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A Pulse Gas Chromatographic Method For Determining The Dispersion And Surface Area Of Co Oxidation Catalysts, Susan Kay Ohorodnik

Chemistry & Biochemistry Theses & Dissertations

Catalysts composed of platinum and/or palladium on tin(IV) oxide supports with or without silica gel have been developed for the recombination of carbon monoxide and oxygen to form carbon dioxide for use in carbon dioxide lasers. A pulse gas chromatographic method has been developed to measure the chemisorption properties of the catalysts. From the chemisorption measurements, the active surface area and dispersion of the catalysts have been determined.

The Role Of The Voltage Gradient In The Agarose Gel Electrophoresis Of Dna, David Wheeler

Theses and Dissertations in Biomedical Sciences

In Part I of this dissertation, empirical equations for predicting DNA mobility during agarose gel electrophoresis (AGE) from voltage gradient are developed from the data of McDonnel (36) for electrophoresis in a 1.6% agarose gel. These equations represented the data well for DNA between 2 and 10 kilobase pairs (KBp) in length. A computer program, called GELSIM, which incorporates these equations is described in Part II. GELSIM was designed to allow researchers to analyze electrophoresis data by predicting the effect on DNA migration of altering the voltage of electrophoresis. In this way, electrophoretic banding patterns produced using different voltages could …

Evaluation Of The Function Exp (X2) Erfc (X) To Higher Precisions For Higher-Order Derivative Polarography Of Ce-Type Electrode Process, Myung-Hoon Kim, Veriti P. Smith, Tae-Kee Hong

Chemistry & Biochemistry Faculty Publications

The function exp(x2)erfc(x), which is often encountered in studies of electrode kinetics, is evaluated to an extended precision with 32 significant decimal digits in order to find theoretical relationships used in derivative polarography/voltammetry for a chemically-coupled electrode process. Computations with a lower precision are not successful. Evaluation of the function is accomplished by using three types of expansions for the function. Best ranges of arguments are selected for each equation for particular precisions for efficiencies. The method is successfully applied to calculate higher-order derivatives of the current-potential curves in all potential ranges for a reversible electron transfer reaction coupled with …

Semiempirical Determination Of Molecular Motions Associated With Phonon Modes In Molecular Crystals, K.M. White, Craig J. Eckhardt

Craig J. Eckhardt Publications

An approach using piezomodulated Raman scattering is presented which permits determination of the molecular motions associated with the eigenmodes of molecular crystals. When coupled with a lattice dynamical calculation for the eigenmodes, the experiment can be used to validate the calculation. The case of 1,2,4,5-tetrabromobenzene is treated and it is shown that the phase relations of the piezomodulated Raman signals confirm the calculated eigenmodes. The Journal of Chemical Physics is copyrighted by The American Institute of Physics.

An Analysis Of On-Road Remote Sensing As A Tool For Automobile Emissions Control, Donald H. Stedman, Gary A. Bishop

Fuel Efficiency Automobile Test Publications

Final report to the Illinois Department of Energy and Natural Resources, ILENR/RE-AQ-90/05

Studies Of Nitro-Pah On Ambient Air Particulate Matter, Yadan Wang Chen

Theses

A rapid, simple method for routine trace analysis of four isomeric nitropolycyclic aromatic hydrocarbons (nitro-PAH) (1-nitropyrene, 2-nitropyrene, 2-nitrofluoranthene and 3-nitrofluoranthene) in ambient air particulate matter is described. Two types of air particle sample (TSP and IP10) were collected and particle extracts were prefractionated by thin layer chromatography and the appropriate zones of interest analyzed by reversed-phase HPLC with UV and fluorescence detection. The study of Zn/Si post-column reaction chamber and oxygen scrubber for catalytic reduction of target compounds is also described. Six nitro-PAH compounds were identified in TSP and five in IP10 air particle samples. The results of identification and …

Synthesis Of Strained Lactams And Study Of Their Energetics And Bonding, Jung-Chou Tsai

Theses

In order to measure nitrogen and oxygen ionization energies of planar and nonplanar lactams, four compounds were synthesized successfully. The comparison of these ionization energies provides a qualitative insight into how the charge distribution of strained lactams varies with molecular geometry. Of special interest was the different ability of amides to exhibit resonance, monitored most sensitively by the core electron energy of nitrogen in the compounds. The nitrogen core (1s) ionization energies for the two nonplanar amides, 1,3-di-tert-butyl aziridinone (405.00 ev) and 1-azabicyclo[3.3.1]nonan-2-one (405.47) each having pyramidal nitrogens, indicated a nitrogen more negative than that in the comparable planar amide. …

Reversing Enantioselectivity In Capillary Gas Chromatography With Polar And Nonpolar Cyclodextrin Derivative Phases, Daniel W. Armstrong, Weiyong Li, Josef Pitha

Chemistry Faculty Research & Creative Works

No abstract provided.

Pea And Faba Bean Symbiosis With Rhizobium., J. Evans, C. Wallace, N. Dobrowolski

Experimental Summaries - Plant Research

Trial 89WH55, 89KA57, 89M26, 90A12, 90A13, 90M59, 90M60

Location: Merredin, Konnongorring, Dalwallinu, Wongan Hills, Kojonup, Avondale Research Station.

To undertake relevant field studies to establish whether there are constraints to pea and bean symbiosis, arising from management, environment or genetics, and affecting crop N accumulation and productivity.

Trial 90BA60

Using Le-mat (omethoate) insecticide and legume inoculant on seed.

Location: Badgingarra Research Station,

To measure the effect of Lemat on the nodulation and growth of medics and luceme.

Rhizoctonia Bare Patch Of Cereals And Lupins. Sterile Red Fungus (Srf) And Control Of Take-All Disease In Wheat., G. C. Macnish

Experimental Summaries - Plant Research

Trial 86E31

Rhizoctonia strains and paddock history.

Location: Esperance Downs Research Station ( Paddock C5)

To determine the effects of pasture, cultivation and cropping on Rhizoctonia root rot, Rhizoctonia patch and distribution of patch and non-patch strains of R. spp

Trial 88E39

Rhizoctonia patch mini-plot establishment area.

Location: Esperance Downs Research Station ( Paddock N1B)

To examine the effects of cultivation and minimum tillage in patches in lupins and to provide sites for mini-plot experiment.

Trial 88KO15

Rhizoctonia bare patch establishment area.

Location: Kojaneerup annex.

To establish an area (with a known history) for future research.

Trial 89E12

Rhizoctonia bare …

Virus Diseases In Lupins., R. Jones, Simon Mckirdy, A. R. Baker, J. Stevenson

Experimental Summaries - Plant Research

Trial 90BA12, 90WH17, 90A6, 90MT13

Location: Badgingarra, Wongan Hills, Avondale and Mt Barker.

Cucumber Mosaic Virus - Effect of different levels of infection in seed sown.

Trials were done at Badgingarra and Wongan Hills in which plots were sown with seed of cv. Gungurru which transmitted CMV at rates of 5,, l' and O,. The plots were separated by 30 m wide cereal buffers. The intended plant density of 45 plants/sq m (seeding rate 80 kg/ha) was not achieved at either site because of non-wetting soil problems (Table 1). Establishment of CMV infected seedlings as opposed to healthy ones was …

Leaf Diseases Of Wheat, R. Loughman, Geoff Thomas, J. A. Bathgate, W. R. Smith

Experimental Summaries - Plant Research

Trial 90PE10

Strategic variety mixtures to reduce septoria diseases of wheat. Evaluation of wheat lines for suitability to mixing for septoria control.

Location: Mt. Barker Research Station

To determine components of partial resistance to both Septoria species to ensure that lines with components that are complimentary are chosen for evaluation as mixtures for Septoria control.

Trial 90MT12 and 90ME10

Assessing effects of a paired variety mixture to reduce Septoria.

Location: Borden and Mt Barker Research Station.

To assess the effects of a variety mixture on Septoria diseases.

Trial 90MT11 and 90JE9

Evaluating variety mixtures to reduce septoria, using a range …

Management Of Lupin Root Rots In The Northern Agricultural Region., W. Macleod

Experimental Summaries - Plant Research

Trial 90GE93

Field survey of lupin root diseases in the northern wheatbelt.

Location: Northern Agricultural Region - majority within Geraldton Advisory District.

To determine the extent, severity and exact nature of fungi causing root and hypocotyl rots of lupins in the northern wheatbelt.

Trial 90GE98

Effect of time of sowing on rhizoctonia infection of lupins.

Location: Woorree.

To examine the effects of sowing lupins at various intervals after the start of the season on the level of Rhizoctonia hypocotyl rot.

Trial 90EC24

Observations on stunt patch on the eradu sandplain.

Location: East Chapman Research Station.

To examine the effects of …

Pleiochaeta Diseases Of Lupins, Mark Sweetingham

Experimental Summaries - Plant Research

Trial 90WH20, 90SC5, 90LG8

Rates of dicarboximide fungicides for lupins.

Location: Wongan Hills Research Station, South Carrabin Research Station, East Hyden.

To compare the disease control and yield response of Rovral and Sumisclex seed treatments at a range of rates.

Trial 90M11, 90BA17

Rates of dicarboxide fungicides for lupins.

Location: Merredin Research Station, Badgingarra Research Station.

To compare the disease control and yield response of Rovral and Sumisclex seed treatments at a range of rates,

Isoprenylation Is Required For The Processing Of The Lamin A Precursor, Michael Sinensky, L. A. Beck, T. J. Hosick

Faculty Publications, Biological Sciences

The nuclear lamina proteins, prelamin A, lamin B, and a 70-kD lamina-associated protein, are posttranslationally modified by a metabolite derived from mevalonate. This modification can be inhibited by treatment with (3-R,S)-3-fluoromevalonate, demonstrating that it is isoprenoid in nature. We have examined the association between isoprenoid metabolism and processing of the lamin A precursor in human and hamster cells. Inhibition of 3-hydroxy-3-methylglutaryl coenzyme A reductase by mevinolin (lovastatin) specifically depletes endogenous isoprenoid pools and inhibits the conversion of prelamin A to lamin A. Prelamin A processing is also blocked by mevalonate starvation of Mev-1, a CHO cell line auxotrophic for mevalonate. …

A Course In Laboratory And Stockroom Management, John T. Moore

Faculty Publications

No abstract provided.

Geochemistry Of Selected Maine Peat Deposits, Stephen A. Norton

Maine Collection

Geochemistry of Selected Maine Peat Deposits

by Steven Allen Norton

Maine Geological Survey, Department of Conservation, Augusta, Maine, 1990.

Contents: Introduction / Purpose of Study / Location of Study Sites / Methods / Acknowledgements / Results / Water Chemistry / Dating of Short Cores / Chemistry of Short Cores / Core Interpretations / Summary / References Cited

Path Integral Study Of The Correlated Electronic States Of Na4–Na6, Randall W. Hall

Collected Faculty Scholarship

Feynman’s path integral formulation of quantum mechanics is used to study the correlated electronic states of Na4–Na6. Two types of simulations are performed: in the first, the nuclei are allowed to move at finite temperature in order to find the most stable geometries. In agreement with previous calculations, we find that planar structures are the most stable and that there is significant vibrational amplitude at finite temperatures, indicating that the Born–Oppenheimer surface is relatively flat. In the second type of simulation, the nuclei are held fixed at symmetric and asymmetric geometries and the correlated electron density is found. Our results …

Telomere Structure In Euplotes Crassus: Characterization Of Dna-Protein Interactions And Isolation Of A Telomere-Binding Protein, Carolyn M. Price

Department of Chemistry: Faculty Publications

The nucleoprotein structure of telomeres from Euplotes crassus was studied by using nuclease and chemical footprinting. The macronuclear telomeres were found to exist as DNA-protein complexes that are resistant to micrococcal nuclease digestion. Each complex encompassed 85 to 130 base pairs of macronuclear DNA and appeared to consist of two structural domains that are characterized by dissimilar DNA-protein interactions. Dimethyl sulfate footprinting demonstrated that very sequence-specific and salt-stable interactions occur in the most terminal region of each complex. DNase I footprinting indicated that DNA in the region 30 to 120 base-pairs from the 5' end lies on a protein surface; …

Weed Control On The South Coast., J. H. Moore

Experimental Summaries - Plant Research

Trial 90A141

Barley variety tolerance to herbicides.

Location: Gairdner river.

To determine the tolerance of five barley varieties to 19 herbicides and mixtures.

Trial 90AL43

Herbicides for erodium control in serradella.

Location: North Woogenilup.

To determine the efficacy and phytotoxicity of a range of herbicides at varying rates, on erodium in a first year serradella pasture.

Trial 90AL44

Silvergrass control in pasture.

Location: Cheynes Beach Road.

To determine the efficacy of simazine and gramoxone, either tankmixed or individually at varying rates, on silver grass in a clover based pasture.

Trial 90AL45

Pattersons curse control.

To determine which herbicides and at …

A Survey Using 14n:15n Natural Abundance Of The N Fixation By Pasture Legumes In The Field And Of Factors Affecting Fixation, P. Sanford

Experimental Summaries - Plant Research

Trial 89AL43, 90AL50, 90KO16

A preliminary survey using 14N:15N natural abundance to assess N2 fixation by pasture legumes in the field.

Location: Albany.

1. Develop a sampling methodology for the 1990 farm survey.
2. An initial assessment of nitrogen fixation by pasture legumes in the field.

Trial 90MT70

Using 14N:15N natural abundance to assess N2-fixation by subterranean clover.

Location Mount Barker Research Station

To examine symbiotic nitrogen fixation by subterranean clover, in detail, through one season in a productive pasture. To better assess the point in the season at which as one time sampling would most accurately determine the proportion …

Biological Markers In Lower Jurassic Synrift Lacustrine Black Shales, Hartford Basin, Connecticut, U.S.A., Michael A. Kruge, John F. Hubert, Jay F. Akes, Paul E. Meriney

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The East Berlin Formation (Lower Jurassic, Hartford basin, Connecticut, U.S.A.) is distinctive for its six cyclic units of lacustrine black shale and gray mudstone. separated by playa and fluvial redbeds. The black shales arc each about a meter thick and were deposited in subtropical, thermally stratified, oligomictic lakes, the youngest of which (lakes 3 through 6) were large enough to flood most of the basin and attained depths of several tens of meters.

The saturate fractions of solvent extracts of organic-rich black shales from each of the six lakes, collected at fresh roadcuts near East Berlin, arc dominated by extended …

Characterization Of Organic Sulfur Compounds In Coals And Coal Macerals, Stephen R. Palmer, Edwin J. Hippo, Michael A. Kruge, John C. Crelling

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Peroxyacetic acid oxidation has been used to investigate the type and distribution of organic sulfur species in samples of vitrinite, sporinite and inertinite, separated from the Herrin No.6 and an Indiana No.5 coal seam. It was established that organic sulfur species were selectively preserved during oxidation and their analysis led to some of the first sulfur-33 NMR spectra obtained for coal. The effects of maceral separation processes on model compounds were also studied. Results from our studies support the following conclusions: 1). Different macerals have different distributions and types of organic sulfur species. 2). Organic sulfur compounds in coal occur …

Organic Geochemistry Of A Lower Jurassic Synrift Lacustrine Sequence, Hartford Basin, Connecticut, U.S.A., Michael A. Kruge, John F. Hubert, David F. Bensley, John C. Crelling, R Jay Akes, Paul E. Meriney

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Synrift terrestrial strata of the Lower Jurassic East Berlin Formation (Hartford basin, Connecticut, U.S.A.) record cyclical expansion and contraction of major lakes, six of which were deep enough to develop anoxic bottom waters. We have studied one representative lacustrine sequence in detail, sampling a new roadcut near the village of East Berlin. The section examined is 4 m thick, with a gray siltstone at the base, deposited in shallow water, overlain by an organic-rich black shale (deep water), succeeded in turn by another gray siltstone, deposited as the lake waters gradually receded. The upper gray siltstone is chemically distinct from …

Herbicide Resistance In Weeds., G. S. Gill

Experimental Summaries - Plant Research

Trial 90WH76

Alternative herbicides for diclofop-methyl resistant annual ryegrass in wheat.

Location: Wongan Hills Research Station.

To investigate the performance of alternative herbicides for the control of diclofop-methyl resistant annual ryegrass in wheat.

Trial 90WH80

Alternative herbicides for diclofop-methyl resistant annual ryegrass in lupins.

Location: Wongan Hills Research Station.

To investigate the performance of alternative herbicides for the control of diclofop-methyl resistant annual ryegrass in lupins

Trial 90A15

Alternative herbicides for Diclofop-methyl resistant wild oats in wheat.

Location: Avondale Research Station.

To investigate the performance of alternative herbicides for the control of diclofop-methyl resistant wild oats in wheat.

Trial 90A17 …

Phosphorus Nutrition., M. D. Bolland, M. J. Baker

Experimental Summaries - Plant Research

Evaluation of soil test for phosphate on sandy soils.

Results presented for this project, commenced in 1988, which started as a joint project between the Department of Agriculture and Soil Science and Plant Nutrition, School of Agriculture, University of Western Australia.

In the field experiments, 10 levels of superphosphate (three replicates) were applied in May 1988, and 10 levels of superphosphate (also three replicates) were applied in May 1989 onto an adjacent area to the 1988 treatments. Colwell P I(soil test values) and yield data are presented for 1988 and 1989 for the 1988 treatments layed out in 1988, and …

Cranola Rapseed Variety Assessment. Cranola Agronomy. Linseed. Tillage., J. D. Warren

Experimental Summaries - Plant Research

Trial 90AB15. 90N68, 90EB39

Canola : assessment of early maturing Stage 2 lines.

Location: Katanning, Newdegate Research Station, East Beverley Annex

Production of Canola in medium rainfall zones offers the opportunity for a rapid expansion of the industry. However presently recommended varieties take too long to mature for the area's shorter growing season. The Stage 2 trials assess Canola lines selected on the basis of earliness from the remnants of Dr Roy's now defunct rapeseed breeding programme as well as selections from Eastern States breeding programmes. The trials arc conducted at three sites to account for environmental effects on cultivar …

Getting The Best Out Of Our Wheats., Brenda Shackley, L. Lambert

Experimental Summaries - Plant Research

Trials: 90KA82 (TOS1), 90KA83 (TOS 2), 90KA84 (TOS 3)
90LG4 (TOS 1), 90LG45 (TOS 2), 90LG46 (TOS 3)
90LG47 (TOS 1), 90LG48 (TOS 2), 90LG49 (TOS 3)
90N42 (TOS 1), 90N43 (TOS 2), 90N44 (TOS 3)

Variety * time of sowing (TOS)

Locations: Wagin, Tarin Rock, Newdegate Research Station and Lake Varley.

Determine the optimum sowing date for maximum yield for a range of released and unreleased wheat cultivars.

Trials: 90KA79, 90LG50, 90LG51, 90N62

Nitrogen application.

Locations: Wagin, Tarin Rock, Newdegate Station and Lake Varley.

Determine the response of released and unreleased wheat cultivars to the application of nitrogen.

Trials: …

Tactical Nitrogen For Wheat., J. W. Bowden, S. J. Burgess, Ian Fillery

Experimental Summaries - Plant Research

Trial 90NO104, 90NO111, 90NO112, 90MO53

Associated Work: 90N0105,111,112, 90M053,54, 55 and 56

Wheat responses to levels, sources and times of application of nitrogen.

Location: Southern Brook, Regan's Ford

This project characterizes the dynamics of nitrogen supply to a wheat crop at each of the sites on which various methods of making fertilizer recommendation were tested. It supposedly provides the "optimum" nitrogen fertilizer regime as well as detailed information on nitrogen supply and demand so that results can be made transferable to other situations.

Trial 90NO105, 90NO112, 90M054

Related trials: 90N0104, 105,111,112; 90M053,54,55 and 56

Tactical nitrogen application for wheat.

Location: …

Pursuit For Weed Control In Peas., S. Curtin

Experimental Summaries - Plant Research

All trials were located in Merredin.

Trial 90ME86

This trial was one of the best demonstrations of pursuits effectiveness against mustard in particular. Other weeds were rough poppy and ryegrass and a small amount of cereal and doublegee.

250 ml applied immediate before seeding (IBS) was by far the best treatment with 100% control of mustard and poppy and good ryegrass control. This is in contract to 375 ml most emergent which had good control of mustard (77%) and suppression of ryegrass. There was no yield advantage from the post emergent treatment but there was a 55% yield increase from …