Digital Commons Network^™

National Subterranean Clover Improvement Programme., P. G. H. Nichols

Experimental Summaries - Plant Research

The National Subterranean Clover Improvement Programme (NSCIP) aims to develop, by breeding and selection, better adapted and more productive low—oestrogen cultivars of subterranean clover for a range of environments in southern Australia. The programme is a collaborative one with the University of Western Australia and consists of two phases: (i) early generation selection, which involves selecting varieties satisfying primary selection criteria; and (ii) field evaluation of advanced lines, which is conducted by the Departments of Agriculture in each State and co—ordinated by the Plant Breeder.

The first phase is conducted at the University Field Station (UFS) and is continued until …

Evaluation Of Persian And Balansa Clovers., R. Snowball

Experimental Summaries - Plant Research

Trial 89MC6, 89HA3, 89W10

Evaluation of Persian and Balansa clovers.

Evaluate a range of Trifolium species including a selection of Persian and Balansa clovers.

Study Of Deposition Methods For Silicon Powder, Kamesh V. Gadepally, Kevin B. Tennal, Roger M. Hawk, Al Robles, James A. Gribel

Journal of the Arkansas Academy of Science

Silicon powder tends to agglomerate at normal atmospheric conditions and is, hence, difficult to aerosolize. Several methods of aerosolizing silicon powder and finally depositing it on various substrates were investigated. This paper presents the investigated methods of aerosolization. The electrostatic spray coating used in dry paint application was found to be the most suitable. The general merits of this method and its use for silicon powder deposition to form films are discussed.

Indirect Photometric Chromatography Of Inorganic And Organic Anions Using Benzoate As An Eluent, Shahab A. Shamsi

Masters Theses

For many years the determination of common inorganic and organic anions was hindered by the lack of adequately sensitive analytical techniques. The determination of these anions was laborious and time consuming (e.g. titration, precipitaion, gravimetric analysis etc.). Because of the development of high-performance liquid chromatography, the anion exchange separation of simple inorganic and organic anions is now possible. Now, there are a broad and ever-increasing array of chromatographic methods supplanting these older chemical methods. However, detection is still a problem, but indirect detection provides a practical route for the detection of non-chromophoric inorganic and organic anions.

This dissertation describes the …

Improving The Analytical Recovery Of Radiostrontium From Environmental Samples, Luz Selenia Acosta

Retrospective Theses and Dissertations

No abstract provided.

¹⁷O And ³³S Nuclear Magnetic Resonance Studies Of Some Selected Sulfonates: Concentration And Solvent Dependence, Telitha M. Murray

Dissertations

No abstract provided.

Substituent Effects On The Stereochemistry Of 1,3-Dipolar Cycloadditions To 7-Substituted Norbornadienes, Ramakrishnan Subramanian

Dissertations

No abstract provided.

Substituent Effects On The Electronic Spectroscopy Of Tryptophan Derivatives In Jet Expansions, John R. Cable, Michael J. Tubergen, Donald H. Levy

Chemistry Faculty Publications

Electronic excitation spectra of seven tryptophan derivatives entrained in a supersonic expansion have been recorded using both resonantly enhanced two-photon ionization and laser induced fluorescence. Two derivatives, tryptophan amide and tryptophan methyl amide, were found to have substantial low frequency vibrational progressions in their excitation spectra, yet in both compounds this behavior was apparent in only one conformer. Other derivatives did not display as much vibronic activity. Conformers which had vibrational progressions were found to emit in a broad band far to the red of excitation. All other conformers were found to fluoresce most strongly in resonance with excitation. The …

Structure Of Ba2cu(Bo3)2, Robert W. Smith, Douglas A. Keszler

Chemistry Faculty Publications

As part of our program in the synthesis and characterization of new solid-state borates, we recently synthesized the polymorphic compound Sr2Cu(BO3)2 (Smith & Keszler, 1989) which undergoes a first-order phase transition from a low-temperature form to a high-temperature form at 1073 K. The high-temperature beta form exhibits larger coordination numbers for the Sr atoms and a substantial rearrangement of the copper borate network relative to that of the low-temperature... form.

Stress-Induced Infrared Frequency Shifts In Polyethylene, George A. Pfeffer, Donald W. Noid

Chemistry Faculty Publications

The molecular dynamics technique is used to study the spectral response of a polyethylene chain in a crystal environment under a mechanical deformation. The MUSIC method, which was previously shown to accurately compute dispersion curves from the time-dependent structure factor, is used. A complete characterization of frequency shifts is presented for various lamellar thickness, temperatures, stress (or pressure), and mass defects.

Rheology Of Aqueous Suspensions Of Polystyrene Latex Stabilized By Grafted Poly(Ethylene Oxide), Harry J. Ploehn, J. W. Goodwin

Faculty Publications

A water-soluble carbodiimide has been used to end-graft aminated poly (ethylene oxide)(PEO) chemically onto colloidal polystyrene particles. Two particle sizes (115 and 347 nm diameter) and two PEO molecular weights (112 000 and 615 000 g mol^–1) were combined to give suspensions with four different ratios of polymer layer thickness to particle radius. Electrophoresis demonstrated that the PEO was grafted, not just adsorbed. Dynamic light scattering showed that the adsorbed and grafted layers had similar structures and that non-ionic surfactant perturbed the PEO configurations. Steady shear and oscillatory rheometry indicated that long-ranged polymeric forces between particles governed the …

The Enhancement Of The Incineration Of Model Volatile Organic Solvents By The Use Of Hydrogen Peroxide As A Novel Oxidative Homogeneous Catalyst, Douglas James Tomlin

Retrospective Theses and Dissertations

No abstract provided.

Intermolecular Potential Of The Methane Dimer And Trimer, M. M. Szczesniak, G. Chalansinski, S. M. Cybulski, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The Heitler–London (HL) exchange energy is responsible for the anisotropy of the pair potential in methane. The equilibrium dimer structure is that which minimizes steric repulsion between hydrogens belonging to opposite subsystems. Dispersion energy, which represents a dominating attractive contribution, displays an orientation dependence which is the mirror image of that for HL exchange. The three‐body correction to the pair potential is a superposition of HL and second‐order exchange nonadditivities combined with the Axilrod–Teller dispersion nonadditivity. A great deal of cancellation between these terms results in near additivity of methane interactions in the long and intermediate regions.

Comparison Of The Molecular Structures Of Monovalent Cation Salets Of N,N-Dimethyldithiocarbamate. Novel Synthesis And Crystal Structure Of (Phi4)(S2cn(Ch3)2)2h2o, Mark Draganjac, David Minick, Elizabeth M. Holt

Journal of the Arkansas Academy of Science

Crystals of the tetraphenylphosphonium N,N-dimethyldithiocarbamate dihydrate (C₂₇H₃₀NO₂PS₂; F.W. = 495.6) are monoclinic; P2₁/n; a = 13.349(6), b = 20,968(6), c = 9.800(4) Å, β = 109.01(3)°; Z = 4; V = 2593.4(16) Å^3; Dₓ = 1.269 gcm- 3 . Data were collected at ambient temperature using MoKα radiation (λ = 0.71069 Å).F(000) = 1048, linear absorption coefficient, n = 2.80 cm- 1. The structure was solved by direct methods and subsequently refined by full matrix least squares techniques. Final R value = 0.064 for 1 61 0 reflections and 298 varied parameters. Due to the nature of the cation, interactions …

Design Of A Viscometer Using Magnetostriction Of Ferromagnetic Probes, Subhendra Nath Sarkar

Journal of the Arkansas Academy of Science

On-line measurement of viscosity of process liquids at process temperature is difficult though industrially very important. A viscometer is designed which can do this up to about 300 °C almost on-line within about 1-8% accuracy except for very viscous liquids like glucose. It uses a ferromagnetic probe designed to mechanically vibrate in the ultrasonic frequency range. An excitation coil sends repeated excitation current pulses to induce mechanical vibration in the probe tip. When placed in a process fluid, the vibration amplitude is damped due to the viscosity of the fluid, and the damped vibration is sensed by Faraday's principle by …

Caudate Infarcts, Louis R. Caplan, Edward Feldmann, Jeremy D. Schmahmann, Carlos S. Kase, Phillip B. Gorelick, Daniel B. Hier, Cathy Helgason, George Baquis, John P. Greenberg

Chemistry Faculty Research & Creative Works

Eighteen Patients Had Caudate Nucleus Infarcts (10 Left-Sided; 8 Right-Sided). Infarcts Extended into the Anterior Limb of the Internal Capsule in 9 Patients, and Also the Anterior Putamen in 5 Patients. Thirteen Patients Had Motor Signs, Most Often a Slight Transient Hemiparesis. Dysarthria Was Common (11 Patients). Cognitive and Behavioral Abnormalities Were Frequent, and Included Abulia (10 Patients), Agitation and Hyperactivity (7 Patients), Contralateral Neglect (3 Patients, All Right Caudate), and Language Abnormalities (2 Patients, Both Left Caudate). the Majority of Patients Had Risk Factors for Penetrating Artery Disease. Branch Occlusion of Heubner's Artery, or Perforators from the Proximal Anterior …

Coatings And Surface Modification By Methane Plasma Polymerization, Chung‐Peng ‐P Ho, H. Yasuda

Chemistry Faculty Research & Creative Works

Polymers formed from plasma‐polymerized methane were employed to modify the surface properties of silicone rubber membrane. Polymers were evaluated based on the energy input parameter W/FM, where W is the discharge power, F is the monomer flow rate, and M is the molecular weight of the monomer. Dealing with the characteristics of plasma polymerization and the deposited polymer film, the effect of pumping rate on deposition rate and the coating thickness, surface energy, and gas permeabilities of methane‐plasma‐polymer‐coated silicone rubber membrane were investigated in three plasma regions. Because more reactive species are expelled at high pumping rates, the monomer‐deficient region …

Self‐Diffusion Coefficients Of Boc‐Amino Acid Anhydrides Under Conditions Of Solid Phase Peptide Synthesis, Stephen Pickup, Frank D. Blum, Warren T. Ford

Chemistry Faculty Research & Creative Works

No abstract provided.

Plasma Surface Treatment On Nylon Fabrics By Fluorocarbon Compounds, Yu Iriyama, Takeshi Yasuda, D. L. Cho, H. Yasuda

Chemistry Faculty Research & Creative Works

Nylon fabrics were treated by low temperature fluorocarbon plasmas. All of the fluorocarbon plasmas applied altered the surface of nylon fabrics to be hydrophobic and water‐repellent. The durability of hydrophobicity and water repellency was examined by measurements of the water contact angle, the water droplet rolling‐off angle, and the breakthrough water pressure after plasma‐treated fabrics were washed. It was found that the structure of starting fluorocarbon and the plasma energy input were important factors in the durability. After washing, surface dynamics were investigated on different drying conditions. It was found that chemical composition and water repellency were dependent on drying …

Derivatized Cyclodextrins For Normal-Phase Liquid Chromatographic Separation Of Enantiorners, Daniel W. Armstrong, San Chun Chang, Apryll M. Stalcup, Martha L. Hilton, Jo Dee Duncan, James R. Faulkner

Chemistry Faculty Research & Creative Works

Several different derivatized β-cyclodextrins were synthesized and used as chiral stationary phases in normal-phase liquid chromatography. The multiply substituted derivatives were made with acetic anhydride, (R)-and (S)-1-(1-naphthyl) ethyl isocyanate, 2, 6-dimethylphenyl isocyanate, and p-toluoyl chloride. The first successful cyclodextrln-based, normal-phase separation of enantiomers was accomplished on these derivative phases. In contrast to chiral separations on the native β-cyclodextrin stationary phase, the enantiomeric separation mechanism on these new phases is not thought to be dependent on inclusion complexation. The similarities and differences between the derivatized cyclodextrin stationary phases and the cellulosic stationary phases are discussed. © 1990, American Chemical Society. All …

Development Of Herbicide Tolerant Lupin Varieties., J. Cooper

Experimental Summaries - Plant Research

Trial 90GL26

Effect of growth stage at application of response to atrazine.

To determine the optimum stage for application of atrazine to show the most consistent and maximum differences between varieties of lupins in glasshouse tolerance trials.

Trial 90GL28

Response to lupin varieties to metribuzin applied post emergence.

This is an initial quick screening to determine if the same pattern of responses occurs when metribuzin is applied as when simazine/atrazine is used. Field rates were used assuming that there are 1,250,000 pots/ha. The recommended rate applied to peas is 300g/ha so this was used as an estimate of the amount …

Trace Element Nutrition., R. F. Brennan

Experimental Summaries - Plant Research

Trial 66N14

Long Term Copper Residual Trial

Location: Newdegate Research Station.

To determine the residual value of previously applied copper.

Trial 86N27

Residual Value of Zinc with DAP.

Location: Newdegate Research Station.

To determine the decline in effectiveness of zinc on this soil types using DAP.

86LG34

Residual Value of Copper, Zinc and Sulphur with DAP Fertilizer

Location: South Newdegate.

To determine the decline in effectiveness of copper, zinc and sulphur on this soil types using DAP

Trial 67E8

Grain Yields of Wheat Grown on a Residual Copper Trial.

Location: Esperance Downs Research Station.

The trial was originally designed to …

Phosphorus And Sulphur Nutrition Of Pastures In High Rainfall Areas., M. D. Bolland, M. F. Clarke

Experimental Summaries - Plant Research

J.S.Yeates and M.F.Clarke started these experiments. In January 1990 M.D.A. Bolland replaced J.S. Yeates (who became Regional Manager of the Northern Agricultural Region) as the Research Officer responsible for the management of the long-term experiments, and to continue the research on the topic.

In the experiments the fertilizers wee applied in autumn (March-April) in the years listed in the tables.

Trial 80AL4

Location: Cuthbert.

A new experiment was started in 1989 to compare two partially acidulated rock phosphate (PARP) fertilizers with ordinary (single) superphosphate (OSP).

Trial 84AL32

Location: Denmark

The fertilizers compared are ordinary (single) superphosphate (OSP). New (pre 1990) …

Investigating Poor Pasture Productivity., J. W. Bowden, R. J. Lunt, C. Broun

Experimental Summaries - Plant Research

Trial 90N06

Location: West Dale

To determine the reason for poor pasture productivity in medium rainfall zone. Specifically why the pastures are dominated by the poorly productive species Trifolium suffocatum and why there was a large response to phosphorous fertilizer at 50 ppm P in the soil.

Selection And Evaluation Of Medic Lines With Resistance To Aphids And Improved Agronomic Characteristics., P. Evans

Experimental Summaries - Plant Research

Trial 89AB12 and 89AB11

Location: Great Southern Agricultural Institute.

Ten commercial cultivars and twenty breeding lines were evaluated in 1990. To assess the effect of insect attack throughout the season, two treatments were imposed, sprayed throughout the season and unsprayed.

Organochlorine Residues In Soil, Plant And In The Body And Wool Fat Of Wethers., Tony Albertsen

Experimental Summaries - Plant Research

Trial 5841

The accumulation and rundown of dieldrin in wethers.

Location: Brookhampton, Donnybrook, Jindong, Manjimup, Carbunup and Pemberton

The background, aims, experimental method, and the first years results and discussion have been reported in the 1989 experimental summary.

The latter phase of the study was continued until December 1990 on six of the sites (these were Brookhampton, Donnybrook, Jindong, Manjimup, Carbunup and Pemberton) with similar measurements being obtained at regular intervals. The sheep monitored during this phase were the 1989 Main mob and the 1989 Replacement mob.

Agronomic Practices To Improve Or Maintain The Protein Content Of High Yielding, Long Season Wheats., Wayne Smith

Experimental Summaries - Plant Research

Trial 90SG8, 90SG9, 90ES9, 90ES11, 90MT8, 90KO2

Wheat variety * Time of sowing

Location: Salmon Gums Research Station, Mt. Ridley, East Gibson, Mt Barker Research Station, Kojaneerup Research Station

The aim is to define the optimum heading/flowering date on the South Coast. This trial also provides information on the performance of the varieties and new cross-breds at various sowing times.

Trial 90E10, 90ES12, 90ES13, 90ES14, 90ES15, 90ES16, 90SG10, 90SG11, 90MT10, 90KO3, 90KO4

Wheat protein on the South Coast

Location: Esperance Downs Research Station, Gibson, Neridup, Mt Ridley, Salmon Gums Research Station, Mt Barker Research Station, Kojaneerup Research Station

The Australian …

Weed Control In Cereals And Pastures Including Declared Plants., J. Peirce, B. J. Rayner

Experimental Summaries - Plant Research

Trial 90C49

Grass and broad leaved weed control in direct sown crops.

Location: Chapman Valley Research Station.

The low rate of sprayseed with diuron was not as effective on the grasses. It may indicate some antagonism within the mix as the same rate of sprayseed with metribuzin did not cause any drop in grass control. The addition of 2, 4-D amine may have boosted the mixes activity on capeweed as the sprayseed metribuzin mix was not very good on capeweed.

Trial 90EB37

Grass and broad leaved weed control in direct sown crops.

Location: East Beverley Annex.

Part of the trial …

Deep Banding Phosphate For Lupins. 1990 Results., R. J. Jarvis

Experimental Summaries - Plant Research

Trials 90SC1, 90SC21, 90SC12, 88SC28, 90WH73

There is no doubt that deep banding is the only effective way to provide an efficient supply of phosphorus for lupins in the eastern wheatbelt.

Location: Carrabin, Wongan Hills.

Development And Management Of Cattle Pastures In The High Rainfall Zone., Tony Albertsen

Experimental Summaries - Plant Research

Trial 87V8

Development and management of cattle pastures in the high rainfall zone.

To compare the effect of pasture species, pasture management and grazing management on pasture quantity, quality and cattle production.

Phalaris evaluation

In 1989 ninety three lines of Phalaris agrundinacea backcross with P. aquatica, bred by Dr. R.N. Oram (CSIRO Canberra) were drilled sown into unreplicated 10m single row plots at Vasse Research Station. In addition 7 controls (with two replications) were planted. Similar trials were planted by Mr. L. Cransberg (Albany) and Dr. R.N. Oram (Bendigo).

Evaluation of annual and short term rotation ryegrass.

The increasing range …