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A Systematic Approach To Organic Qualitative Analysis Using Mass And Nuclear Magnetic Resonance Spectroscopy, Duane R. Greenly

Morehead State Theses and Dissertations

A thesis presented to the faculty of the School of Science and Mathematics at Morehead State University in partial fulfillment of the requirement for the Degree of Master of Science by Duane R. Greenly on January 14, 1974.

History Of So2 Removal System At The Meramec Plant Of Union Electric, Gerald E. Dreifke, John F. Mclaughlin, Jerrel D. Smith

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

In line with the then emerging air pollution control regulations Union Electric installed a limestone injection wet scrubber sulfur dioxide removal system on an intermediate size coal-fired utility boiler at its Meramec Power Plant on an experimental basis in September, 1968. During approximately 3 years of operation many difficulties were encountered with plugging and scaling of various system components by calcium sulphate. As a result of this experience along with related experiences by other utilities employing similar systems, the experiment was terminated in June, 1971.

As a result of the experiences gained, however, second generation experiments in sulfur dioxide removal …

Future United States Energy Demand Patterns, Leland Blank, Richard Riley

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The future energy demands of the United States are forecast using a unique approach. The saturation forecasting method reflects the inability of an individual to utilize more than a limited amount of energy. This technique also allows evaluation of various conservation methods and their effects on the future energy needs.

Reduced Nicotinamide Adenine Dinucleotide Dehydrogenase, Piericidin Sensitivity, And Site 1 Phosphorylation In Different Growth Phases Of Candida Utilis, S. Grossman, John G. Cobley, T. P. Singer, H. Beinert

Chemistry Faculty Publications

Reports in the literature indicate that during the exponential phase of growth of Candida utilis NADH oxidation is insensitive to rotenone, that rotenone sensitivity is acquired during the transition to the late stationary phase and is again lost on catabolite repression. The acquisition and loss of rotenone sensitivity appears to be accompanied by similar changes in Site 1 phosphorylation but does not appear to be reflected in the rate of oxidation of NADH (by mitochondria) or of NAD-linked substrates (by mitochondria or whole cells). In the present paper evidence is presented that these fluctuations in sensitivity to inhibitors of NADH …

A Study Of Oxomolybdenum Chelate Compounds Of Oxidation States (V) And (Iv) When Prepared By Photochemical Reduction Of Oxomolybdenum (Vi) Complexes In Ethanol Under Inert Atmosphere And By Chemical Reduction, Richard Donald Dendinger

Electronic Theses and Dissertations

A photolysis system was designed for meticulous exclusion of oxygen and moisture. Photolyzed ethanol solutions of dioxobis(acetylacetonato)­-molybdenum(VI), Mo0₂ (acac)₂, were studied via preparation of derivatives with several uninegative bidentate ligands (chelH, cysteine was designated cystH₂) and pyridine (py). Infrared spectroscopy was a useful tool in identifying these compounds. An oxomolybdenum(IV) compound, MoO(dtc)₂ was isolated from the red photolyzed solution when dtc was the N,N-diethyldithiocarbamate ion. Tropolone, 8-hydroxyquinoline, N,N-diethyldithiocarbamate, and cysteine formed products formulated as the dioxo bridged molybdenum(V) compounds, Mo₂0₄(che1)₂. Acetylacetone, tropolone, 8-Hydroxyquinoline and N,N-diethyldithiocarbamate, formed derivatives formulated …

Infrared Spectrophotometric Analysis Of Serum Triglycerides, Gerald J. Miille

University of the Pacific Theses and Dissertations

In recent years elevated levels of serum triglycerides have become of increasing importance in the field of medical technology. Abnormally high triglycerides have been claimed to be a major cause of numerous diseases and illnesses. Fredrickson and his associates (7, 15) have introduced a system for classifying hyperlipidemia and in all classes elevated triglycerides is a major laboratory finding. Disorders include obesity, diabetes, pancreatitis, xanthomatosis, hypothyroidism, and liver and kidney diseases; but most important is atherosclerosis

Some work has been done in the development of new methods of serum triglyceride analyses. The most advanced work makes use of an "automated …

Film Formation On Anodically Polarized Lead, H. Vaidyanathan, Ram A. Narasagoudar, Thomas J. O'Keefe, William Joseph James, James W. Johnson

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

The Effect Of Surface Impurities On The Thermal Accommodation Of Rare Gases On A Tungsten Surface, D. Vincent Roach, Louis Biolsi, Robert E. Harris

Chemistry Faculty Research & Creative Works

A Rather Comprehensive Experimental Examination of the Effect of Surface Impurities (Potassium and Cesium) on the Thermal Accommodation of Rare Gases on a Tungsten Surface Has Been Made by Roach and Thomas. the Present Work Examines These Effects from a Theoretical Viewpoint with Particular Emphasis on the Effect on the Thermal Accommodation of Helium on a Tungsten Surface Caused by the Adsorption of Cesium Ions And/or Atoms. for This Examination, the Theory of Allen and Feuer Has Been Utilized using Reasonable Values of the Interaction Parameters for Helium with the Adsorbate as Well as the Force Constant for the Adsorbate-Substrate …

Chemistry Departments In Predominantly Black Institutions, James O. Wear, Nirmal K. Shastri

Journal of the Arkansas Academy of Science

Chemistry programs in 87 predominantly Black institutions were compared by questionnaire survey. Advanced undergraduate courses were offered for chemistry majors by 86% of these schools, but only 28% offered research and independent study for undergraduates. Although there were extremes, most of the faculty taught 15 to 18 contact hours and their median salaries were below the national median. Library support seemed adequate with 1 to 1.5% of the total library materials being chemistry books, texts and reference, and the libraries of most schools had holdings of 15 principal chemistry-related journals. More than 90% of the schools were well-equipped with laboratory …

Nitrous Acid Deamination Reactions Of Benzyl Amino-4,6-0-Benzylidene-D-Hexopyranosides, Wai-Pan Chan

University of the Pacific Theses and Dissertations

This study concerns an investigation of nitrous acid deamination of various amino sugar derivatives. Deamination reagents have also been used for the diazotization of aromatic compounds. Nitrous acid deamination was used in the deamination of amino acids pinacolic amino alcohols and amino sugars.

A Phytochemical Investigation Of Liverwort Frullania Franciscana Howe, Timothy Ta-E Huang

Dissertations and Theses

Liverwort Frullania franciscana Howe was found high on the allergic test scale by J. Mitchell of the Medical School of the University of British Columbia and co-workers. Frullanolide was isolated from Frullania tamarisci by J.D. Connoly and by G. Oisson and his co-workers.

The plant sample, collected in Oregon, was hand separated, confirmed, air dried and milled before the extractions were done. A Soxhlet extraction with ether and cold extractions with n-hexane and with ether were carried out. Ether is a better extraction solvent than n-hexane for cold extraction.

Column chromatography was used for the separation of the extract based …

Metal Promoted Reactions Of Enamino Ketones, Suhas Satchidanand Joshi

Masters Theses

The reaction of 4-amino-3-allyl-3-penten-2-one (7) with mercuric acetate in acetic acid was found to produce 4-amino-1-pentene (12) in 70% yield. The scope of this unusual cleavage reaction was investigated by systematic variation of substituents on the enamino ketone framework, the metal salt and the solvent. The presence of the allyl group was necessary for the reaction to produce compound 12.

Under a variety of conditions there was no evidence for cyclization of 7 to give heterocyclic compounds. Neither was there evidence for cyclization in reactions of 4-amino-3-penten-2-one with vinyl acetate in the presence of mercury (II) or thallium (III) salts …

Mechanism Of Solvolysis Of 3-Methyl-2-Butyl Brosylates., Luu Le Nghi

Masters Theses

"The brosylates of 3-methyl-2-butanol and it's a-d₁-, ß-d₁-, B-d₃-, and S-d₄- analogs have been synthesized. The solvolytic rate data for these compounds were determined. The solvolytic products in 70% (vol.) ethanol-water have been identified by flame ionization gas chromatography using a Carbowax 20M column. The amount of each product was measured by integrating the peak areas from the chromatograms. By analyzing the isotope effect data, the rate determining step is shown to be the formation of the hydrogen bridged ion pair intermediate. By evaluating the GC-mass spectral analysis of the isopentenes, a …

The Chemical And Electrochemical Oxidative Decarboxylation Of Methyliminodiacetic Acid In Acid Media, Rita Kathleen Hessley

Doctoral Dissertations

"Methyliminodiacetic acid (MIDA) is oxidized with cerium. (IV) in both perchloric and sulfuric acids to give sarcosine, formaldehyde, and carbon dioxide"--Abstract, page 2.

A Study Of The Kinetic And Thermodynamic Properties Of Carbon Acids In Methanol, Dennis L. Filger

Doctoral Dissertations

The thermodynamic acidity (pK_a) of iodoform in methanol was determined at 25°C and 35°C; the values are 18.74 and 18.05, respectively . These acidity constants were determined by a modification of the equilibrium quenching technique which involves the conversion of the conjugate base of iodoform, present at equilibrium, to the radioactively labelled acid.

The rate constants for the methoxide-catalyzed hydrogentritium exchange of chloroform, iodoform, 9-phenylfluorene and indene were determined in methanol at various temperatures. The second-order rate constants obtained from these studies were shown to be the rate constants for removal of a triton. The activation parameters (ΔH …

Metal Salt Catalyzed Carbenoids Ii, Robert Stephen Mcdaniel Jr.

Doctoral Dissertations

"The interaction of diazomalonic esters with olefins in the presence of homogeneous Cu(II) catalyst species has been examined relating to olefin structure effects and catalyst structure effects using partial rate data as a method of determining the mechanistic aspects of the various reactions.

It has been possible to examine the mechanistic details of cyclopropanation, C-H insertion, and both "dimer" forming reactions.

Cyclopropanation proceeds via a transition state including olefin, copper (II), ligands, and carbene C-H insertion results from hydrogen abstraction prior to collapse of the transition state. "Dimer" is formed by the attack of diazo compound on the carbenoid carbon, …

Base-Induced Reactions Of P-Nitrobenzyl Compounds, Paul Henry Ruehle

Doctoral Dissertations

"The base-induced reactions of several p-nitrobenzyl compounds were studied. The products varied with changes in the leaving groups. With relatively poor leaving groups (Cl, S⁺(Me)₂), p,p'- dinitrostilbene was produced in good yield. The products of the reaction of p-nitrobenzyl chloride and hydroxide ion in 50% aqueous dioxane were 52.0% p,p'-dinitrostilbene, 43.9% cis- and trans-p,p'-dinitrostilbene oxides, 3.2% p-nitrobenzyl alcohol, and traces of other compounds. With dissolved oxygen, no stilbene was produced; the main product was 88% cis- and trans-p,p'-dinitrostilbene oxides. The addition of small amounts of di-t-butyl nitroxide caused a decrease in both the rate of the reaction and the amount …

A Study On Two Iodine Containing Peptides Isolated From Porcine Thyroglobulin, Frederick E. Bishop Jr.

Masters Theses

"Two iodopeptides were isolated from thyroglobulin that had been digested with trypsin by paper electrophoresis and paper chromatography. The amino acid analysis demonstrated that the amino acid compositions were similar. The N-terminal amino acid of both iodopeptides was shown to be leucine. The amino acid sequence of one of the iodopeptides was determined by the Edman degradation method and digestion with the enzyme Carboxypeptidase A. The sequence was shown to be: NH₂-Leu-Asn-Ala-Ser-Glu-MIT-Gly-Thr-Ser-Gly-COOH. Other workers have shown that synthetic tyrosyl peptides with the sequence Glu-Tyr are iodinated by the thyroid peroxidase enzyme with a greater specificity than other tyrosyl peptides. This …

Metal Salt Catalyzed Carbenoids The Catalysts In Trialkyl Phosphite Copper (I) Complex Catalyzed Decomposition Of Diazo Compounds, Nguyen Van Thinh

Masters Theses

"Partial rate data, asymmetric induction studies, interrupted experiments and additives studies indicate that copper(I) salt-phosphite complexes are destroyed during the course of reactions with dimethyl diazomalonate (1) and ethyl diazoacetate (2). All evidence is consistent with the copper(I) being oxidized to copper(II) and copper(0) being oxidized by impurities in the olefin which most probably are hydroperoxides.

Several new copper(I) salt-phosphite complexes were prepared and examined but none proved as effective for decomposing (1) as copper(II) bis acetylacetonate.

The utility of the copper (I) chloride-trimethyl phosphite complex for decomposing (1) is a function of the means of preparation. The three general …

A Kinetic Study Of The Cerium (Iv)-Oxalic Acid System In Acidic Sulfate Media., Robert Richard Kessler

Masters Theses

"The kinetics of the cerium (IV) oxidation of oxalic acid was studied by a stopped-flow spectrophotometric technique in acidic sulfate media. The media consisted of perchloric acid, sodium sulfate and sodium perchlorate which allowed for the determination and control of the various sulfate and hydroxo species of cerium (IV) at prescribed hydrogen ion concentrations. The rate of reaction decreases rapidly with increasing sulfate concentration which yields evidence against previous reports indicating Ce (SO₄)₂ and Ce (SO₄)^2-₃ as the reactive cerium (IV) species. The results indicate that Ce (SO₄)²⁺ is the …

Kinetic And Thermodynamic Acidities Of Selected Weakly Acidic Hydrocarbons, Darrell R. Strait

Doctoral Dissertations

"The kinetic and thermodynamic acidities in methanol for bromoform and phenylacetylene have been determined at various temperatures. The thermodynamic acidities of phenylacetylene were obtained through a quench method which involved tritium tagging of the phenylacetylene anions present at equilibrium. With the use of this method, a pK_a of 18.34 for phenylacetylene at 0ºC was obtained. Through the use of these acidities, it was shown that the kinetics for these proton exchange processes are not diffusion controlled.

Isotope effects ( k_H/ k_D) were obtained for chloroform, bromoform and phenylacetylene at three temperatures (0ºC, -10ºC and -20ºC). …

Effects Of Surfactants On Atomic Absorption Analysis Of Dilute Aqueous Copper And Nickel Solutions, Raymond L. Venable, Robert V. Ballad

Chemistry Faculty Research & Creative Works

No abstract provided.

Some Comparative Studies Of Atomic Absorption Of Three Rare-Earth Elements Of [I.E. In] Organic-Aqueous Solutions, David L. Dozark

Dissertations and Theses @ UNI

The atomic absorption of dysprosium, erbium, and europium in nitrous oxide-acetylene flames was studied, using aqueous solutions, organic solvent-water systems, and 100% organic solutions. Efforts were made to relate the viscosity and concentration of organic solvents to absorption. The effects of organic solvents on chemical and interelement interference were studied. The precision of analysis by atomic absorption using both aqueous and organic solutions was compared with that of EDTA titrations. Enhancement in the absorption showed a linear dependence on the logarithm of the product of viscosity and boiling point of 100% organic solutions of the rare earth acetylacetonates. In alcohol-water …

Synthesis And Reactions Of P-Nitrobenzyl 4,6-0-Benzylidene-2,3-Di-0-Methoxymethyl-Β-D-Glucopyranoside, Ray Douglas Carpenter

University of the Pacific Theses and Dissertations

The purpose of this work was the preparation of specifically blocked D-glucose derivatives with a free hydroxyl group on the anomeric carbon (C-1).

Comparative Phytochemistry Of Saururaceae Essential Oils., Lohit Venkateswara Tutupalli

University of the Pacific Theses and Dissertations

In view of their native medicinal uses, a systematic investigation of the phytochemistry and Hippocratic screening of three members of the Saururaceac namely, Anemopsis californica, Saururus cernuus and Houttuynia cordata was undertaken.

Front Matter, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.

Radiation Testing Under Simulated Loca Conditions, Kenneth G. Mayhan, D. R. Edwards, W. F. Oberbeck, J. F. Montle

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The purpose of this evaluation is to gather data to determine whether or not radiation during a simulated Loss of Coolant Accident would have any effect upon the coatings being used. Because of the concern in industry regarding the safety of nuclear power generating stations and the strong actions of the various environmentalist clubs and agencies clubs and agencies, the utilities have been required to prove the safety of the power facilities to extraordinary degrees before licensing can be obtained to operate. One of the areas regarding the safety is the necessity of proving that the coatings will remain intact …

Oxidation Reactions Of Unsaturated Hydrocarbons For Fuel Cells, James W. Johnson, William Joseph James, A. K. Agrawal

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The anodic oxidation of unsaturated hydrocarbons has been the subject of numerous studies, primarily on Pt and Au electrodes at low temperatures, < 100°C. The complete oxidation to CO₂ is usually the predominant reaction with both H₂O and OH^- having been proposed as the oxygen source. Usually a single study consists of a comprehensive investigation of a single compound on a single electrode or a somewhat limited study of several compounds on a single electrode. A diversity of proposed mechanisms has resulted and is illustrated by the following summary.

Ua66/7/2 Newsletter, Wku Chemistry

WKU Administration Documents

Newsletter created by and about the WKU Chemistry department.

A Study Of The Adsorption Of Some Atmospheric Gases On Soils Of The Willamette Valley River Basin, Thomas R. Quale

Dissertations and Theses

Recent work indicates that microorganisms present in soils can remove carbon monoxide from the atmosphere and as such constitutes a major sink. B.E.T. adsorption studies were carried out on representative soils from the Willamette Valley River Basin in order to determine their adsorptive characteristics for carbon monoxide and other gases. Attempts were made to isolate, through a non-soildestructive sterilization, the adsorptive characteristics of the soil microorganisms as well as of the test soil.

The carbon monoxide studies show physical adsorption equivalent to the coverage of a few per cent of the surface area at 25.0° and 76 cm-Hg. Adsorption studies …