Digital Commons Network^™

Aphasia After Left Thalamic Infarction, Philip B. Gorelick, Daniel B. Hier, Louis Benevento, Susan Levitt, Walter Tan

Chemistry Faculty Research & Creative Works

We Examined a 70-Year-Old Woman Who Became Aphasic after a Left Thalamic Infarction. Computed Tomographic Scan Showed Injury that Was Largely Limited to the Ventral Anterior and Rostral Ventral Lateral Thalamic Nuclei. Speech Was Characterized by Reduced Voice Volume, Impaired Auditory and Reading Comprehension, Perseverations, Intermittent Use of Jargon, Fluctuations in the Ability to Perform Confrontation Naming, Extraneous Intrusions, Verbal Paraphasia, Intact Repetition Skills, and Fluent Speech that Was Laconic But Grammatically Correct. We Propose that the Deficits after Left Thalamic Injury Can Be Grouped into the Following Four Large Clusters: Extrapyramidal Deficits (Decreased or Fading Voice Volume), Deficits in …

Alignment Of A Nonaqueous Lyotropic Liquid Crystalline Phase With Lecithin, David W. Larsen, Shankar B. Rananavare, Stig Friberg

Chemistry Faculty Research & Creative Works

No abstract provided.

A Study Of Oxygen Functional Groups In Illinois Coal Fractions, Kenneth R. Osborne

Masters Theses

Ferric chloride/acetic anhydride reacted with butyl phenyl ether in acetonitrile at 80° to give a 75.6% yield of p-butoxyacetophenone. Reactions with benzyl aryl ethers gave 30% cleavage. The reaction of benzyl phenyl ether gave 10.3% p-benzyloxyacetophenone as well as cleavage product. Reaction of a pyridine soluble, toluene insoluble fraction (preasphaltene) of an Illinois No. 6 coal with ferric chloride/acetic anhydride in acetonitrile gave a product 94% insoluble in pyridine. The insolubility was ascribed to condensation reactions.

Phenols were measured in coals, preasphaltenes and preasphaltene derivatives by acetylation with acetic anhydride in pyridine. Suggestions for improvement in the method were presented. …

Plasma Polymerization Of Tetramethyldisiloxane By A Magnetron Glow Discharge, Ashok K. Sharma, H. Yasuda

Chemistry Faculty Research & Creative Works

Plasma polymerization of tetramethyldisiloxane by a magnetron glow discharge was studied. The glow discharge was created between parallel electrodes with a 10 kHz electric power source with a superimposed magnetic field using permanent bar magnets. Polymers were deposited onto moving substrates placed on the surface of a rotating disc located in between the electrodes. The deposition rates were determined with a quartz crystal thickness monitor placed on the plane of the rotating disc and just outside the edge of the disc. The current-voltage relationship observed for plasma polymerization of the monomer depends on the monomer feed rate and the conditioning …

Electrical Properties Of Plasma-Polymerized Thin Organic Films, Maciej Gazicki, H. Yasuda

Chemistry Faculty Research & Creative Works

The electrical properties of plasma-polymerized films are summarized and compared to those of conventional polymers. Particular attention is devoted to the dielectric relaxation, dielectric breakdown, electric conductivity and photoconductivity, and their control via control of the plasma parameters. © 1983 Plenum Publishing Corporation.

25th Rocky Mountain Conference

Rocky Mountain Conference on Magnetic Resonance

Abstracts and meeting program from the 25th annual meeting of the Rocky Mountain Conference, co-sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy and the Rocky Mountain Chromatography Discussion Group. Held in Denver, Colorado, August 14-17, 1983.

Transport Properties Of Ground State Nitrogen Atoms, James C. Rainwater, Louis Biolsi Jr., Kevin J. Biolsi, Paul M. Holland

Chemistry Faculty Research & Creative Works

Transport properties of dilute monatomic gases depend on the two body atom-atom interaction potential. When two ground state (⁴S) nitrogen atoms interact, they can follow any of four potential energy curves corresponding to the N₂ molecule; the X ¹Σ⁺_g, A³Σ⁺_u, ⁵Σ⁺_g, and ⁷Σ⁺_u curves. Transport collision integrals for the ¹Σ⁺_g and ³Σ⁺_u states have been calculated by representing the potentials for these states with the Hulburt-Hirschfelder potential. The⁵Σ⁺_g state has a …

Photochemical Energy Storage (Photosensitized Isomerization Of Norbornadiene To Quadricyclane By Copper(I) Complexes), Dennis J. Fife

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This research has focused on the sensitized photoisomerization step of a solar energy storage system based on the interconversion of norbornadiene (NBD) and quadricyclane (Q). Sensitizers studied in the photoisomerization were arylphosphine complexes of copper(I) halides [(Ph₃P)₃CuX, (MePh₂P)₃CuX, (DIPHOS)CuCl; X = Cl, Br, I and DIPHOS = Ph₂P(CH₂)₂PPh₂]. The lowest electronic excited state of the complexes can be an effective triplet energy sensitizer as evidenced by a maximum quantum yield of 1.0 with (MePh₂P)₃CuX. The sensitization mechanism of the L …

Chemistry, Norman Kulevsky

UND Departmental Histories

This departmental history was written on the occasion of the UND Centennial in 1983.

Use Of Hydroelectric Dams To Control Evaporation And Salinity In The Colorado River System, Larry J. Paulson

Publications (WR)

The main stem reservoirs on the Colorado River comprise one of the largest and most heavily used freshwater bodies in the nation. These reservoirs (Lake Powell, Lake Mead, Lake Mohave and Lake Havasu) can store up to 53,590,400 acre-feet of water at their maximum capacities. Nonetheless, local water shortages still exist in some areas of the Colorado River Basin. There is also concern that salt concentrations are approaching levels that could severely affect municipal and agricultural uses. Water shortages will become even more acute as demands for water increase with continued urban and agricultural development in the basin. Water conservation …

The Effects Of Impoundments On Salinity In The Colorado River, Larry J. Paulson, John R. Baker

Publications (WR)

The increase in salinity of our western rivers has been identified as one of the most serious water quality problems in the nation. This is of special concern in the Colorado River where salinity has increased from pristine levels estimated at 380 mg/1 to present-day levels of 825 mg/1 at Imperial Dam. Flow depletions, associated with decreased runoff and increased evaporation and diversions, coupled with high salt loading from natural and man-created sources are considered the primary causes for rising salinity in the river. The urban and agricultural development projected to occur in the basin through this century could deplete …

Role Of D Functions In Ab Initio Calculation Of The Equilibrium Structure Of H2s–Hf, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Full geometry optimizations are performed to determine the equilibrium geometry of the hydrogen‐bonded complex H₂S–HF. The angle between the plane of the H₂S moiety and the H‐bond axis calculated with the 4–31 G basis set is 106° as compared to the experimental value of 91±5°. This quantity is reduced significantly when d orbitals are added to the basis set, yielding an angle within experimental error of 91°. (AIP)

Evaluation Of A New Silicone-Methane Polymer Contact Lens, Jeffrey E. Koziol, Gholam A. Peyman, Hirotsuga Yasuda

Chemistry Faculty Research & Creative Works

A new gas permeable contact lens is produced using a solid silicone core and a plasma polymer surface. This surface is hydrophilic and impermeable to macromolecules. The surface characteristics of this lens were compared with the surface characteristics of available silicone contact lenses. We found that in contrast to our lens, the silicone contact lenses lost their hydrophilic surface with time. In addition, they are permeable to lipid dyes, eg, Sudan red. © 1983 Arch Ophthalmol All rights reserved.

Thermal Decomposition Kinetics Of Iodine‐Doped Polyacetylene In Vacuum, J. ‐E Osterholm, H. Yasuda, L. L. Levenson

Physics Faculty Research & Creative Works

The thermal stability of iodine‐doped polyacetylene films, (CHIy)x, has been studied by means of electrical conductivity measurements, measurements on weight loss, and mass spectrometric analysis of desorbing species. When heated between room temperature and 125°C in vacuum, these films proved to be of poor thermal stability, being unstable at temperatures above 20°C. During the thermal treatments, molecular iodine desorbs from the films, resulting in an appreciable dopant weight loss with accompanying decrease in the electrical conductivity. The decomposition process does not follow simple kinetics. Copyright © 1983 John Wiley & Sons, Inc.

Oxidation Activity Of Catalyst 3-7a Toward Formaldehyde, Hydrogen Cyanide, And Some Alkane Gases, John Kawas

Masters Theses & Specialist Projects

The activity of Catalyst 3-7A toward the oxidation of formaldehyde, hydrogen cyanide, methane, propane, and isobutene was examined at temperatures between 25°C and 400°C. The catalyst consists of palladium(II) and copper (II) salts impregnated on an alumina support. The oxidation measurements were made primarily with gas chromatographs, although form aldehyde and hydrogen cyanide were also examined using the colorimetric fushsin method and Liebig titrations, respectively. Catalyst 3-7A demonstrated appreciable activity toward the oxidation of all gases studied except formaldehyde where there was no evidence of oxidation. The latter result is quite unexpected since aldehydes are more easily oxidized than alkanes. …

24th Rocky Mountain Conference

Rocky Mountain Conference on Magnetic Resonance

Abstracts and meeting program from the 24th annual meeting of the Rocky Mountain Conference, co-sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy and the Rocky Mountain Chromatography Discussion Group. Held in Denver, Colorado, August 1-5, 1982.

Binary Collision Dynamics And Numerical Evaluation Of Dilute Gas Transport Properties For Potentials With Multiple Extrema, James C. Rainwater, Paul M. Holland, Louis Biolsi

Chemistry Faculty Research & Creative Works

Prediction of gaseous transport properties requires calculation of Chapman-Enskog collision integrals which depend on all possible binary collision trajectories. The interparticle potential is required as input, and for a variety of applications involving monatomic gases the Hulburt-Hirschfelder potential is useful since it is determined entirely from spectroscopic information and can accomodate the long-range maxima and minima found in many systems. Hulburt-Hirschfelder potentials are classified into five distinct types according to their qualitative binary collision dynamics, which in general can be quite complex and can exhibit “double orbiting”, i.e., a pair of orbiting impact parameters for a single energy of collision. …

Development Of An On-Line Computer System For Enzyme Kinetics Studies, Jacqueline R. Thweatt

Chemistry & Biochemistry Theses & Dissertations

The PDP-11/10 minicomputer was interfaced to the Beckman 25 ultraviolet/visible spectrophotometer and this on-line computer system was applied to enzyme kinetics studies. This interface involved hardware equipment to locate, amplify, and transmit the analog signal to an analog-to-digital converter, and software to acquire and store the digital data. Data processing programs were used to calculate kinetic parameters and statistical information from the acquired data.

The Varian Cary 219 ultraviolet/visible spectrophotometer can be readily interfaced to the Apple II Plus microcomputer by hardware equipment which can be purchased from the manufacturer. Various software may also be purchased for use in enzyme …

Development, Verification And Use Of Methods To Model Chemical And Thermal Processes For Lakes Mead And Powell, John Eric Edinger, Edward M. Buchak, Joseph S. Norton, Bureau Of Reclamation

Publications (WR)

Analysis and development of carbonate-bicarbonate chemical subroutine.

Investigation Of The Role Of Phenols In Oxidative Degradation Of Coal-Derived Naphthas, Jeffrey Macke

Masters Theses & Specialist Projects

The oxidative instability of coal liquids is a possible problem for the utilization of these alternate fuels. Past experience with both petroleum and coal-derived distillates indicates that heteroatomic species are intimately involved in such degradation. However, the exact nature of the chemistry is, in many cases, unclear. The goal of this work is to study the role of phenols in the chemistry of oxidative degradation of naphthas from a variety of current conversion processes. The effects of exposure to oxygen, metal surfaces, and metal salts have been investigated in order to identify the major routes leading to gum formation.

Coal-derived …

A Study Of Poly(P‐Xylylene)‐Coated Asf5‐Doped Polyacetylene, J. E. Osterholm, H. Yasuda, L. L. Levenson

Physics Faculty Research & Creative Works

Electrical conductivity measurements and scanning electron microscopy have been used to study uncoated and poly(p‐xylylene)‐coated samples of polyacetylene doped with AsF5. These initial results indicate a considerable reduction in the decay rate of conductivity in the presence of oxygen as well as a decreased rate of thermal decomposition of the dopant when heated between 50°C and 115°C in vacuum by the coating. Copyright © 1982 John Wiley & Sons, Inc.

Biomedical Applications Of Plasma Polymerization And Plasma Treatment Of Polymer Surfaces, H. Yasuda, M. Gazicki

Chemistry Faculty Research & Creative Works

Thin polymer films obtained by plasma polymerization usually show good biocompatibility when compared to classical biomaterials such as Silastic. The thicknesses of these films (from several hundreds of Å to several μm) make them suitable for the purpose of changing the surface properties of the substrate without altering its bulk properties. Both the above features together indicate the possible Biomedical use of plasma polymerization as well as plasma treatment of polymer surfaces processes. The purpose of this review is to present the most significant efforts to develop such applications with the specification of particular fields where these efforts are directed. …

A Comparison Of The Surface Polysaccharides Of Rhizobium Trifolii Su843 With Its Genetically Altered Mutant, 8002, Which Is Defective At Root Hair Curling (Hac-), Elroy Alfredo Turnbull

Masters Theses

Bacteria of the genus Rhizobium are capable of forming a complex nitrogen fixing (fix⁺) symbiotic association with leguminous plants. The surface polysaccharides are believed to be essential in the symbiotic process. The surface polysaccharides of a genetically altered Rhizobium trifolii mutant, 8002--which does not cause root hair curling (HAC^-), forms no nodules (Nod^-) nor fixes nitrogen (Fix^-)--is compared with its parent, SU843, which causes root hair curling (HAC⁺), forms nodules (Nod⁺), and fixes nitrogen (Fix⁺). Three types of surface polysaccharides--extracellular polysaccharide(s) (EPS), capsular polysaccharide(s) (CPS), and …

A Potential Problem With The Tsi Electrostatic Aerosol Classifier, Darryl J. Alofs, Max B. Trueblood

Mechanical and Aerospace Engineering Faculty Research & Creative Works

No abstract provided.

Picosecond Laser Pulse Irradiation Of Crystalline Silicon, K. L. Merkle, H. Baumgart, R.H. Uebbing, F. Phillipp

Electrical & Computer Engineering Faculty Publications

Morphology changes introduced by picosecond laser pulses at λ = 532 nm and 355 nm in (111) and (100) silicon samples are studied by means of optical and high-voltage electron microscopy. Depending on energy fluence, orientation and wavelength, amorphous or highly defective regions may be created. From an analysis of damage thresholds and damage depth distributions it is concluded that melting and energy confinement precedes the formation of the structural changes.

Preparation Of Cationic Polymer Surfaces By Grafting Polymerization, H. Yasuda, B. Sherry, M. A. Ei‐Nokaly, Stig Friberg

Chemistry Faculty Research & Creative Works

A cationic polymer surface with extensive capacity for adsorption of anionic surfactants was prepared by graft polymerization of vinyl pyridine onto a plasma‐treated polypropylene surface. The nitrogen was quaternized in order to obtain the cationic sites. The concentration dependence of adsorption from high eletrolyte solution of the anionic surfactant was similar to the one a solid surface from solutions with no added electrolyte. The hydrophobic contribution to the adsorption was experienced at surfactant concentrations far below its critical micellization. Copyright © 1982 John Wiley & Sons, Inc.

Synthesis And Evaluation Of Polymer Supported Homogenous Oxidation Catalysts, Raymond J. Riley

Retrospective Theses and Dissertations

Polystyrene bis(salicylaldehyde)-propylene-1,3-diiminato Cobalt (II) [salen] and Polystyrene bis(2,4-pentanedione)-propylene-1,3-diiminato Cobalt (II) [BAE] were prepared stepwise from chloromethylated polystyrene. In addition, a new preparation of a Schiff base was attempted resulting in Polystyrene bis(salicylaldehyde)-isobutylene-1,3-diiminoato Cobalt (II) being produced. Optimum reaction conditions were determined with regard tot ime, temperature, reaction ratios and solvent for each step for the reaction. The ability of the above named Cobalt (II) Schiff bases to oxidize 3-methyl indole to give the corresponding o-formylaminoacetophenone was also studied. One polymer-bound Schiff base cobalt catalyst (co-salen) demonstrated a very small amount of catalytic activity resulting in a minimum amount of o-formylaminoacetophenone …

23rd Rocky Mountain Conference

Rocky Mountain Conference on Magnetic Resonance

Abstracts and meeting program from the 23rd annual meeting of the Rocky Mountain Conference, co-sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy and the Rocky Mountain Chromatography Discussion Group. Held in Denver, Colorado, August 2-6, 1981.

Some Physical And Mechanical Properties Of Iron Calcium Silicate Glasses-Iron Composites, Hani Louis Rizkalla

Archived Theses and Dissertations

No abstract provided.

Theory And Intuition, E. A. Mccullough Jr.

Faculty Honor Lectures

Among the practitioners of science are people who are called theorists , and this lecture is concerned with the question, Just what is it that a theorist does?

If an experimentalist does experiments, then a theorist presumably does theories. What is a theory? My dictionary defines it as ". . . a system of assumptions, accepted principles, or rules of pro· cedure devised to analyze, predict or otherwise explain the nature or behavior of a specified set of phenomena."

Those who now understand perfectly what a theorist does may stop reading here because everything that follows will be superfluous. For …