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Synthesis Of Imidazolines, Diazepines, Triazepines And Imidazolidones From A 1, 2-Diamine And 1, 1-Dicarboxylic Esters, Irwin J. Pachter

Chemistry and Chemical Biology ETDs

In 1884 Freund (1) heated a mixture of malonic ester and ethylenediamine and obtained a product which dried to give a high melting powder. He named the compound ethylenemalonamide and attributed a seven-membered ring structure to it.

The Synthesis And Physical Properties Of Several Aromatic Fluorides, Charles J. Basso

Bachelors’ Theses

Since the advent of the Manhattan Project, more attention is being focused on fluorine compounds. Most of the inorganic fluorides are well known and are being used daily in industry. However, the realm of organic fluorides has not been investi­gated much up until recently, mainly because of the lack of safe and efficient fluorination reactions. Only within the last twenty-five years have reliable, indirect methods of fluorination been developed.

The purpose of this thesis is to give an outline of the most important fluorination processes, speaking of laboratory scale operations. The author illustrates the synthesis of an· aromatic fluoride by …

Electrolyte Equilibria In Blood, Edward J. Fitzsimons

Dissertations

No abstract provided.

Separation Of The Selenium Compounds In Seleniferous Plant Protein Hydrolysates By Paper Partition Chromatography, Arnold L. Smith

Electronic Theses and Dissertations

In 1943 Franke reported that the protein of "allolied" or "toxic" wheat carried the toxicant, and Franke and Painter in 1935 reported that those "toxic" proteins contained selenium which was in organic combination in the protein. There has been much speculation regarding the possibility of selenium replacing sulfur in the amino acids cysteine and methionine. The toxicity of selenium in selenium analogs of these compounds is similar to that of selenium occurring naturally in proteins seleniferous cereals, which indicated that the selenium may be present in the proteins as the analogue of these sulfur amino acids.

Studies Of Some Reactions Of Quinoxaline, 2-Methyl-, And 2,3-Dimethylquinoxaline, Delos Edward Bown

Theses and Dissertations

Although many compounds have been prepared which contain the heterocyclic nucleus known as the quinoxaline nucleus, very little fundamental experimentation has been reported by way of expanding the chemistry of quinoxaline beyond the basic condensation reaction and its valuable use as a means of characterization, for example, the reaction of vicinal diketones with o-phenylenediamine. Also, no know effort has been made to assemble the chemistry of the quinoxalines into one paper for ready reference. Additional interest is concerned with the chemotherapeutic value of basically substituted quinoxalines^1; however, this aspect of the problem will not be discussed. The chemistry of quinoxaline …

The Preparation Of Double Complex Cobalt Salts By The Resinous Exchange Method, Russell H. Berry Jr.

Chemistry Honors Papers

This six page thesis examines the preparation of double complex cobalt salts by the resinous exchange method.

A Scheme Of Analysis For The Ceric Rare Earths, Herschel Gordon Frye

University of the Pacific Theses and Dissertations

The elements numbered 57 to 71 have presented a problem in analytical chemistry unparalleled by that of any other group since their discovery over the span of the nineteenth century. The striking similarities in chemical behavior of the fifteen elements comprising this series have almost completely baffled analysts in every attack, and it is only with the increased use of those newer methods, best described as being of a strictly physical nature, that much real progress has been achieved. Where time-honored classical wet methods have failed rather disappointingly, newer methods based upon the use of the spectrograph and similar instruments …

The Cleavage Of Acylacetonitriles By Phenylmagnesium-Bromide., Murrell Pinckney Morris

LSU Historical Dissertations and Theses

No abstract provided.

A Spectrophotometric Study Of Some Deuterium Substituted Toluenes--Infrared Region., Olen Alvin Nance

LSU Historical Dissertations and Theses

No abstract provided.

Electrophoretic Studies Of A Synthetic Rubber-Like Lastex., Hulen Brown Williams

LSU Historical Dissertations and Theses

No abstract provided.

A Study Of The Vogel Reaction For The Determination Of Cobalt., Charles Gosse De Vries

LSU Historical Dissertations and Theses

No abstract provided.

The Influence Of Certain Factors In Urine On The Viscosity Of Gelatin, Leonard Driss

Bachelors’ Theses

The aims of this thesis are four-fold:

1. To determine the apparent proteolytic activity of normal urine from day to day.
2. To determine the apparent proteolytic activity of a sample of 8-12 hours after emission.
3. To determine whether the ether extracts of normal urine possess apparent proteolytic activity.
4. To determine the effect of hyaluronidase on the viscosity of gelatin.

A Comparative Study Of Some Dehydrating And Infiltrating Agents, Albin A. Sheputa

Bachelors’ Theses

During the past two decades methods in biological technique have been constantly improved and perfected. However, the choice of a universally satisfactory dehydrating and infiltrating agent has been much debated and various well known authorities in the field of biological technique have left this problem unsolved to the complete satisfaction of all concerned.

The Influence Of Certain Factors In Urine On The Viscosity Of Gelatin, Leonard Driss

Bachelors’ Theses

After reading the Masters Thesis of Mr. Herman L. Karl, the writer became interested in this problem and then took · up the study of the proteolytic activity of normal urine. Mr. Karl worked on the urine of pregnant women. Using gela­tin as a substrate, he hoped to find a difference in prote­olytic activity between the urine of a woman pregnant with a male fetus and the urine of a woman pregnant with a female fetus. His results were not conclusive but suggested that the problem of proteolytic action of urine should be studied under normal conditions.

An Improved Confirmatory Test For Arsenic, Mary Ellen Mckennan

Bachelors’ Theses

As any student in freshman chemistry can tell you, many of the tests in qualitative analysis do not work as well as they should. Of course, for a particular student, this may be more his fault than the fault of the test, but in some cases the test itself is to blame. One of these cases is the confirmatory test for arsenic. There is a combination of difficulties which make it hard to detect arsenic by the present method used in qualitative analysis so it is the hope of the author to determine exactly what these difficulties are, find some …

The Synthesis And Physical Properties Of A Few Unsymmetrically Substituted Ethanes, Gerald R. Aldrich

Bachelors’ Theses

The writer's interest was aroused in the synthesis of organic fluorides while taking a course in Organic Preparations. The fact that fluorine chemistry was something relatively recent made the topic especially appealing. While the chloro, bromo, and iodo derivatives of most of the homologous series had been prepared, many of the fluorine compounds had not. Previous research had disclosed the asymmetrical diaryl ethanes possessed peculiar properties - to mention one, fluorescence. It was proposed that a few of the asymmetrical diaryl ethanes having fluorine and chlorine substituted on the ring in various positions with respect to one another be prepared …

The Identification Of Various Alkyl Halides Through Formation Of Quaternary Ammonium Salts, John L. Canning

Bachelors’ Theses

Within the field of the characterization of organic compounds the preparation of suitable derivatives of the compound to be identified is the final process of the laboratory analysis. When the unknown is of such chemical nature that the preparation of derivatives is difficult or impossible the identification is not too satisfactory. This is often the case when the unknown is an alkyl halide. At present the identification of many of these compounds depends exclusively upon an examination of the physical constants.

It is the purpose of this paper to investigate the possibility of preparing quaternary ammonium compounds by treating the …

An Investigation Of Sundry Reactions For Application As Confirmatory Tests In Qualitative Analysis, Patricia Ann Lillis

Bachelors’ Theses

Is the present "scheme" of Qualitative analysis satisfactory? For many years the answer has been, No ! In the present ”scheme” it has frequently been necessary to strike a compromise between accuracy and simplicity. One solution to the problem can be found in the availability of a number of specific reagents, one for each substance to be identified, giving unmistakable tests and positive results. It would greater simplify the situation if a single inorganic salt could be used as a reagent for all the metallic ions.

One of the most successful reagents used was potassium mercuric thiocyanate. The water soluble …

An Investigation Of Phosphate Adsorption By The Clays Montmorillonite And Kaolinite /|Cby Gordon Richard Bradford, G. R. Bradford

Theses and Dissertations

Clay minerals have widespread application in industry and play an important role in plant life (2, 17). It is the adsorptive capacity of clay which determines largely its importance to man (2). The purpose of this investigation is to interpret the mechanism of adsorption of the phosphate anion by the two clay minerals montmorillonite and kaolinite. This particular system was singled out for two reasons: 1. It has agricultural significance. 2. It is believed that if the particular phosphate adsorption mechanism is understood it will aid in an understanding of many other adsorption phenomena associated with clay.

A Study Of Fossil Resins In Huntington Canyon Coal, Ross D. Gardner

Theses and Dissertations

The object of this investigation was to determine whether or not a certain sample of raw resin, collected by Mr. Adriaan Nagelvoort from coal from Huntington Canyon, Emery County, Utah, could be separated into more than one fraction with each fraction having distinctly different properties. Three methods of separation were attempted: (l) Separation of specific gravity fractions, (2) separation by use of solvents, and (3) chromatographic separation. Properties determined as a means of establishing any differences in the resins were: solubility, softening points, acid numbers, and iodine numbers.

The Carbethoxylation Products Of P-Aminoacetophenone And P-Dimethylaminoacetophenone, Chao-Yuan Chu

Theses and Dissertations

The carbethoxylation product of p-aminoacetophenone with diethyl carbonate by means of sodium amide has been proved to be ethyl p-acetylphenylcarbamate instead of ethyl p-aminobenzoylacetate. Thus the amino group was shown to be more active than the methyl ketonic. group tow ard carbethoxylation. Attempt at further carbethoxylation of this carbamate were unsuccessful.

Synthesis Of 2-Phenyl-2,1,3-Triazole-4-Carboxaldehyde And Some Derivatives, Gene Sumrell

Chemistry and Chemical Biology ETDs

It was decided in this problem to prepare 2-phenyl-2,1,3-triazole-4-carboxaldehyde (III) as a starting material by the method suggested by Hann and Hudson and run a number of typical aldehyde reactions with it. The preparation of (III) involved: (1) The hydrolysis of sucrose to form glucose and fructose; (2) conversion of these two sugars to D-glucose phenylosazone (I), by reaction with phenylhydrazine; (3) transformation of (I) to D-glucose phenylosotraizole (II), by the action of hot aqueous copper sulfate; and (4) oxidation of the side chain from (II) with sodium periodate, forming (III).

The reactions selected were: (1) the Grignard reaction; (2) …

An Investigation Of Several Electrode Combinations In An Effort To Find A Suitable Combination For The Potentiometric Titration Of Fluorides Using Cerous Nitrate As The Titrating Reagent, Miriam Knoebel

Bachelors’ Theses

The increasing commercial and industrial interest in compounds of fluorine as important industrial materials, and the importance of the relation of fluorides in water and foods to human health, has necessitated an accurate and rapid method for the quantitative determination of fluorides.

Conductance Of Organic Nitrogen Compounds At Their Melting Points, Leonard Joseph Burant

Bachelors’ Theses

Even though there are many practical applications using the conductance of fused salts, such as the commercial preparation of aluminum, sodium, potassium, calcium, and magnesium, there is very little in the literature on such conductance.

Because organic compounds as a class do not conduct as well as acids, bases, and salts, even less attention has been paid to the conductance of organic compounds in the fused state. Since the author has had some experience with organic preparations, it seemed worth while to prepare certain types of related heterocyclic organic compounds and to test their conductance in the fused state.

The Identification Of Alkyl Halides Through Conversion To Alkyl 3, 5 Dinitrobenzoates By A Reaction Between The Alkyl Halide And A Metallic Salt Of The Acid, James L. Finnerty

Bachelors’ Theses

To materially aid in the identification of a series of organic compounds one must develop a new system of derivatives or suggest better methods for preparing known derivatives. The problem of characterizing alkyl halides is one in which there is room for improvement, for the best derivatives of these compounds are now prepared by means of the Grignard reaction which may often fail to give satisfactory results. Moreover, there is a series of solid alkyl esters, the 3, 5 dinitrobenzoates, which serve very well for the identification of aliphatic alcohols, and which should be applied to the alkyl halides if …

A Study Of Chromatographic Adsorption Analysis And Its Application To Inorganic Qualitative Analysis, Sidney Marion Beck

Theses and Dissertations

This work is a study of the analytical applications of the chromatographic method, particularly as applied to inorganic qualitative analysis. It is divided into four parts as follows: (a) The main part of the work is a search of the common laboratory reagents, likely to be found in any beginning qualitative analysis laboratory, with the purpose of finding the best reagents for developing an invisible chromatogram on an adsoption column of activated alumina. For the most part, only inorganic reagents were used, but in special cases, a few of the more common orgaic reagents were used. (b) An evaluation of …

Chemistry-Restricted, Robert Molkenbur

Journal of the Minnesota Academy of Science

No abstract provided.

Some Reactions Of Chloro-Cyclo-Hexanone And Its Derivatives And The Synthesis Of 1 Chloro-2 Methyl Cyclo Hexene., Elle Bolt

Electronic Theses and Dissertations

No abstract provided.

Microchemical Identification Of Amidone., Robert C. Watson

Electronic Theses and Dissertations

No abstract provided.

Preparation And Physical Properties Of Some Unsymmetrically Substituted Ethanes, William F. Buth

Bachelors’ Theses

Early in 1947, while investigating the potentialities of various compounds for use as liquid dielectric materials, A method was found for the preparation of unsymmetrical ditolyl ethane by a condensation method using sulfuric acid. This material was thought to have excellent dielectric characteristics so it was prepared and tested. The tests were favorable enough, to warrant further investigation into the field of the unsymmetrical ethanes. Being aware of the physical properties required for a good liquid dielectric; it was proposed to prepare a few of the related compounds for which no data was known to exist and to select those …