Digital Commons Network^™

Binding And Transport Properties Of Lithium In Red Cells From Hypertensive Patients And Normotensive Controls, Ravichandran Ramasamy

Dissertations

No abstract provided.

Interaction Of Season With Wheat Response To Nitrogen Fertilizer., J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89M3

Interaction of season with wheat response to nitrogen fertilizer.

Location: Merredin Research Station.

History: 1988 pasture.

Sown on 30/5/89. Gutha Wheat at 50 kg/ha Madiera Serradella at 15 kg/ha. Basal superphosphate at 200 kg/ha plus Molybdenum drilled with the seed and 100 kg/ha Muriate of Potash topdressed. At seeding (A.S) nitrogen treatments topdressed by hand on 1/6/89 and 4 weeks after (4WAS) treatments applied on 29/6/89. Supplementary water applied.

Trial 89NA61

Pasture deterioration trial.

Location: West Dale

History: Long term pasture dominated by non-productive 'suffocating clover'.

Trial 88NA88

Effect of clover growth on nitrogen for following cereals.

Location: …

Pasture Agronomy., C. K. Revell

Experimental Summaries - Plant Research

Trial 89ME82

a. Medic establishment.

Establishing burr medic pastures with cereal cover.
Merredin

Trial 89SC19

b. Serradella - Potash response.

Response of serradella to potash fertilizer.
South Carrabin

Trial 89M44

c. Serradella/Grass competition

Effect of grass competition on production of serradella.
Merredin Research Station.

Trial 89SC HERB

d. Herbicide tolerance of Serradella.

Herbicide tolerance of Madeira serradella.
South Carrabin

Influence Of Soil Acidity On Cereals And Acidification Rates., P. J. Dolling

Experimental Summaries - Plant Research

Soil acidity and the availability of nitrogen to cereals.

To determine the extra nitrogen available due to better pasture legume growth after liming.
To determine the extra nitrogen released from soil organic matter after liming.

Trial 89NO81

Location: South Cunderdin.

Trial 89NO82

Location: Cunderdin

Trial 89NO83

Location: Konnongorring.

Trial 89NO84

Location: Jennacubbine.

Trial 88AL35

Location: Woogenellup.

Trial 88TS54

Location: Three Springs.

Trial 88NO76

Location: Goomalling.

Trial 88NO77

Location: Ejanding.

Effect Of Seed Origin And Seed Phosphorus On The Growth Of Lupins., M. M. Riley, M. D. Bolland, K. Adcock

Experimental Summaries - Plant Research

Trial: 89BA29

Location: Badgingarra Research Station, Paddock 4A2, old block.

Lupin cv. Gungurru sieved to uniform size and sown without inoculation. No basal fertilizers were applied as the soil had previously been treated with high rates of superphosphate, micro-nutrients and potassium. Muriate of potash topdressed on 18/8/89 at 100 kg/ha.

Pasture Deterioration Trial, J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89NA61

Location: Duranillin

In this site we would expect a very large response (40 to 50% ) to phosphorus.

History:

The site was chosen because of the patchy and poor pasture production. The poor areas tend to have more suckling clover than the good areas. The pasture was legume dominant.

Treatments were applied on April 16, 1989.

New Block Badgingarra Rs Late Time Of Seeding., J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89BA33,

Location: Badgingarra

Based on a 1.5 t/ha potential yield, the strategic treatment was planned to be 120 kg urea/ha 4WAS. However, the crop was poorly established and so NH4NO3 was used in the hope of getting better tillering than would be possible with the slower release urea source. Gambling on equal dollars to urea for 2/3 N, but believe that twice as effective.

DAP was used to place nitrogen with the seed in case there was no rain of significance after seeding. This nitrogen (only 5 kg/ha) was probably lost with the rains of 20-28/7/89 (50 mm). Urea …

Nitrogenous Fertilisers For Cereals In Different Rotations. Results From 1989 Trials., I. Rowland, M. G. Mason

Experimental Summaries - Plant Research

Trial 78BA1

Nitrogen fertiliser requirement in alternate crop - pasture rotation.

Location: Badgingarra Research Station.

Trial 88B4

Effect of amount and quality of organic matter residues on response to N.

Location: Badgingarra Research Station.

Trial 86WH36, 86M44

Lupin/wheat rotation.

Location: Wongan Hills Research Station, Carrabin Research Station.

Trail 87N084, 86M39, 86ME64, 87N25, 87KA49

Pea/wheat rotation.

Location: Konnongorring, Merredin Research Station, Narembeen, Newdegate Research Station, Nyabing,

The Effect Of Seed Origin And Seed Phosphorus On The Growth Of Lupins, M. M. Riley, M. D. Bolland, K. Adcock

Experimental Summaries - Plant Research

Trial: 89SC20

Location: South Carrabin Research Station, Hayden paddock.

The effects of superphosphate and fertilizer on seeds planted over a 21 week period.

Tactical Nitrogen Decisions For Wheat (And Nitrogen Sources Rates And Times On Wheat), J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89MO49

Location: Tenderloin, Brand Highway, Regan's Ford.

History:

1987 Aroona wheat with 70 kg DAP and 3 kg CuSO4 at seeding followed by 60 urea at 3WAS and another 40 urea at 6WAS. Yield was about 1.7 to 1.8 t/ha;
1988 Gungurru lupins with 120 kg super and manganese/ha yielded 1.9 t/ha. 350-400 ml Roundup/ha and one cultivation prior to seeding.

Effect Of Seed Phosphorus , Seed Size And Seeding Density On The Growth Of Wheat At Two Soil P Levels., M. M. Riley, M. D. Bolland, K. Adcock

Experimental Summaries - Plant Research

Trial 89SC23

Location: South Carrabin

Effect of soil P, seed P and seed rate on plant counts at 5 weeks.
Shoot dry matter (DM) at tillering and heading and seed DM at maturity were strongly depressed by low soil P levels.

Phosphate Nutrition Of Burr Medic And Yellow Serradella., Blakely Paynter

Experimental Summaries - Plant Research

Trial 89ME50, 89ME51, 89ME53, 88ME55, 89ME56

Location: Mutadgin, Doodlakine, Noongar, Mt Hampton, Nungarin

Compare the response of burr medic to topdressed P with the response of wheat to drilled P.

Trial 89ME52, 89ME54

Location: Noongar, Mt. Hampton.

Compare the response of burr medic to topdressed P with the response of wheat to drilled P.
Measure the response of burr medic pasture to applied potash.

Trial 89ME59

Location: Beacon

Compare the response of yellow serradella to topdressed P with the response of wheat to drilled P.

Trial 89ME60, 89ME61

Location: Muntadgin

Compare the response of yellow serradella to topdressed P with …

An Analysis Of The Inhibitory Effects Of Linolenic Acid Upon Photosystem Ii Of Higher Plants, Mark Edward Iven

Dissertations and Theses

This study utilizes steady state fluorescence measurements, flash-induced P680+ absorption transients, and DCIP reduction kinetics to study the inhibitory effects of linolenic acid (LA) upon Photosystem II (PSII) in whole spinach chloroplasts and insideout wheat thylakoids. It confirms the presence within PSII of LA-induced inhibition of energy trapping and/or primary charge separation (i.e., primary inhibition), in addition to donor side inhibition. The latter is diminished in the presence of 1,5-Diphenylcarbohydrazide (DPC) and probably takes place at the oxygen evolving complex. Primary inhibition, which is more controversial, probably occurs between Ph and QA, with a likely contribution at the level of …

Study Of Photolytic Interference On Ho Measurements By Lif-Fage, Carmen Ivette Martinez

Dissertations and Theses

For many years there has been a great interest among the scientific community in the study of the hydroxyl radical, HO. This interest stems from the fundamental role played by this molecule in the photochemistry of the atmosphere, mainly as a cleansing agent of environmental pollutants. Knowing the concentration of the radical would enable scientists to corroborate current atmospheric models and to predict future trends in the atmosphere. Even though there is a great interest in the determination of atmospheric concentrations of this molecule, the task has been very difficult. This is mainly due to the lack of a method …

The Chemistry Of Sulfonyl Fluorides: Sf5 And/Or So2f Containing Compounds As Precursors To Sulfonic Acids, Robin Joyce Terjeson

Dissertations and Theses

Sulfonyl fluoride systems and their derivatives, RS0₂F, where R represents hydrocarbon/fluorocarbon moieties continue to be of considerable interest. The incorporation of the sulfonyl fluoride group (S0₂F) into molecular systems can lead to compounds that are useful as ion-exchange resins, surface active agents, fuel cell electrolytes, and strong sulfonic acids/salts.

Interest in preparing SF₅ containing sulfonyl fluorides led to the synthesis of the ᵝ-sultone, SF₅CHCF₂0S0₂, and its rearranged product. Hydrolysis of the sultone gave SF₅CH₂S0₂F which led to the sulfonic acid and salt, SF …

Chemical Modification Of Skeletal Muscle Sarcoplasmic Reticulum Vesicles: A Study Of Calcium Permeability, Janice F. Stuart

Dissertations and Theses

Skeletal muscle contains an internal membrane system called the sarcoplasmic reticulum (SR) whose function is to regulate the Ca²⁺ concentration of the myoplasm. Ca²⁺ is transported into the SR from the myoplasm via a Ca²⁺ dependent ATPase thus lowering the myoplasmic Ca²⁺ concentration. Ca²⁺ exits from the SR via a Ca²⁺ releqse pathway resultingin the increase of myoplasmic Ca²⁺. Muscles contract when the myoplasmic Ca²⁺ concentration is > 5 uM and relax when the Ca²⁺ concentration is lowered below 1 uM. The Ca²⁺ dependent ATPase has been extensively studied but …

7li Nmr Of Normal Human Erythrocytes, Rao P. Gullapalli, Roger M. Hawk, Richard A. Komoroski

Journal of the Arkansas Academy of Science

Lithium has been known to be an effective medication for people with bipolar disorder. The mechanisms of action of lithium in the brain is not very well understood. NMR spectroscopy and imaging are effective both in determining lithium levels in tissue and brain. We have monitored lithium levels in red blood cells. We have been able to separate intra- and extracellular compartments of lithium using shift reagents, thereby obtaining T^1 's of both the compartments. Lithium uptake as a function of hematocrit was monitored weekly over a 3 week period. The time constant of 50 mM lithium uptake at 25°C …

Preparation Of A Series Of Pyridyl Phenylureas Of Potential Agricultural Interest, Frank L. Setliff, Steve H. Rankin, Mark W. Milstead

Journal of the Arkansas Academy of Science

Substituted phenylurea derivatives of 3-amino-2-chloro-5-methylpyridine and 5-amino-2-chloro-3- methylpyridine were prepared by treating the amines with appropriately substituted phenyl isocyanates. Structure- confirming spectral data are also presented.

A Spectroscopic Study Of Charge Distribution In Transition Metal Bridging Hydride Complexes, Shixiong Chen

Masters Theses

A series of transition metal bridging hydrides of general formula C[μ-HM₂(CO)₁₀] (C = tetraethylammonium, Et₄N⁺; tetraphenylphosphonium, Ph₄P⁺; of bis(triphenylphosphine)iminium, PPN⁺; M = Cr or W) were synthesized from M(CO)₆ and NaBH₄ bt known methods. As a means of obtaining information about the charge distribution in these complexes, they were allowed to interact in solution and the solid state with triphenylphosphine oxide (TPPO) on the premise that this electron donor could identify sites of relative electron deficiency. Evidence for interaction was sought via solution and …

Derivatization Of Coal By Alkylation And Lithium Iodide Treatment, Cynthia L. Ludwig

Masters Theses

The hypothesis that hydrogen-bonded ethers in coal could be cleaved by reaction with lithium iodide in pyridine to form new phenol groups was investigated for coals #2, 3, and 5 plus their alkylated derivatives from the Argonne Premium Coal Sample Program. Changes caused by alkylation and reaction with LiI were monitored by solvent extraction yeilds, solvent swelling, FT-IR and Size Exclusion Chromatography (SEC).

Solubilities of alkylated coals are rank and oxygen functionality dependent. Evidence supports the hypothesis that the solubilization mechanism is dependent on the extent of hydrogen-bonding in the coal. Elimination of hydrogen-bonds through alkylation increases toluene solubility and …

Residual Influence Of Macronutrient Enrichment On The Aquatic Food Web Of An Okefenokee Swamp Abandoned Bird Rookery, J. Douglas Oliver, Steven A. Schoenberg

Faculty Publications and Presentations

We present evidence for residual nutrient enrichment of diverse components of a blackwater marsh, by a biotic component of the ecosystem itself. Thousands of nesting white ibis (Eudocimus albus) that foraged over a 20-km radius fertilized a rookery with guano within Okefenokee Swamp. Georgia. USA. One to two yr after the birds abandoned it. this marsh showed continued enrichment effects. Elevated available phosphorus in sediments, as measured by equilibrium phosphate concentration, contributed to enhanced biomass of phytoplankton in the overlying water column. Planktivorous fish were greater in biomass than at reference sites. Experimental phosphorus and nitrogen fertilization of enclosures at …

Synthesis And Nucleophilic Reactions Of Bifunctional Thiourea S,S,S-Trioxides, Dan Webb '89

Honors Projects

The synthesis of bifunctional thioureas and the corresponding thiourea S,S,S-trioxides has been examined. Two methods for the synthesis of the bisthioureas were employed. One involved the treatment of a diamine with silicon tetraisothiocyanate in benzene. The second involved treatment of the amine with ammonium thiocyanate in dilute acid. This latter synthesis was superior because of the ease of its use, the high yields obtained, and the purity of the products. Though this synthesis worked well for the preparation of phenylene-l,4-bis(thiourea), it yielded only bisthiocyanate salts in the synthesis of aliphatic thioureas. The oxidation of the bisthioureas was carried out using …

A Strategy For The Design Of Flame Retardants: Cross-Linking Processes, Charles A. Wilkie, Sunil J. Sirdesai, Thitivat Suebsaeng

Chemistry Faculty Research and Publications

Cross-linking is identified as an effective means for flame retardation of polymers and schemes for the cross-linking of poly(ethylene terephthalate) and poly(methyl methacrylate) are presented. For poly(ethylene terephthalate) the scheme involves polymerization of the initially produced vinyl ester. This is followed by chain-stripping, producing a polyene, and cyclization of this polyene. For poly(methyl methacrylate) the scheme entails the formation of anhydride linkages between adjacent polymer strands. Evidence is presented to show the efficacy of these processes and information is produced to aid in the identification of new flame retardants.

Electron Affinity Of Chlorine Dioxide, Lucia M. Babcock, Thomas C. Pentecost, W. H. Koppenol

Peer Reviewed Articles

The flowing afterglow technique was used to determine the electron affinity of chlorine dioxide. A value of 2.37 ± 0.10 eV was found by bracketing between the electron affinities of HS° and SF₄ as a lower limit and that of NO₂ as an upper limit. This value is in excellent agreement with 2.32 eV predicted from a simple thermodynamic cycle involving the reduction potential of the C10₂/C10₂^- couple and a Gibbs hydration energy identical with that of SO₂^-.

Permanganate Colorimetric Rapid Method For Chemical Oxygen Demand In Seawater, Myung Zoon Czae, Taekee Hong, Myung Hoon Kim

Chemistry & Biochemistry Faculty Publications

No abstract provided.

Friedrich Wöhler, John Alfred Heitmann

History Faculty Publications

Friedrich Wöhler synthesized urea in 1828 and thus first demonstrated that organic materials, heretofore believed to possess a vital force, need not be made exclusively within living organisms. He also isolated aluminum metal in 1827 and discovered the elements beryllium and yttrium.

Solid-Phase Electrochemical Enzyme Immunoassay With Attomole Detection Limit By Flow Injection Analysis, Yan Xu, H. Brian Halsall, William R. Heineman

Chemistry Faculty Publications

A sandwich electrochemical enzyme immunoassay with flow injection analysis for the model antigen mouse IgG has been developed with alkaline phosphatase as the enzyme label. The enzyme substrate, 4-aminophenyl phosphate and its enzymatic reaction product, 4-aminophenol have been studied by cyclic and hydrodynamic voltammetry. The determination of 4-aminophenol by flow injection analysis with electrochemical detection (FIAEC) has a linear range of 5.0 × 10−8 to 1.0 × 10−5 M, a detection limit of 2.4 × 10−8 M, and a sample throughput of 72 samples/h. The detection limit is set by a background capacitance response, which depends on the ionic strength …

Nonadditive Effects In Hf And Hcl Trimers, G. Chalasinski, S. M. Cybulski, M. M. Szczesniak, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Nonadditive effects are calculated for (HF)₃ and (HCl)₃ complexes and analyzed via the combination of perturbation theory of intermolecular forces with Møller–Plesset perturbation theory (MPPT). In both systems the nonadditivity is dominated by the self‐consistent field (SCF) deformation effect, i.e., mutual polarization of the monomer wavefunctions. Heitler–London exchange and correlation effects are of secondary importance. Three‐body terms exhibit much lesser basis set dependence than the two‐body effects and even quite moderate basis sets which are not accurate enough for treatment of two‐body forces can yield three‐body effects of quantitative quality. This is due in large measure to the …

Analysis Of The Potential Energy Surface Of Ar–Nh3, G. Chalasinski, S. M. Cybulski, M. M. Szczesniak, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The combination of supermolecular Møller–Plesset treatment with the perturbation theory of intermolecular forces is applied in the analysis of the potential energy surface of Ar–NH₃. Anisotropy of the self‐consistent field (SCF) potential is determined by the first‐order exchange repulsion. Second‐order dispersion energy, the dominating attractive contribution, is anisotropic in the reciprocal sense to the first‐order exchange, i.e., minima in one nearly coincide with maxima in the other. The estimated second‐order correlation correction to the exchange effect is nearly as large as a half ΔE^SCF in the minimum and has a ‘‘smoothing’’ effect on the anisotropy of …

Fluorinated Esters: Synthesis And Identification, Jilla Schaff

Dissertations and Theses

Reactions of different alcohols with 2-hydroxy - 1- trifluoromethyl -1,2,2-trifluoroethanesulfonic acid sultone F₃CCFCF₂OSO₂ were studied. Six new esters were prepared: C₆F₅OC(O)CF(CF₃)SO₂F, CH₃CH₂OC(O)CF(CF₃)SO₂F, CF₃CH₂OC(O)CF(CF₃)SO₂F, (CF₃)₂CHOC(O)CF(CF₃)SO₂F, CH2=CHCH₂OC(O)CF(CF₃)SO₂F, (CH₂OC(O)CF(CF₃)SO₂F)₂. Analytical data, infrared, nmr and mass spectra are presented supporting the proposed structures for these new compounds.