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Potential Role Of Inorganic Polyphosphate In The Cycling Of Phosphorus Within The Hypoxic Water Column Of Effingham Inlet, British Columbia, Julia M. Diaz, Ellery D. Ingall, Samuel D. Snow, Claudia R. Benitez-Nelson, Martial Taillefert, Jay A. Brandes

Faculty Publications

[1] The upper basin of Effingham Inlet possesses permanently anoxic bottom waters, with a water column redox transition zone typically occurring at least 40 m above the sediment‐water interface. During our sampling campaign in April and July 2007, this redox transition zone was associated with sharp peaks in a variety of parameters, including soluble reactive phosphorus (SRP) and total particulate phosphorus (TPP). Based on sequential extraction results, TPP maxima exhibited preferential accumulation of an operationally defined class of loosely adsorbed organic phosphorus (P), which may contain a substantial fraction of polyphosphate (poly‐P). This poly‐P may furthermore be involved in the …

Speciation And Removal Mechanisms Of Rhenium In Anoxic Waters: Roles Of Zero-Valent Sulfur, Mineral Oxide Catalysis, And Pyrite Surfaces, Trent P. Vorlicek

All Private Grants

Global warming is expected to intensify the effects of coastal anoxia. Knowledge of the causes of geohistorical anoxic episodes may prove critical in developing strategies for the mitigation of or adaptation to the consequences of climate change upon the global aquatic environment. The geochemistry of Re provides the means to acquiring this knowledge. Within oxic waters, Re exists as geochemically-inert ReO4-. Under reducing conditions, Re is removed from the aqueous phase and deposited in sediments. Unfortunately, an incomplete understanding of Re geochemistry hampers exploitation of Re as a paleoredox indicator. Authors purport Re sequestration begins in suboxic environments; others produce …

Global Estimates Of Mineral Dust Aerosol Iron And Aluminum Solubility That Account For Particle Size Using Diffusion-Controlled And Surface-Area-Controlled Approximations, Qin Han, Charles S. Zender, J. Keith Moore, Clifton S. Buck, Ying Chen, Anne Johansen, Christopher I. Measures

All Faculty Scholarship for the College of the Sciences

Mineral aerosol deposition is recognized as the dominant source of iron to the open ocean and the solubility of iron in the dust aerosol is highly variable, with measurements ranging from 0.01–80%. Global models have difficulty capturing the observed variations in solubility, and have ignored the solubility dependence on aerosol size. We introduce two idealized physical models to estimate the size dependence of mineral aerosol solubility: a diffusion‐controlled model and a surface‐area‐controlled model. These models produce differing time‐ and space‐varying solubility maps for aerosol Fe and Al given the dust age at deposition, size‐resolved dust entrainment fields, and the aerosol …

Assessment Of The Oxbow Morphology Of The Caloosahatchee River And Its Evolution Over Time: A Case Study In South Florida, Chloe Delhomme

USF Tampa Graduate Theses and Dissertations

The Caloosahatchee River, located in Southern Florida, was originally a meandering and relatively shallow river. During the 1920s, the Caloosahatchee River was channelized and became the C-43 canal. The channelization has significantly impacted the river ecosystem, particularly the oxbows. The oxbows are the U-shaped water bodies on each side of the river channel, which are the remnant bends of the original river. To understand how anthropogenic influence affects hydrologic systems, the proposed case study was designed to assess the geomorphic changes of the oxbows of the Caloosahatchee River, Florida. Understanding and documenting the evolution of river morphology is becoming increasingly …

The Effects Of Biochar Age And Concentration On Soil Retention Of Phosphorus And Infiltration Rate, Emilie Schneider

Natural Resources Management and Environmental Sciences

Changes in land use and land management practices are regarded as one of the main factors in altering the hydrogeological system, causing changes in runoff, surface supply yields, and the quality of receiving water (Tong and Chen, 2002). Phosphorus is a significant contributor to accelerated eutrophication of fresh water and is largely sourced from agricultural runoff (Sharpley et al., 1994). The dominant processes controlling solution composition in agricultural soils are primarily ‘chemical’ for P (i.e. adsorption/desorption and dissolution/precipitation) (Edwards and Withers, 1998). Biochar has chemical characteristics that have the potential to adsorb P or influence precipitation of P insoluble pools …

Modeling Glacial Termination, Michael Murphy

Natural Resources Management and Environmental Sciences

Examines possible cause of the glacial termination or ice age cycle using a numerical model created by Tziperman et al. Also explores possible physical mechanisms causing the observed cycle of slow cooling followed by rapid warming.

Using Environmental Variables And Soil Processes To Forecast Denitrification Potential And Nitrous Oxide Fluxes In Coastal Plain Wetlands Across Different Land Uses, Jennifer L. Morse, Marcelo Ardón, Emily S. Bernhardt

Environmental Science and Management Faculty Publications and Presentations

We examined relationships between denitrification (DNF) and nitrous oxide (N2O) fluxes and potentially important chemical and physical predictors to build a predictive understanding of gaseous N losses from coastal plain wetlands. We collected soil, gas, and pore water samples from 48 sampling locations across a large (440 ha) restored wetland, an adjacent drained agricultural field, and nearby forested wetlands every two months over two years. In summer and fall 2007, we measured soil DNF potential (21.6-3560 mg N m-3 d-1) and N2O efflux (-4.36-8.81 mg N m -2 d-1), along with 17 predictor variables. We developed statistical models for the …

Integrating Depositional Facies And Stratigraphy In Characterizing Hydrothermal Dolomite Reservoirs: Trenton Group Of The Albion-Scipio Trend, Michigan, Marcel R. Robinson

Masters Theses

Reservoir characterization of carbonate rocks requires understanding the role of depositional and diagenetic parameters in reservoir distribution. This is especially true for the diagenetically-altered and structurally-influenced Trenton-Black River reservoirs of the Michigan Basin. Evaluating the depositional evolution and reservoir characteristics of component depositional facies through modeling and stratigraphic reconstruction would aid in exploration and characterization through providing a prediction tool for reservoir distribution, both within and outside of the Michigan Basin.

Results indicate that reservoir development is controlled by primary rock fabric related to depositional facies. Depositional and stratigraphic reconstructions show facies distribution trends occur consistently and therefore predictably away …

Chlorophyll-Based Approach For Remote Estimation Of Crop Gross Primary Production: From In Situ Measurements To Satellite Imagery, Yi Peng

School of Natural Resources: Dissertations, Theses, and Student Research

The synoptic and accurate quantification of crop gross primary production (GPP) is essential for studying carbon budgets in croplands and monitoring crop status. The objective of this dissertation is to develop a quantitative technique to estimate crop GPP using remotely sensed data collected from close range to satellite altitudes. In this study, a model based on a recently developed paradigm, which relates crop GPP to a product of total crop chlorophyll content and incident radiation affecting vegetation photosynthesis, was justified for the remote estimation of GPP in crops. The model was tested with ground-observed incoming photosynthetically active radiation (PAR_{in …}

Paragenesis Of Lacustrine Microbialites In The Upper Wilkins Peak Member, Green River Formation, Wyoming, Bethania Chagas Tosta Siviero

Loma Linda University Electronic Theses, Dissertations & Projects

Microbialites from the upper Wilkins Peak Member were investigated to determine their paragenesis and to help interpret lake chemistry. Two specific microbialite beds were analyzed that are associated with the “layered tuff”. Samples were collected from correlated sections along a NW to SE, 24 km line of section from lake margin towards lake center. XRD, SEM/EDS, and petrographic analysis show differences in diagenesis above and below the layered tuff.

Microbialites below the tuff bed contain some primary calcite with diagenetic dolomite and abundant secondary silicification. Later, dolomite replaces both calcite and quartz. Pores are commonly filled with 20 μm euhedral …

Determination Of Toxic Heavy Metals In Wet Deposition And Ambient Air In Columbus, Ga, Melissa K.M. Nestor

Theses and Dissertations

Atmospheric pollution is one of the most significant and potentially catastrophic environmental issues threatening the United States and the world today. One such source of this pollution is heavy metals. The impact of heavy metal pollution on living organisms can be disastrous, having the potential to cause the deterioration of ecosystems and posing danger to the health and survival of the human race. Chronic and acute human exposure to this type of pollution can damage the proper functioning of vital body organs by inhibiting important neurological pathways. In plants, it essentially acts as a counter-agent to proper growth. In areas …

North Central Region Soil Survey Conference Field Tour

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

The International Bathymetric Chart Of The Arctic Ocean (Ibcao) Version 3.0, Martin Jakobsson, Larry A. Mayer, Bernard Coakley, Julian A. Dowdeswell, Steve Forbes, Boris Fridman, Hanne Hodnesdal, Riko Noormets, Richard Pedersen, Michele Rebesco, Hans Werner Schenke, Yulia Zarayskaya, Daniela Accettella, Andy Armstrong, Robert M. Anderson, Paul Beinhoff, Angelo Camerlenghi, Ian Church, Margo Edwards, James V. Gardner, John K. Hall, Benjamin Hell, Ole Hestvik, Yngve Krisoffersen, Christian Marcussen, Rezwen Mohammad, David Mosher, Son V. Nghiem, Maria Teresa Pedrosa, Paola G. Travaglini, Pauline Weatherall

Center for Coastal and Ocean Mapping

[1] The International Bathymetric Chart of the Arctic Ocean (IBCAO) released its first gridded bathymetric compilation in 1999. The IBCAO bathymetric portrayals have since supported a wide range of Arctic science activities, for example, by providing constraint for ocean circulation models and the means to define and formulate hypotheses about the geologic origin of Arctic undersea features. IBCAO Version 3.0 represents the largest improvement since 1999 taking advantage of new data sets collected by the circum-Arctic nations, opportunistic data collected from fishing vessels, data acquired from US Navy submarines and from research ships of various nations. Built using an improved …

The Relation Among Essential Habitat, Ocean Acidification, And Calcification On The Nantucket Bay Scallop (Argopecten Irradians), Bryanna Joy Broadaway

Graduate Doctoral Dissertations

The relation among essential habitat, ocean acidification, and calcification in Argopecten irradians (Lamarck 1819) was examined through field and laboratory research. Three major questions were addressed: 1) What habitat conditions are associated with abundant populations of bay scallops in Nantucket Harbor? 2) How might future predictions of ocean pH decline affect the biomineralization of shell by bay scallop across juvenile and adult life stages? 3) Are there biochemical indicators that can inform our understanding on how the bay scallop may cope with ocean acidifying events? Elemental fingerprinting of adult and juvenile Nantucket bay scallop shells, A. irradians, revealed distinct element/Ca …

New Insights Into Troglotella Incrustans Wernli & Fookes, 1992, A Fascinating Upper Jurassic-Upper Cretaceous Foraminifer, Felix Schlagintweit

Studia UBB Geologia

New data about the highly variable test morphology of the benthic foraminifer Troglotella incrustans WERNLI & FOOKES (Oxfordian-Lower Cenomanian) are presented, permitting an emended species/genus diagnosis. This concerns mainly the existence of a large final chamber with fistulose extensions that may follow the uniserial or the irregular-branching test part. The way of life of T. incrustans (cryptoendolithic vs. euendolithic) is discussed against the background of different existing models in the literature. The study is based on material (thin-sections and provided photographs) mainly from the Upper Jurassic of Austria, Italy, Romania, Ukraine, and also the type-locality of France.

Magnitude And Composition Of Sinking Particulate Phosphorus Fluxes In Santa Barbara Basin, California, Emily Sekula‐Wood, Claudia R. Benitez-Nelson, Melissa A. Bennett, Robert Thunell

Faculty Publications

[1] The composition and bioavailability of particulate P influence marine biological community production on both modern and geologic time‐scales, and continental margins play a critical role in the supply, modification, and storage of particulate P. This study examined particulate P cycling in the Santa Barbara Basin (SBB) off the coast of southern California using a ∼520 m deep‐moored sediment trap deployed from 1993–2006 and a sediment core collected in 2005 directly beneath the sediment trap at 590 m. Total particulate P (TPP), particulate inorganic P (PIP), and particulate organic P (POP) were quantified using a 5‐step sequential extraction method (SEDEX) …

Using Emerging Methods To Investigate Stream And Groundwater Interaction At Multiple Spatial Scales, Martin Ashley Briggs

Earth & Environmental Sciences - Dissertations

Fundamentally, streams represent physical conduits of water across gradients, yet a more holistic definition reveals stream corridors support a mosaic of living communities in a blend of surface and ground waters. The physical and biogeochemical patterns these dynamic systems support affect natural habitat and water quality, directly impacting the human experience. Our understanding of stream and groundwater interactions is at a time of rapid expansion due to an increase in environmental awareness, accountability, and emerging techniques which can be used to decipher underlying controls and develop predictive relationships. Water temperature has been used as a qualitative environmental tracer during the …

A Chemical And Morphological Study Of Soils At The Cal Poly Vineyard, Glade A. Dlott

Natural Resources Management and Environmental Sciences

Despite cultivation for close to a decade, the soils at the Cal Poly vineyard have never been studied in detail. This study was designed to gain a better understanding of the soils for better management. Soil pits and auger holes were dug throughout the site to accurately classify soils. Soils were classified using USDA-NRCS Soil Taxonomy, and samples were taken from each horizon of each soil pit for chemical analysis. Four soil map units were delineated on the site. The pH, EC, total percent carbon and nitrogen, and plant available nitrate, sulfate, phosphate, base cations, and metal micronutrients of each …

The Use Of Diatoms To Infer Environmental Change Of The Lower White River, Southeastern Arkansas, Ruchi Bhattacharya

Graduate Theses and Dissertations

This dissertation describes the limnology of the lower White River oxbow lakes in southeast Arkansas, inundated by the major 2008 spring flood. The flood water and sediment deposited in oxbow lakes were analyzed for water chemistry, sediment geochemistry and diatom assemblages and used as an analogue for past floods. The 2008 spring flood inundated and homogenized the entire floodplain; also represented by the predominantly planktonic diatom assemblage suggesting riverine input. Indicator species for eutrophication were also recorded consistent with the high nutrient content in the lakes. However, the variance in the surface diatom assemblage was best explained by the lake …

Assessment Of The Rainfall Response On Headwater Streams In Lower Coastal Plain South Carolina, Thomas Epps

All Theses

Toward the goal of the assessment of the rainfall response on forested headwater catchments in the Lower Coastal Plain (LCP) of South Carolina, rainfall, streamflow, and groundwater elevation were monitored on two similar streams. Upper Debidue Creek (UDC) in coastal Georgetown County, South Carolina is slated for development and Watershed 80 (WS80) in the Francis Marion National Forest serves as an undeveloped reference watershed. Spatial rainfall variability was assessed at UDC and it was concluded that a single gage was sufficient to accurately measure rainfall for this watershed. Throughfall measurements at UDC indicate a seasonal difference that may influence seasonal …

Treatment Of Oilfield Produced Water Using A Pilot-Scale Constructed Wetland Treatment System, Michael Pardue

All Theses

In recent years production of oil in sub-Saharan Africa has generated thousands of barrels of oilfield produced water (OPW). If water produced from oilfields in sub-Saharan Africa can be treated, this large volume of water has the potential for use in irrigation, which could decrease demand on existing water resources. In this investigation a pilot-scale constructed wetland treatment system (CWTS) consisting of three series: a free water surface flow (FWS) series, a subsurface flow (SSF) series, and a hybrid SSF series preceded by an oil-water separator (OWS), was utilized to treat OPW. Two major objectives were to: 1) assess treatment …

Interspecific Hybridization Among Black Basses (Micropterus Spp.) In The Chattahoochee River, Columbus Georgia, Kimberly S. Holley

Theses and Dissertations

Interspecific hybridization can lead to the evolution of a new hybrid species or extinction of parental species due to competition or excessive backcrossing, When parental populations differ in abundance, hybrids tend to backcross more frequently with the more abundant parent, resulting in asymmetrical introgression. The objective of this study was to determine the extent and apparent direction of hybridization between shoal bass {Micropterus cataractae), a rare endemic species to the Apalachicola drainage, and spotted bass (M. punctulatus), an introduced and more abundant species. Pelvic fin tissue (N = 130) was taken from bass species in the Chattahoochee River between Columbus, …

Evaluation Of Electrophoretic Protein Extraction And Database-Driven Protein Identification From Marine Sediments, Eli K. Moore, Brook L. Nunn, Jessica F. Faux, David R. Goodlett, H. Rodger Harvey

OES Faculty Publications

Intact proteins comprise a major component of organic carbon and nitrogen produced globally and are likely an important fraction of organic matter in sediments and soils. Extracting the protein component from sediments and soils for mass spectral characterization and identification represents a substantial challenge given the range of products and functionalities present in the complex matrix. Multiple forms of gel electrophoresis were evaluated as a means of enhancing recovery of sedimentary protein before proteomic characterization and compared with a direct enzymatic digestion of proteins in sediments. Resulting tryptic peptides were analyzed using shotgun proteomics and tandem mass spectra were evaluated …

Fate Of Cerium Oxide (Ceo₂), Nanoparticles In Landfill Leachate, Casey Marie Ezyske

Theses, Dissertations and Culminating Projects

Nanomaterial (NM) based manufacturing is predicted to grow to 15% of the global manufacturing economy by 2014. Subsequent to their use, most of the engineered nanomaterials (ENMs), man-made particles with at least dimension between 1 and 100 nm, will be disposed of in landfills. Landfill leachate is highly contaminated wastewater containing a variety of constituents that may affect the fate and transport of the nanomaterials. In this study, the size and zeta potential of cerium oxide (CeO₂), an industrially important nanomaterial, was investigated in different solution matrices (Milli-Q water, a real landfill leachate, KC1 solution, and humic acid …

Analysis Of A Stormwater Pond For Stormwater Management On The Buffalo State College Campus – Year 1 Operation Conditions, Jessica Bakert

Multidisciplinary Studies Theses

Under U.S.EPA Phase II stormwater regulations Buffalo State was required to develop a stormwater management plan. This plan pursues both hard‐engineering and low impact development approaches for stormwater management. As part of the plan, a detention pond came on‐line in early summer, 2010, to collect flow before it discharges to Scajaquada Creek. The objective of this study was to assess the detention pond impact on water quantity and quality prior to discharge to the creek. A meter was installed in 2007 (pre‐construction) and 2010 (post‐construction) to record stormwater discharge to Scajaquada Creek. Regression analysis between rainfall and runoff characteristics showed …

Using Landsat Thematic Mapper Satellite Imagery Assessing And Mapping Trophic State In Cheney Reservoir, Kansas, Dingnan Lu

Master's Theses or Doctor of Nursing Practice

Eutrophication is a major inland water problem that is researched by many environmentalists and hydrologists. A eutrophic inland water body can cause many negative water problems, such as taste and odor, biotoxin, and low dissolved oxygen. Many previous studies were effective based on using remote sensing to evaluate water body trophic state. In this study, the Cheney Reservoir is selected as an object to test the performance of using remote sensing, specifically the Landsat Thematic Mapper sensor, to evaluate the trophic state of a reservoir. Based on Landsat TM imagery, the chlorophyll a concentration is estimated to be used to …

Understanding Of The Hydrologic Connections Between Wide-Channel And Adjacent Aquifers Using Numerical And Field Techniques, Cheng Cheng

School of Natural Resources: Dissertations, Theses, and Student Research

Streambed sedimentary structure plays a vital role in controlling the interactions between surface water and groundwater. In the study, three rivers -the Big Blue River, the Little Blue River, and the lower reach of the Platte River in Nebraska were chosen to characterize the shallow streambed for the two types of rivers (braided and meandering rivers) and investigated the variations of the streambed electrical and hydraulic conductivities with depth. In-situ and laboratory permeameter tests were conducted to determine streambed hydraulic conductivity up to 20 m below the channel surface in the three rivers. Additionally, the electrical conductivity logs were obtained …

The Carbon Budget Impact Of Sagebrush Degradation, Andrew Connor Austreng

Boise State University Theses and Dissertations

More than 20,000 km2 of sagebrush (Artemesia spp.) ecosystems within the Great Basin have been replaced, often following wildfire, by the nonnative winter annual cheatgrass (Bromus tectorum). At a field site in the central Snake River Plain of southern Idaho, the impact of this invasion on the soil carbon (C) reservoir has been evaluated and the potential soil C benefits of bunchgrass (Agropyron cristatum) seeding was assessed. Using a large soil C dataset (n = 850), differences in total organic carbon and root biomass were quantified in immediately-adjacent sagebrush, cheatgrass, and bunchgrass communities. Statistical …

Natural And Constructed Wetlands For Ecosystem And Engineering Services In The Arid And Semi-Arid Regions, Achyut Raj Adhikari

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Las Vegas Wash (LVW) has undergone significant wetlands degradation and soil erosion over the past thirty years due to increasing flow resulting from urbanization and large rainfall events in the Las Vegas Valley Watershed. The increased flow and associated pollution load in the LVW and its adverse impact in Lake Mead have alerted stakeholders to pay a greater attention to explore alternative measures for rehabilitation of wetland ecosystems. This dissertation, using the case of changes in LVW, analyzes and describes ecological and engineering services provided by wetlands in arid and semi-arid regions and provides a knowledge base that can …

The Fluvial Muddy Creek Formation Near Overton, Nevada, Carl Taylor Swenberg

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Muddy Creek Formation (MCF) may represent an ancestral Colorado River deposit. To test this hypothesis, I mapped exposures of the MCF within the Virgin River Depression (VRD), a rift basin in the central Basin and Range. This is the first study to analyze fluvial MCF facies and test their viability as ancestral Colorado River deposits.

Mapping, paleocurrent analysis, conglomerate provenance, and architectural elements analysis were used in order to characterize the fluvial MCF near Overton NV. Architectural elements analysis revealed that MCF fluvial facies are most closely associated with those of a high-energy sand-bed braided river system. These results …