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Fluxes Of Dissolved Organic Carbon During Storm Events In The Neponset River Watershed, Keith Thomas Cialino

Graduate Doctoral Dissertations

The transport of dissolved organic carbon (DOC) and chromophoric dissolved organic matter (CDOM) from land to coastal environments strongly influences coastal ecosystems. The presence of first flush phenomena due to rainwater runoff traveling from land into waterways can greatly affect carbon fluxes to coastal areas. This research utilizes sensors, autosamplers, and standard watershed sampling in order to assess for the presence of first flush and its significance. A rainfall simulator was built in order to collect runoff on two land use types. Time series data suggest that first flush of dissolved organic carbon was present for all rainfall intensities simulated …

Microfossils As Proxies For Holocene Climate In Semi-Enclosed Basins: The Hudson River Estuary, New York, Usa And The Marmara Sea, Turkey, Damayanti Gurung

Dissertations, Theses, and Capstone Projects

The transition from the late Pleistocene glacial to the warmer Holocene interglacial occurred within a series of climatic oscillations. The Holocene, a relatively warm and stable period, was also marked by smaller climatic variability of millennial- to-centennial-scale oscillations. Furthermore, during this period global sea level was much lower than at present. My present study will analyze micro-fossils as proxies for their response to these climatic fluctuations, as well as marine influences during the late Pleistocene to Holocene periods. Sediments from marginal basin environments have been selected for the study due to their connection to the open sea and terrestrial environments, …

Crop Rotational Diversity Enhances Belowground Communities And Functions In An Agroecosystem, L. K. Tiemann, A. Stuart Grandy, E. E. Atkinson, E. Marin-Spiotta, M. D. Mcdaniel

Faculty Publications

Biodiversity loss, an important consequence of agricultural intensification, can lead to reductions in agroecosystem functions and services. Increasing crop diversity through rotation may alleviate these negative consequences by restoring positive aboveground–belowground interactions. Positive impacts of aboveground biodiversity on belowground communities and processes have primarily been observed in natural systems. Here, we test for the effects of increased diversity in an agroecosystem, where plant diversity is increased over time through crop rotation. As crop diversity increased from one to five species, distinct soil microbial communities were related to increases in soil aggregation, organic carbon, total nitrogen, microbial activity and decreases in …

Ion Interactions At The Mineral-Water Interface During Biogeochemical Iron And Manganese Cycling, Margaret A. G. Hinkle

Arts & Sciences Graduate Student Theses and Dissertations

The biogeochemical cycling of iron and manganese involves the reductive dissolution and oxidative precipitation of Fe(III) and Mn(IV/III) oxides. Biogenic Fe(III) and Mn(IV/III) oxides are often characterized by high surface areas and therefore high sorptive capacities. As a result, these minerals can substantially alter the chemistry of natural waters and the availability of micronutrients in soils and sediments by scavenging trace metals. Recent research indicates that the adsorption of aqueous Fe(II) onto Fe(III) oxides involves oxidative adsorption, electron transfer, and subsequent reductive dissolution at another surface site [a process collectively referred to as `electron transfer-atom exchange' (ET-AE)]. Aqueous Mn(II) adsorption …

Possible Precursor Events To Earthquakes And The Resulting Effects On Organic Material In The Surrounding Water Bodies, Kiyoko Nakatsui

Student Scholar Symposium Abstracts and Posters

Being located on the “Ring of Fire” Japan experiences many seismic events. Adding to this, it is located at the convergence of four fault lines where seismic activity will be even more frequent and severe. Although small tremors occurring in an area are indicators of an earthquake to come it only gives minutes of warning. Scientists are now trying to see if latent heat and gas release from fault lines can indicate an earthquake to come with hours or even days of warning. MODIS aqua and terra data will be analyzed in order to see if such precursors can be …

Insomniac Of The Soil: A Collection Of Poetry And Essays, Sarah E. Golibart

Senior Honors Projects, 2010-2019

“Insomniac of the Soil” is a homage to a landscape that has deeply informed Sarah Golibart's life and her artistic voice – the tidewater flatlands of Virginia’s Chesapeake Bay peninsula where her family lives and where Golibart has worked on farms since high school. Both her poems and essays are earthy, imagistic, and grounded – quite literally – in the soil as well as in a sensibility of ecological ethics and sustainability. “Insomniac of the Soil” is also a love song to the fervent and fallow cycles of the soil.

Geochemical Analysis Of Surface Materials Surrounding The Bautsch-Gray Mine Superfund Site Near Galena, Illinois, Ryan Plath

Celebration of Learning

The Bautsch-Gray zinc and lead mine, near Galena, Ill., was in operation from the early 1900s until closing in 1975. The mine’s tailings pile has documented elevated lead and zinc concentrations in the surface materials surrounding the site. Numerous floods have caused contaminated sediment to migrate off the mine tailings pile, across Blackjack Road and into an outwash basin, and towards Smallpox Creek. Since this site was designated an EPA priority list superfund site in 2010, there have been numerous remediation efforts.

This study attempts to develop a better understanding of the contamination within the soils of the outwash basin …

Geochemical Analysis Of Surface Materials Surrounding The Bautsch-Gray Mine Superfund Site Near Galena, Illinois, Ryan Plath

Geology: Student Scholarship & Creative Works

The Bautsch-Gray zinc and lead mine, near Galena, IL, was in operation from the early 1900s until closing in 1975. The mine’s tailings pile has documented elevated lead and zinc concentrations in the surface materials surrounding the site. Numerous floods have caused contaminated sediment to migrate off the mine tailings pile, across Blackjack Road and into an outwash basin, and towards Smallpox Creek. Since this site was designated an EPA priority list Superfund site in 2010, the EPA has conducted numerous remediation efforts. This study attempts to develop a better understanding of the contamination within the soils of the outwash …

Stable Isotopes As A Tool To Characterize Carbon Cycling And Develop Hydrologic Budgets In Mantled Karst Settings, Katherine Knierim

Graduate Theses and Dissertations

Isotopes of water (δ2H/δ18O), carbon dioxide (δ13C-CO2), and dissolved inorganic carbon (δ13C-DIC) were used to explore water quality, trace carbon cycling, and quantify recharge sources through mantled karst and into Blowing Spring Cave (BSC). Of the possible sources of contamination in the BSC recharge area, septic-tank effluent was hypothesized to degrade water quality at the spring outlet of BSC because of the dominance of septic tanks for waste treatment, unsuitable topography and soil for septic-tank absorption fields, increased nitrate and chloride concentrations concomitant with increased urbanization, and increased Escherichia coli with discharge. Carbon cycling between the soil and BSC was …

Cockatoo Sands In The Victoria Highway And Carlton Hill Areas, East Kimberley: Land Capability Assessment For Developing Irrigated Agriculture, Henry Smolinski, Shahab Pathan, Paul Galloway, Kus Kuswardiyanto, Justin Laycock

Resource management technical reports

This report identifies areas of Cockatoo Sands adjacent to the Ord River Irrigation Area (ORIA), Kununurra, with high potential for developing irrigated agriculture. It builds on a reconnaissance soil survey conducted in 2009 which identified significant areas of sandy and loamy soils in the Kununurra area that could be suitable for agriculture.

Vegetative And Climatic Controls On Holocene Wildfire And Erosion Recorded In Alluvial Fans Of The Middle Fork Salmon River, Idaho, Kerry Riley, Jennifer Pierce, Grant A. Meyer

Geosciences Faculty Publications and Presentations

The Middle Fork Salmon River watershed spans high-elevation mixed-conifer forests to lower-elevation shrub-steppe. In recent decades, runoff from severely burned hillslopes has generated large debris flows in steep tributary drainages. These flows incised alluvial fans along the mainstem river, where charcoal-rich debris-flow and sheetflood deposits preserve a record of latest Pleistocene to Holocene fires and geomorphic response. Through deposit sedimentology and ¹⁴C dating of charcoal, we evaluate the processes and timing of fire-related sedimentation and the role of climate and vegetation change. Fire-related deposits compose ~66% of the total measured fan deposit thickness in more densely forested upper basins …

Characterization Of Uv-Quenching Dissolved Organic Matter In Landfill Leachate, Alicja Trzopek

Theses, Dissertations and Culminating Projects

Discharge of landfill leachate to publicly owned treatment works (POTWs) is a common and preferred practice in the United States. Namely, the leachate is mixed with municipal wastewater prior to traditional secondary wastewater treatment, including physical screening, primary settling, aerobic biological degradation, secondary settling and disinfection. Recently, ultraviolet (UV) light has been increasingly applied as a disinfection method at POTWs as an alternative for traditional chlorination, because the latter can produce unwanted disinfection byproducts. However, high strength dissolved organic matter (DOM) in leachate significantly increase the UV absorbing properties of the mixed wastewater at POTWs and decrease the disinfection efficiency …

An Assessment Of New Jersey Trout Production Systems : A Movement Towards Sustainability, Luke J. Diglio

Theses, Dissertations and Culminating Projects

New Jersey supports reproducing populations of three lotic salmonids. Only Brook Trout (Salvelinus fontinalis) are native and until approximately 100 years ago, were found in abundance throughout the northern part of the state. Presently, native populations have been documented in 115 streams or stream sections and declines are thought to be in response to anthropogenically originated environmental stressors. To evaluate the deterioration extent and assess numbers of breeding non-native Brown Trout (Salmo trutta) and Rainbow Trout (Oncorhynchus mykiss), comparisons are made between sets of historical (1968-1977) and modern (2001-2010) young-of-the-year presence/absence and abundance data …

A Study On Photodegradation And The Fate Of Pyrogenic Carbon, John Thomas Howell

Master's Theses

Accounting for all possible sources of atmospheric CO₂ is a pressing issue today due to the increasing effects of climate change. Estimates suggested that on the order of 1.3 million tons of dissolved pyrogenic carbon (pyDOC) could be entering the northern Gulf of Mexico annually. Assessing the fate of pyDOC in aquatic systems is crucial to understanding ecosystem impacts and potential feedback to climate change. Current research indicates that despite a generally lower susceptibility to biodegradation than their unpyrolyzed equivalents, pyrogenic carbon is not environmentally inert. While the role of microorganisms on the fate and transformation …

Effects Of Landscape Disturbances On Autotrophic Processes Within Arkansas Ozark Streams, Bradley J. Austin

Graduate Theses and Dissertations

Land-use change is one of the most widespread human impacts and can influence abiotic and biotic processes within surrounding streams. For example, streams in agricultural and urban watersheds receive greater light and nutrient inputs that can promote increased algal growth and primary production. Natural gas (NG) infrastructure development, a recent land use change in many regions, may also stimulate forested stream primary production, by reducing forest cover and increasing sediments and nutrient transport. I sampled streams across a NG activity gradient for algal biomass and gross primary production (GPP) to assess potential effects of this emerging land-use type. Algal biomass …

Rice Grain Yield And Nitrogen Uptake And Ammonia Volatilization From Urea As Affected By Urea Amendment And Simulated Rainfall, Randy Dempsey

Graduate Theses and Dissertations

The effect of rainfall between urea application and flood establishment on N loss and grain yield of rice (Oryza sativa L.) has not been studied. The first research objective was to compare the effects of simulated rainfall amounts and N-(n-butyl) thiophosphoric triamide (NBPT) urease inhibitor rate on NH3 volatilization and rice growth. Three field experiments were conducted and NH3 volatilization was measured in two experiments for 11 days after urea application (DAU) in semi-open chambers. Urea or NBPT-treated urea (NBPT-Urea) was subjected to six simulated rainfall amounts (0-25 mm) applied 5 to 15 h after urea application and flooded 7 …

Methane Emissions From Direct-Seeded, Delayed-Flood Rice Grown On A Clay Soil, Alden Daniel Smartt

Graduate Theses and Dissertations

Due to the production of methane (CH4) under flooded-soil conditions, rice (Oryza sativa L.) cultivation is a major contributor to agricultural CH4 emissions. Studies examining CH4 emissions from rice have only recently been initiated in Arkansas and no data have been collected from rice produced on clay soils in Arkansas. Therefore, research was conducted in 2012 and 2013 at the Northeast Research and Extension Center in Keiser, Arkansas to examine the factors affecting CH4 emissions from rice produced on a Sharkey clay (very-fine, smectitic, thermic Chromic Epiaquerts). The objectives of this study were to determine: 1) the effect of vegetation …

Hydrologic Mediation Of The Spatial And Temporal Variability Of The Soil Carbon Dioxide Stable Isotopic Composition Of A Subalpine Watershed, Theresa Marie Lorenzo

School of Natural Resources: Dissertations, Theses, and Student Research

The stable carbon isotopic composition of CO₂ (δ¹³C-CO₂) has been studied as an indicator of changes in ecosystem CO₂ exchange. Soil moisture is an important factor in ecosystem CO₂ exchange through its influence on physiological and soil physical processes. However, the majority of previous research analyzing the influence of soil moisture on soil and soil-respired δ¹³C-CO₂ has been conducted with limited consideration of topographical variation, which controls the distribution of soil moisture across a landscape. This study characterized the stable isotopic composition (δ¹³C) and concentrations of soil CO …

Naturally-Occurring Metals Concentrations In Michigan Soils: A 2015 Survey, Zachary Lowell Spotts

Masters Theses

Closure of hazardous waste sites can be aided through the use of a soil background survey for metals. Data for these studies come from either field sampling or publicly available environmental files. Previous studies were conducted in Michigan, known as the Michigan Background Soil Survey (MBSS). The current update is a refinement and improvement of the 2005 update. New data was collected from publicly available environmental files and other sources. Both the current update and the 2005 update differentiated data by soil type and glacial lobe. GIS analysis was used to observe spatial distribution of the data and to determine …

Recent Shoreline Erosion Rates Along Black River Bay, Jamaica: Erosion And Recovery After Hurricane Ivan In 2004, Karen Louise Zelzer

Graduate Theses/Dissertations

Rising sea level is threatening coastal areas, particularly those in the Caribbean which rely heavily on tourism and marine resources to support local economies. The purpose of this study is to analyze shoreline position along the south coast of Jamaica to determine the locations and rates of coastal change. IKONOS satellite imagery sets for 2003, 2007 and 2012 were used to monitor land use and shoreline changes along Black River Bay, including Galleon Beach Fish Sanctuary, in St. Elizabeth, Jamaica. In particular, the effect of Hurricane Ivan in 2004 on shoreline changes was evaluated. Erosion rates were significantly higher during …

Going With The Flow Or Against The Grain? The Promise Of Vegetation For Protecting Beaches, Dunes, And Barrier Islands From Erosion, Rusty A. Feagin, Jens Figlus, Julie C. Zinnert, Jake Sigren, Marisa L. Martínez, Rodolfo Silva, William K. Smith, Ashley Cox, Daniel Cox, Donald R. Young, Gregory A. Carter

Faculty Publications

Coastlines have traditionally been engineered to maintain structural stability and to protect property from storm‐related damage, but their ability to endure will be challenged over the next century. The use of vegetation to reduce erosion on ocean‐facing mainland and barrier island shorelines – including the sand dunes and beaches on these islands – could be part of a more flexible strategy. Although there is growing enthusiasm for using vegetation for this purpose, empirical data supporting this approach are lacking. Here, we identify the potential roles of vegetation in coastal protection, including the capture of sediment, ecological succession, and the building …

Using Geometric Morphometrics To Differentiate Lower First Molars Of Microtus Species: A Review Of The Clark’S Cave Bone Deposit, Va, Mark Shelleman

Electronic Theses and Dissertations

Clark’s Cave contains a large collection of late Pleistocene mammal material. In particular, it contains a sizable amount of Microtus spp. which can be valuable paleoclimate indicators. Identification techniques traditionally used to classify these species have been shown to be unreliable. Recent studies have shown that using geometric morphometric techniques on lower first molars can be more successful. By placing landmarks and running a discriminate analysis on new and previously collected material from the cave, significant differences in Microtus species proportions were found. Specifically, showing the deposit has a larger proportion of M. xanthognathus than previously reported; resulting in a …

Additional Research And Taxonomic Resolution Of Salamanders (Amphibia: Caudata) From The Mio-Pliocene Gray Fossil Site, Tn, Hannah E. Darcy

Electronic Theses and Dissertations

The Gray Fossil Site (GFS), a Mio-Pliocene (4.5–7 Ma) locality in the southern Appalachians, boasts the most diverse pre-Pleistocene salamander fauna in North America: Desmognathus sp., Plethodon sp., Notophthalmus sp., a Spelerpinae-type plethodontid, and Ambystoma sp. Because greater taxonomic resolution can result in more precise paleobiological interpretations, additional specimens were studied here. ETMNH 8045, a nearly complete articulated ambystomatid, appears most like Ambystoma maculatum in dentition and vertebral proportions. ETMNH 18219, an isolated vomer, is consistent with modern Pseudotriton and Gyrinophilus in possessing a postdentigerous process and a similar dentigerous row morphology. If these taxa, or species …

Trace Element Variations In A Stalagmite From Southwest Mexico: Implications For Paleoclimate, Chad Michael Crotty

UNLV Theses, Dissertations, Professional Papers, and Capstones

The combination of stable isotope and trace element concentrations in speleothems has been shown to be a valuable indicator for interpreting paleoclimatic conditions. Anomalous spikes in trace element concentrations have also been shown to indicate anthropogenic environmental changes to the surface, such as deforestation events. In this study, trace element concentrations (24Mg, 25Mg, 84Sr, 88Sr, 137Ba, and 238U) of a stalagmite (JX-6) from Juxtlahuaca Cave, in southwestern Mexico, were measured using an inductively coupled plasma mass spectrometer (ICP-MS). These trace element concentrations were compared to previously analyzed δ18O and δ13C values from JX-6, and to the results of previous studies …

Controls On Dissolution Rate Variation At A Pair Of Underflow-Overflow Springs At The Savoy Experimental Watershed, Kiefer Allen Vaughn

Graduate Theses and Dissertations

Physical dissolution experiments and numerical modeling have been used in the past to study limestone dissolution rates. Numerical models have typically used constant dissolution rates, whereas rates in nature vary in time. Limestone tablets allow natural estimation of rates over month time scales, but these rates cannot necessarily be extrapolated to geologic timescales and also do not aid our understanding of short term variability. This study characterizes natural variability in these rates and examines potential causes of that variability from first principles. This may enable more accurate projections of dissolution rates within models. This study combines measurement of physical and …

Digital Soil Mapping Using Landscape Stratification For Arid Rangelands In The Eastern Great Basin, Central Utah, Brook B. Fonnesbeck

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

In some parts of the western US there is limited publicly available soil information that can be used to make land management decisions on both public and private land. A goal of the USDI Bureau of Land Management (BLM) in Utah was to map an area in central Utah where such soil maps and value-added information was not available for management and restoration decisions following a wildfire. In 2007, the Milford Flat Fire had burned more than 363,000 acres, removing vegetation that was holding erosion-sensitive soils in place. Following inconsistent results from stabilization and restoration efforts, this study was funded …

Org Or Inorg? Atmospheric Carbon Controls That Initiated The Late Paleozoic Ice Age 326mya, Paco Defrancis

CLAS: Colby Liberal Arts Symposium

The Late Paleozoic Ice Age (LPIA) was a major global icehouse that initiated in the Mississippian (326 million years ago; ma) and lasted through the Early Permian (267ma). An ice sheet nucleated in southern Gondwana near the South Pole, which either paleogeography (positioning of paleocontinents) or atmospheric concentration of the greenhouse gas CO2 controlled. In this paper I accept recent findings that prove atmospheric pCO2 and not paleogeography forced global cooling that resulted in the nucleation of Gondwanan ice sheets that defined the LPIA. There remains no broad consensus of what caused pCO2 lowering in the Mississippian. Organic carbon found …

Mapping Regional Inundation With Spaceborne L-Band Sar, Bruce Chapman, Kyle Macdonald, Masanobu Shimada, Ake Rosenqvist, Ronny Schroeder, Laura Hess

Publications and Research

Shortly after the launch of ALOS PALSAR L-band SAR by the Japan Space Exploration Agency (JAXA), a program to develop an Earth Science Data Record (ESDR) for inundated wetlands was funded by NASA. Using established methodologies, extensive multi-temporal L-band ALOS ScanSAR data acquired bi-monthly by the PALSAR instrument onboard ALOS were used to classify the inundation state for South America for delivery as a component of this Inundated Wetlands ESDR (IW-ESDR) and in collaboration with JAXA’s ALOS Kyoto and Carbon Initiative science programme. We describe these methodologies and the final classification of the inundation state, then compared this with results …

Utilizing Remote Sensing Imagery To Monitor Vegetation Change Within World Heritage Sites, Mimi Eve Hatzis

Theses and Dissertations

ABSTRACT

World Heritage sites provide a glimpse into the stories and civilizations of the past. There are currently 1007 unique World Heritage properties with 779 being classified as cultural sites, 197 as natural sites, and 31 falling into the categories of both cultural and natural sites (UNESCO & World Heritage Centre, 1992-2015). However, of these 1007 World Heritage sites, at least 46 are categorized as in danger and this number continues to grow. These unique and irreplaceable sites are exceptional because of their universality. Consequently, since World Heritage sites belong to all the people of the world and provide inspiration …

Deposition And Characteristics Of West Bay Sediment In The Mississippi River Delta, And The Effects Of Polymers On Sediment Erodibility, Patrick Robichaux

Honors Capstones

No abstract provided.