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Molecular Catalysts For Electrochemical Nitrogen Activation Toward Sustainable Ammonia Synthesis, Jin-Xiu Han, Hao Xue, Xian-Biao Fu

Journal of Electrochemistry

Homogeneous electrocatalytic nitrogen reduction reaction (NRR) provides a powerful framework to interrogate molecular nitrogen-fixation pathways under mild conditions. By tuning the metal center, ligand architecture, and reaction medium, these systems enable capturing key intermediates and delivering mechanistic insight at the molecular-level resolution. Nevertheless, advances remain constrained by highly reduced operating potentials, intense competition from the hydrogen evolution reaction (HER), limited durability in turnover, and inadequate long-term stability.

In this review, we take electron delivery to the molecular active site as the guiding principle for organizing homogeneous electrochemical N₂ activation and transformation. We classify reported systems into direct electron transfer …

Water-Driven Solid Electrolyte Interphase Governs Continuous-Flow Ammonia Electrosynthesis, Peng-Bo Liu, Sheng-Liang Zhai, Ji Huang, Zhong-Shuo Zhang, Jie Zeng, Shao-Feng Li

Journal of Electrochemistry

Flow-cell architectures have emerged as a powerful platform for continuous and stable lithium-mediated nitrogen reduction (Li-NRR), enabling ambient-condition electrochemical ammonia synthesis and offering a promising alternative to Haber-Bosch processes. However, Li-NRR is exceptionally sensitive to trace water, and even minor variations in water content can profoundly alter interfacial chemistry. Here, we systematically investigate how initial water concentration affects Li-NRR performance in a continuous-flow cell. Excess water drives the formation of a thick solid electrolyte interphase (SEI) layer, which may impede nitrogen access to metallic lithium and hinder lithium-ion transport. As a result, the ammonia Faradaic efficiency collapses from ~61% to …

A Comparative Study Of Tin Electrorefining In Molten Licl–Kcl–Cacl₂: Experimental Two-Electrode Current Control And Theoretical Three-Electrode Potential Control, Bryant Johnson, George Ankrah, Ander Fuller, Devin Rappleye

Reviews, Analyses, and Instructional Studies in Electrochemistry (RAISE)

Molten salt electrorefining is a mature technology for metal recovery, yet conventional current‑controlled, two‑electrode operation provides limited electrochemical selectivity and restricted insight into electrode‑specific behavior. In this work, a simplified model is developed to compare current‑controlled two‑electrode electrorefining data with a potential‑controlled three‑electrode electrorefining simulation using tin in molten LiCl–KCl–CaCl₂ as a surrogate for plutonium processing. The model examines anodic and cathodic limitations under fixed‑potential operation and evaluates implications for selectivity, efficiency, and runtime relative to experimentally demonstrated two‑electrode performance. Results indicate that independent potential control enables operation closer to thermodynamic selectivity limits, with the potential to suppress impurity oxidation …

Targeting Chemical Pollutants Through Assimilation Of Hydrophobic Deep Eutectic Solvents With Metal-Organic Frameworks, Carbon Nanotubes, And Activated Carbon, Tanner William Baughman

ONU Student Research Colloquium

Water contamination by heavy metals has a harmful human threat to the environment and to human health. This is derived from their bioaccumulation and toxicity characteristics. The study directly looks at the assimilated of lignin-derived hydrophobic deep eutectic solvents (HDES) with 3 different class of materials: Metal-Organic Frameworks (MOFs), Carbon Nanotubes (CNTs), and Activated Carbon (AC). Four different HDES mixtures were assimilated into these porous materials through impregnation. Composites were evaluated by characteristic peaks through Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR). The morphology of the samples was assessed as well through scanning electron microscopy (SEM). The colloidal stability …

Large-Scale Production Of Polyethylene Furanoate From Algae- Derived Feedstocks, Anjolaoluwa Buraima, Jasmine Gordon, Christian Jung, Brianna Oropeza

Chemistry and Chemical Engineering Student Publications

This work presents a process to convert microalgal feedstocks (Chlorella vulgaris) into Polyethylene Furanoate (PEF), a biobased alternative to Polyethylene Terephthalate (PET) with improved barrier properties, proving a sustainable pathway for bioplastic production.

Photochemical Activation Of Cyanine-Based Nanogels For Controlled Drug Delivery, Presley Clary

Chemistry and Chemical Engineering Student Publications

Cyanines are highly conjugated molecules with useful properties, such as ease of aggregation and fluorescence. In this project, they were incorporated into an acrylamide-based nanogel made through organic synthesis to exploit these properties for controlled drug delivery. Exposing the nanogel to nearinfrared (NIR) light causes it to react with reactive oxygen species (ROS), forming an unstable intermediate. The intermediate splits into two fragments, releasing the nanogel's cargo.1 The cargo, temozolomide, is an alkylating agent which can be used to disrupt the DNA of cancer cells.

Comparative Phytochemical And Antioxidant Analysis Of Acalypha Wilkesiana Extracts Using Different Solvents, Tj Cataloni, Victor Chibuzor Johnson, Gabrielle Depowski

Chemistry and Chemical Engineering Student Publications

Medicinal plants are a rich source of bioactive compounds with therapeutic potential. Antioxidants play a critical role in combating oxidative stress associated with chronic diseases. The extration of these compounds depends on solvent polarity, affecting yield and composition. Acalypha wilkesiana provides an excellent model for such studies. This work presents an evaluation of phytochemical content and antioxidant activity of A. wilkesiana extracts obtained using solvents of varying polarity.

Thiocoumarin As A Photocaging Scaffold: Synthesis And Light- Triggered Release, Angelina Gaffey, Gabrielle Depowski, Victor Johnson

Chemistry and Chemical Engineering Student Publications

Photocaging involves inhibiting a molecule’s function with a photolabile protecting group (PPG), allowing for precise spatiotemporal control and release of the molecule in vivo. Photocages which respond to UV light upon single photon irradiation have limited use in vivo due to cytotoxicity. Thiocoumarin is a promising photocage which absorbs in the visible light region and can cage multiple essential neurotransmitters, such as GABA and glutamate. In addition, thiocoumarin can be easily tracked through live cells due to its persistent fluorescence throughout the caging process. In this project, GABA was utilized to explore the properties of thiocoumarin as a light-triggered photocage.

Non-Isocyanate Polyurethanes From Kraft Lignin, Savannah Madairy, Ayden Weil, Eric Huynh, Elliott Bischof

Chemistry and Chemical Engineering Student Publications

Adhesives from isocyanate polyurethanes have strong bonding properties yet pose serious health risks in both production and daily life. Kraft Lignin, a common organic waste, contains the functional groups that can make a renewable alternative and replace isocyanate’s role in adhesives. Our production plant will be placed in Rome, Georgia attached to an existing paper mill with competitive pricing of 26.47$/kg. Our three-step process proposes a sustainable approach to producing polyurethane adhesives without incorporating isocyanates.

Sustainable Ethanol Production From Agricultural Waste, Eva Shealy, Bre Venditti, Muath Alharbi, Jacob Dymock

Chemistry and Chemical Engineering Student Publications

This project presents a commercial-scale process which converts waste corn stover into fuel grade ethanol through syngas fermentation. By integrating thermochemical conversion with microbial processing, the design explores an innovative pathway for ethanol production, resulting in a lower-impact alternative to traditional processes.

Photoswitchable Metal Chelators, Rhea Sharma

Chemistry and Chemical Engineering Student Publications

Develop a light-responsive chelator that switches between OFF and ON metal-binding states, enabling spatiotemporal control of metal coordination.

High Performance Ae-Cnn Model Enhanced Via Gaussian Augmentation For Rssi-Dependent Indoor Positioning In Wireless Sensor Networks, Kahlaa K. Al-Nassrawy, Ghaidaa A Al-Sultany

Karbala International Journal of Modern Science

Precise indoor positioning system remains a significant challenge within Wireless Sensor Networks (WSNs) due to the instability and noise sensitivity of Received Signal Strength Indicator (RSSI) data. This paper proposes an advanced hybrid deep learning framework designed for 2D indoor localization, utilizing RSSI measurements to predict human or object position. Furthermore, to enhance the robustness of the model against signal variance and promote its generalization capability under this uncertainty, a data augmentation strategy is applied using three methods: Gaussian Noise Injection (GNI), Gaussian Mixture Model (GMM), and Bayesian Gaussian Mixture Model (BGMM). The purpose of data augmentation is to simulate …

Investigating The Bioactivity Of Novel Β-Diketonate Complexes, Celeste Remolina, Dylan Wolfe

Research & Creative Achievement Day

Ruthenium β-diketonate complexes have emerged as promising chemotherapeutics due to their selective bioactivity against tumors. We assessed the bioactivity of novel synthesized ruthenium β-diketonate complexes on human cancer cells as well as wild-type cells. Using cell growth assays, we screened candidate ruthenium complexes and determined the IC50 value for effective candidates. Here we present a model for ruthenium-mediated growth inhibition

Using Fluorimetry And Spectroscopy For Quantitative Analysis Of Biomaterial-Derived Carbon Dots, Kahun N. Vue

Research & Creative Achievement Day

Carbon Dots (CDs) are renowned for having great quantum yield, absorption, electron transfer, and stability. Biomaterial-derived carbon dots are eco-friendly nanomaterials synthesized through the carbonization and condensation of organic surface groups. This study investigates the synthesis, characterization, and application of CDs derived from various biomaterial precursors, including chitosan, cellulose, β-keratin, α-keratin, and amylose derived from chitosan, corn husk, chicken feathers, human hair, and potato skin respectively. Hydrothermal and purification methods were used to develop a green, cost-effective synthesis while evaluating the eco-friendliness and sustainability of the resulting nanomaterials. The physicochemical properties of each CD were evaluated based on fluorescence intensity, …

Computational Investigation Of Ruthenium Complex Interactions With Dna For Anticancer Applications, Mikayla A. Ertz

Research & Creative Achievement Day

Ruthenium complexes are being studied as potential alternatives to platinum-based cancer drugs because they are often less toxic and more selective for cancer cells. This project uses computational modeling to investigate how a ruthenium complex interacts with DNA, which is an important target for anticancer activity. All simulations were performed using the MSI Agate supercomputing system through Termius. The complex was first tested in the major groove of DNA with and without a leaving group, followed by the same set of simulations in the minor groove. Binding energies were analyzed to compare interaction strength and determine how groove position and …

Co-Precipitation Synthesis Of Magnetic Nanoparticles (Mnps) Fe3o4 And Their Photocatalytic Performance, Leo Doan, Natalie R. Chouinard, Kahun N. Vue

Research & Creative Achievement Day

Iron oxide nanoparticles (NPs) were prepared and evaluated for their photocatalytic activity in degrading methylene blue (MB). MB is widely used in different industries and is difficult to remove from waste due to the benzene groups, so the removal of MB becomes an emergency problem. Magnetic nanoparticles (MNPs), Fe3O4, were successfully synthesized using a co-precipitation method between FeCl3.6H2O and FeCl2.4H2O. The point of zero charge (PZC) was determined to be approximately at pH 6.37. The NPs were examined under UV light irradiation, and their catalytic activity was monitored using UV-Vis spectroscopy. The λmax of MB was determined to be approximately …

Deep Tissue Massage-Induced Muscle Damage Associated With Delayed Onset Muscle Soreness (Doms), Stress, And Rhabdomyolysis, Lily M. Ekert, Ella R. Halopka, Micah Maddio, Marisa Wood, Bailey Kerkow, Logan Murphy, Ashley Wise

Research & Creative Achievement Day

Deep tissue massage is a common treatment method used to aid in muscle recovery, reduce pain, and promote overall physical well-being. However, there is limited research explaining its biochemical effects at a cellular level, particularly in relation to muscle damage and systemic inflammation. Severe cases of muscle tissue breakdown are Rhabdomyolysis, which is discussed with an emphasis on clinical evidence rather than biochemical aspects. The goal of this study is to determine whether deep tissue massages cause cellular damage and tissue inflammation. This testing will be done through quantitative measurements of biomarkers within the bloodstream. In previous studies, four specific …

Purification And Investigation Of Bromelain Enzyme From Pineapple, Elsie J. Dahnert, Leah O. Hanson, Regan E. Stafanoni, Reyna Olson, Eion D. Hinkle, Muaj-Infinite S. Yang

Research & Creative Achievement Day

Bromelain proteins are a group of digestive protease enzymes that act as a chemical defense to prevent grazing. Bromelain is often taken as a dietary supplement in an attempt to support digestion, and it is used as a meat tenderizer in the restaurant industry. Extracting Bromelain from pineapple, especially the skin, leaves, and stem of the plant, can create a value-added product from what is widely considered to be agricultural waste. In this research, we examined the difference in Bromelain concentrations between the flesh of the pineapple and the skin, leaves, and stem of the pineapple, and the efficacy of …

Vanadium’S Journey From Essential Trace Metal To Emerging Environmental Pollutant In The Anthropocene Era, Tanu Arora, Nivedita Agnihotri, Mohammad Azam

Turkish Journal of Chemistry

Vanadium, previously considered a minor trace element, is gaining global environmental attention due to its expanding applications in metallurgy, energy storage, catalysis, and agriculture. With this rise in its industrial and technological uses, however, anthropogenic emissions of vanadium into the atmosphere, soils, and water bodies have also escalated. Unlike many heavy metals, vanadium exhibits complex redox behavior, primarily existing as V(IV) and V(V) species, which significantly impacts its environmental mobility, bioavailability, and toxicity. Vanadium exhibits complex behavior that necessitates an integrated research approach to better understand its various roles in scientific fields. This review summarizes the current knowledge on vanadium’s …

Computational And Experimental Analysis Of Oleanolic Acid As An Allosteric Activator Of Sirt1, Emrah Sariyer, Eda Dokumacioğlu, Hati̇ce İskender

Turkish Journal of Chemistry

Sirtuin 1 (SIRT1) is a member of the sirtuin protein family and the biological effects of SIRT1 encompass various areas such as the ageing process, metabolism regulation, and cellular stress response. SIRT1 activators are compounds that enhance the activity of SIRT1 enzyme. These activators can be natural or synthetic compounds and have the potential to provide health benefits by augmenting the biological effects of SIRT1. Oleanolic acid (OA) is a triterpenoid compound that has antiinflammatory, antioxidant, and glucose and lipid metabolism-regulating properties naturally found in many plants. The aim of the present study was to investigate the effect of OA …

Synthesis Of Werner- And Werner-Like-Type Clathrates, Their Characterization, And Theoretical Calculation Of Their Properties, Zari̇fe Si̇bel Şahi̇n, Zeki̇ Kartal

Turkish Journal of Chemistry

In this paper, the synthesis and structural characterization of three new coordination compounds in crystal structure consisting of a nickel atom, varying numbers of 3-aminopyridine molecules, and two isothiocyanate ion ligands are presented. The crystal structures of these compounds were determined by single crystal X-ray diffraction. Consequently, the explicit formulas and shorthand notations of the compounds are [Ni(NCS)2(C5H6N2)2(H2O)]·(H2O) (1), [Ni(NCS)2(C5H6N2)3]·(C2H6) (2), and [Ni(NCS)2(C5H6N2)4]·2(C5H6N2) (3). The consistency of the crystal structure data was confirmed by elemental analysis and infrared spectroscopy. These coordination compounds are Werner-like-type clathrates containing water, ethane, and 3-aminopyridine molecules as guest molecules in their structures, respectively. According to …

Investigation Of The Enzyme-Inhibitory, Antibacterial, And Anticancer Properties Of Metal Phthalocyanines, Meryem Topal, Fevzi̇ Topal, Firat Yilmaz, Esra Bulut Atalay, Ümi̇t Muhammet Koçyi̇ği̇t, Emre Güzel

Turkish Journal of Chemistry

In this study, the enzyme inhibitory, antibacterial, and anticancer activities of a phthalonitrile derivative and its metal phthalocyanines (Pcs; indium, zinc, copper, cobalt, and manganese; 1–6) were investigated. The cobalt and manganese Pcs were synthesized for the first time in this study. The inhibitory activities of the symmetric Pcs, which were expected to interact with acetylcholinesterase (AChE) and butyrylcholinesterase (BChE) via their 4-(isopropylbenzyl)oxy substituents through host–guest interactions, were investigated. More selective inhibition of AChE than BChE was observed for these compounds. For AChE, CoPc was identified as the most potent inhibitor (IC50 = 14.81 nM), whereas for BChE, InPc was …

Templating Effect Of Neutral Dithiane Ligands On The Self-Assembly Of Cationic Au(I)-Phosphine Units, Farzane Osanlou, Abdollah Neshat, Mohammad Reza Yousefshahi, Vaclav Eigner, Michal Dusek, Shahram Seidi

Turkish Journal of Chemistry

The interactions between the dinuclear Au(I) precursor (dppm)Au2Cl2 and neutral sulfur-containing dithianes (specifically 1,3- and 1,4-dithiane) were examined in the presence of NH₄PF₆. Although these sulfur-based ligands were initially employed to facilitate the formation of mixed phosphine/sulfur Au(I) complexes, single-crystal X-ray diffraction analysis revealed the unexpected generation of multinuclear Au(I) assemblies exclusively coordinated by phosphine ligands. When 1,3-dithiane was present, a trinuclear Au(I) complex was isolated, characterized by a central four-coordinate Au(I) center exhibiting a distorted see-saw geometry, flanked by two terminal Au(I) centers with T-shaped coordination environments. Importantly, the dithiane ligand did not coordinate directly to the gold centers …

Influence Of Precursor Synthesis Temperature And Hydrothermal Alkaline Medium On Agglomeration And Crystal Phase Of Barium Titanate Nanoparticles, Murat Özen

Turkish Journal of Chemistry

Phase‑pure, cube‑like barium titanate (BaTiO3) nanoparticles were synthesized via hydrothermal treatment of a single‑source barium-titanium peroxo-hydroxide precursor. Precursor solutions prepared at room temperature, 0 °C, and –10 °C with various storage times exhibited Ba/Ti molar ratios ranging from 0.66 to 1.05 as determined by X-ray fluorescence. Cooling the precursor solution to –10 °C effectively suppressed the polymerization of Ti-O-Ti, yielding near‑ideal stoichiometry and finer precursor particles. Subsequent hydrothermal processing in NH4OH, KOH, and NaOH (0.5–10 M, 100–200 °C) revealed the strong dependence of agglomeration and morphology on the alkaline medium. While NH4OH and KOH resulted in severe agglomeration and the …

Uptake And Fate Of Silver And Zinc Engineered Nanoparticles In Maize Under Single And Binary Dosing Soil Ecosystems, Lei Xu, Qingbo Yang, Xingmao Ma, Honglan Shi, John Yang, Hu Yang, Samira Mahdi, Ying Wang, Young Shin Jun

Chemistry Faculty Research & Creative Works

Recent agricultural applications of engineered metallic nanoparticles (ENPs) have raised concerns about their uptake and fate in plants. To understand this critical issue, this study investigated the fate and uptake of silver (Ag) and zinc oxide (ZnO) ENPs in maize (Zea mays L.) after single or binary ENP exposure in soil. Results indicated that both Zn and Ag elemental concentrations in roots increased with increasing ENP dosage. Ag NPs in the tissues were detected, but not Zn NPs. Ag NP concentration was 3 times higher in the roots than in the shoots at low Ag NP dosing, while Ag NP …

Techno-Enviro-Economic Analysis Of Precipitated Calcium Carbonate Production From Carbon Dioxide In Cement Industry Flue Gas And Calcium Hydroxide, Natalia Debora Panggabean, Widodo Wahyu Purwanto

Journal of Materials Exploration and Findings

CCUS is a technological solution to reduce emissions from the cement industry, which is the second largest CO2-intensive industry. This study aims to analyze technical, economic, and environmental performance of Precipitated Calcium Carbonate (PCC) synthesis in cement industry flue gas. The process simulation includes the CO2 capture system from cement plant, CO2 captured used as feedstock for PCC synthesis process through its reaction with calcium hydroxide. The simulation was carried out using ASPEN Plus software. Technical analysis was performed to determine the CO2 capture efficiency and PCC synthesis efficiency. Economic analysis was conducted to calculate CO2 capture cost and production …

Feasibility Analysis Of Thermal Oxidizer To Determine Remaining Life Using Fitness- For-Service Level 3 Method, Yudhi Yudistirawan, Donanta Dhaneswara, Wahyuaji Narottama Putra, Gama Widyaputra, Dewi Kurnia Suci, Agung Putra Mahardhika

Journal of Materials Exploration and Findings

An aged thermal oxidizer (TOX) in the oil and gas industry necessitates a comprehensive evaluation to ensure its continued safe operation. This study presents a Remaining Life Assessment (RLA) and a Fitness for Service (FFS) evaluation for the four main components of the TOX, in accordance with API 510, API 579/ASME FFS-1, and ASME BPVC Section VIII Div-1 standards. The investigation includes the determination of maximum stress and maximum temperature required to assess the operational viability of the reactor. The four components are radiant, convection, transition, and stack sections—were modeled using the finite element method (FEM). Following the geometric modeling, …

Assessing Passenger Electric Vehicle Growth Strategies And Their Impacts On Electricity Demand Load And Co2 Emissions In Aceh Province To Achieve Net Zero Emission Target By 2060, Taufik Hidayat, Widodo Wahyu Purwanto

Journal of Materials Exploration and Findings

The electrification of the transport sector is a crucial pathway for achieving Indonesia’s Net Zero Emissions (NZE) target by 2060. This study assesses the potential impact of passenger electric vehicle (EV) penetration on electricity demand and CO2 emissions in Aceh Province through a scenario-based modelling approach. Two policy-aligned scenarios are assessed: a low-penetration (LP) scenario and a high-penetration (HP) scenario. Using the Gompertz model and the ASIF framework, total CO2 emissions were projected from 2020 to 2060. Results show that although higher EV penetration reduces direct emissions from internal combustion engine (ICE) vehicles, total CO2 emissions increase more significantly under …

Czts Nanoparticles As Cost Efficient Catalysts For Producing Green Hydrogen, Aidan Hau

Undergraduate Research Symposium (2026- )

Hydrogen gas is produced to be used as feedstock, fertilizer, and fuel. Traditional hydrogen production produces “gray hydrogen” in a process that uses and releases fossil fuels into the atmosphere. One way to produce “green” hydrogen is with renewable energy technologies that produce hydrogen gas using electrolysis without emitting fossil fuels. In electrolysis, the hydrogen atoms bonded to oxygen in a water molecule are split to produce hydrogen. A typical catalyst for this process would be a precious metal like palladium, which can be costly. In order to make green hydrogen production more affordable, an alternative catalyst composed of CZTS …

Electroenzymatic Cascades For Nitrogen Upgrading: Beyond Ammonia Towards Value-Added Nitrogen Chemicals, Rohit G. Jadhav, Vamshi Krishna Kamaja, Wassim El Housseini, Monica Brachi, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

The global transition toward sustainable chemical manufacturing demands technologies that leverage natural carbon and nitrogen cycles while minimizing reliance on sacrificial reagents and fossil resources. These biogeochemical cycles are fundamental to life, and enzymes catalyze many of their key transformations. Bio electrochemical, specifically electroenzymatic, systems offer a promising route to sustainable synthesis by enabling selective redox transformations powered by electricity. However, whereas carbon-cycle enzymes are now well established in bio electrochemical synthesis, enzymes from the nitrogen cycle remain comparatively underexplored. Moreover, the nitrogen cycle alone does not access many value-added nitrogen-containing products, which require additional C-N bond formation and organic …