunavut, Canadian High Arctic, Jakub Witkowski, David M. Harwood, Karen Chin

Department of Earth and Atmospheric Sciences: Faculty Publications

Upper Cretaceous sediments of the Kanguk Formation exposed in Eidsbotn and Viks Fiord grabens on Devon Island, Nunavut, Canadian High Arctic, yielded 91 fossil marine diatom species and varieties (including indeterminate taxa), representing 41 genera. Excellent preservation of the assemblages was aided by shallow burial, protection in down­faulted linear grabens, and the presence of abundant volcanic material. Planktonic species and resting spores com­prise nearly 70% of the diatom assemblage, and provided abundant food resources for the Late Cretaceous Arctic eco­system. Deposition of the approximately 225 m-thick stratigraphic sequence was predominantly in a shallow marine neritic setting, with an upward progression …

Secretive Marsh Bird Species Co-Occurrences And Habitat Associations Across The Midwest, Usa, Jason R. Bolenbaugh, Sarah E. Lehnen, David G. Krementz

United States Geological Survey: Staff Publications

Because secretive marsh birds are difficult to detect, population status and habitat use for these birds are not well known. We conducted repeated surveys for secretive marsh birds across 264 sites in the Upper Mississippi River and Great Lakes Joint Venture region to estimate abundance, occupancy, and detection probabilities during the 2008 and 2009 breeding seasons. We identified species groups based on observed species co-occurrences. Two species, least bittern Ixobrychus exilis and American bittern Botaurus lentiginosus, co-occurred with other species less often than expected by chance, and two species groups, rails (Virginia rail Rallus limicola and sora Porzana carolina) and …

Historical Legacies, Information And Contemporary Water Science And Management, Daniel J. Bain, Jennifer A. S. Arrigo, Mark B. Green, Brian A. Pellerin, Charles J. Vörösmarty

Advanced Science Research Center

Hydrologic science has largely built its understanding of the hydrologic cycle using contemporary data sources (i.e., last 100 years). However, as we try to meet water demand over the next 100 years at scales from local to global, we need to expand our scope and embrace other data that address human activities and the alteration of hydrologic systems. For example, the accumulation of human impacts on water systems requires exploration of incompletely documented eras. When examining these historical periods, basic questions relevant to modern systems arise: (1) How is better information incorporated into water management strategies? (2) Does any point …

Determining The Lon-Exchange Mechanism Of Strontium Into A Niobium Doped Titanosilicate, Samantha Jane Kramer

Masters Theses & Specialist Projects

A 25% niobium substituted sitinakite was exchanged with strontium as time resolved X-ray diffraction data was collected. The structural modeling of this data by Rietveld method1 has lead to the determination of the atomic positions of the ions and unit cell parameters as strontium occupancy increases.

The starting material of the exchange experiment is the protonated phase, H2Nb0.67Ti1.33SiO7·1.9 H2O, with space group P42/mcm2,3. Once strontium (Sr2+) enters the unit cell, extra-framework H2O molecules shift to provide the necessary hydration coordination. These new positions of H2O result in a lowering of symmetry to the P-42m space group, and it is thought …

Rapid Wetland Expansion During European Settlement And Its Implication For Marsh Survival Under Modern Sediment Delivery Rates, Matthew L. Kirwan, A. Brad Murray, Jeffrey P. Donnelly, D. Reide Corbett

United States Geological Survey: Staff Publications

Fluctuations in sea-level rise rates are thought to dominate the formation and evolution of coastal wetlands. Here we demonstrate a contrasting scenario in which land-use–related changes in sediment delivery rates drive the formation of expansive marshland, and vegetation feedbacks maintain their morphology despite recent sediment supply reduction. Stratigraphic analysis and radiocarbon dating in the Plum Island Estuary (Massachusetts, United States) suggest that salt marshes expanded rapidly during the eighteenth and nineteenth centuries due to increased rates of sediment delivery following deforestation associated with European settlement. Numerical modeling coupled with the stratigraphic observations suggests that existing marshland could survive, but not …

Improving Energy Sustainability In Pound Hall, Craig Adams

Department of Environmental Studies: Undergraduate Student Theses

This research project deals with improving energy sustainability in Pound Hall dormitory located on the University of Nebraska at Lincoln’s (UNL) city campus.  An investigation on the current energy usage of Pound Hall showed that its energy rates worsened between the years of 2009 and 2010.  These combined (electricity, steam, and water) energy rates were compared with those of the newly renovated Othmer Hall to emphasize the lack of sustainability in the older dormitory.  In order to improve Pound Hall’s energy rates, an energy benefit analysis of implementing a green roof was performed.  Having a green roof on this dormitory …

Spatial Analysis Of A Bioterrorist Attack On Four Major United States Cities Using An Aerosolized Hemorrhagic Fever Virus, Kathryn Prinslow

Master's Theses or Doctor of Nursing Practice

Before the attack on September 11,2001, the United States was very vulnerable to a biological attack. Since then, those responsible for the security of the United States Homeland Security have become more aware of the country's vulnerability. Biological agents have the potential to give small groups of people unprecedented power to terrorize, as indicate by the "Amerithrax" attack in 2001, and of all of these agents, none have more potential for destruction than Ebola Hemorrhagic Fever (EHF). This research uses one of the deadliest viruses that have not been eradicated to identify the number of fatalities in an outbreak affecting …

Process-Based Management Of Downy Brome In Salt Desert Shrublands: Assessing Pre- And Post- Rehabilitation Soil And Vegetation Attributes, Merilynn Carol Hirsch

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

As an ecosystem driver, downy brome (Bromus tectorum L.) presents obstacles to land rehabilitation efforts, including restoring desirable species cover. Because damaged ecosystems may have crossed both abiotic and biotic thresholds, ecologically-based control strategies may assist with altering successional trajectories and restoring desirable plant species. My thesis research had three objectives: 1) assess soil and vegetation relationships in degraded salt desert ecosystems prior to implementing downy brome control treatments, 2) determine the effects of control treatments on soil properties and resident plant species, and 3) evaluate the relative importance of shrubland soil type, herbicide type, and herbicide rate on seedling …

Stratigraphic, Microfossil, And Geochemical Analysis Of The Neoproterozoic Uinta Mountain Group, Utah: Evidence For A Eutrophication Event?, Dawn Schmidli Hayes

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Several previous Neoproterozoic microfossil diversity studies yield evidence for a relatively sudden biotic change prior to the first well‐constrained Sturtian glaciations. In an event interpreted as a mass extinction of eukaryotic phytoplankton followed by bacterial dominance, diverse assemblages of complex acritarchs are replaced by more uniform assemblages consisting of simple leiosphaerid acritarchs and bacteria. Recent data from the Chuar Group of the Grand Canyon (770‐742 Ma) suggest this biotic change was caused by eutrophication rather than the direct effects of Sturtian glaciation; evidence includes total organic carbon increases indicative of increasing primary productivity followed by iron speciation values that suggest …

Relationships Of Exotic Plant Invasions With Biological Soil Crust, Desert Pavement, And Soil Carbon In The Eastern Mojave Desert, Adria Decorte

UNLV Theses, Dissertations, Professional Papers, and Capstones

In a matter of 50 years, exotic annual plants have become widespread in the Mojave Desert, contributing to drastic landscape changes such as those caused by recent fires. Invasions by exotics threaten native Mojave Desert plant communities by altering community functions (e.g. fire regimes) and by reducing plant diversity. Because it is not practical, or even possible, to eradicate these exotics, developing effective prevention techniques is the key to controlling these invasions.

This thesis used a greenhouse experiment, a field experiment, and a correlational field study to examine the affect soil surface types have on the establishment of three exotic …

Impacts Of Climate Change And Weather Modification On Hydrologic Characteristics Of Watersheds In The Western United States, Anil Acharya

UNLV Theses, Dissertations, Professional Papers, and Capstones

This research quantifies the impacts of climate change and weather modification (WM) on hydrologic characteristics of watersheds in the arid regions of the western United States. This research performs a long-term simulation of streamflow for present and future climate conditions in the North Platte (NP) Watershed, Wyoming; a shorter duration simulation is then performed to observe the likely impacts of event based changes in an urban watershed in Las Vegas, Nevada.

First, a study is carried out in Chapter 3 that evaluates the impacts of WM on water supply by developing a hydrologic model for the NP Watershed. The variable …

Co-Development Of Biological Soil Crusts, Soil-Geomorphology, And Landscape Biogeochemistry In The Mojave Desert, Nevada, U.S.A. – Implications For Ecological Management, Amanda Jean Williams

UNLV Theses, Dissertations, Professional Papers, and Capstones

Biological soil crusts (BSCs) are complex matrices of soil particles, mosses, lichens, and cyanobacteria that prevent erosion and influence water and energy balances, soil fertility, and vascular plant germination. The processes that form BSCs, the factors that control their distribution, and the ecosystem feedbacks that they sustain are poorly understood. This dissertation employed a novel interdisciplinary approach to address those research unknowns through investigations of the micromorphological structure, soil-geomorphic relationships, and biogeochemical feedbacks of BSCs in the Mojave Desert.

A micromorphological study of BSCs resulted in a succession model that illustrates how crust formative processes and structures change through time. …