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Beneficial Investigation Of Sustainable Recycled Waste Plastic In Treating The Consolidation Behavior Of Fine Soil, Aram Mohammed Raheem, Cumaraswamy Vipulanandan, Mohammed Hiwa Abdullrahman, Ali Tariq Omer

Journal of Sustainable Construction Materials and Technologies

Recycled waste plastic is one of the regular garbage utilized as a sustainable material in soil remediation. This study examines the efficacy of utilizing local recycled waste plastic as an ecological quantifiable along with soil containing fine particles to analyze the consolidation behavior. Various recycled waste plastic contents ranging from 2% to 10% were employed experimentally in two patterns where in the first pattern the recycled waste plastic were mixed as dry material with the fine soil particles while in the second pattern a sandwich layer of 10% of the recycled waste plastic was placed in the middle of the …

Enhanced Thermal Energy Storage In Buildings: Impregnation, Leakage, And Environmental Performance Of Organic And Inorganic Pcm Composites, Gökhan Genç, Esra Yılmaz, M. Yusuf Yazıcı

Journal of Sustainable Construction Materials and Technologies

This study experimentally investigates the impregnation and leakage performance of various organic (tobacco, sawdust, bay leaf, black cumin) and inorganic (vermiculite, perlite, bentonite, sepiolite) carrier materials used for phase change material (PCM) integration in building applications. The commercial paraffin-based PCM RT-31 was used as the thermal storage medium. Impregnation and leakage tests were conducted to evaluate the PCM absorption capacity, form stability, and energy storage potential of each carrier. The results revealed that perlite (C = 80%) and bay leaf (C = 78%) exhibited the highest impregnation capacities due to their porous and fibrous structures; however, they also demonstrated significant …

Modeling Of Tensile Stress-Strain Response For Steel Fiber Reinforced Self-Compacting Concretes, Anıl Niş, Nilufer Özyurt, Turan Özturan

Journal of Sustainable Construction Materials and Technologies

Main aim of the research was to further understand self-compacting concrete reinforced with steel fibers (SFR-SCC) behavior and to contribute modeling of the tensile stress-strain diagrams for the standardization of the fiber reinforced materials for structural utilization. Fiber reinforced materials has not been used without structural rebar because of the absence of stress-strain curve in tension required for the structural design codes. Hence, an inverse analysis (multi-layer model) was further modified for various steel fibers to predict tensile stress-strain behaviour. For this purpose, 5 different mixes; control, reinforced with long fibers with 0.5% and 1%, short fiber with 0.5% and …

Optimization Of Bio-Briquettes Production From Cassava Stems Co-Blended With Sisal Bole Bagasse Using Response Surface Methodology, Agnes Nshoma Msobi, Neema O. Msuya, Kando Khalifa Janga

Tanzania Journal of Science

This research aimed at producing bio-briquettes from cassava stems and sisal bole bagasse as an alternative source of cooking energy. A Response Surface Methodology (RSM) with Face - Centered Central Composite Design (FCCCD) featured a multi-objective optimization of the effect of the production parameters, focusing on maximizing char yield and Higher Heating Value (HHV) of the produced briquette while minimizing carbonization temperature and residence time. The findings showed that bio-briquettes produced at the lowest temperature (250 ℃) and residence time (30 min) and the blending ratio of 75% by 25% had the highest char yield of 76.92% and HHV of …

Extraction Of High-Quality Cashew Nutshell Liquid Using Carbon Dioxide-Expanded Hexane, Frank N. Jacob, Neema Msuya, Joseph Y.N Philip, Kando Khalifa Janga

Tanzania Journal of Science

Cashew nutshell liquid (CNSL) is a by–product from cashew processing industries containing four naturally occurring phenolic compounds. This study investigated an extraction approach using CO2–expanded hexane. The central composite design (CCD) was employed in experimental design to investigate the effects and interaction of CO 2 mole fractions and extraction temperature on the CNSL yield and quality (Colour) from Steamed CNSL. The dissolution power of the CO2–expanded hexane was assessed by determining the solubility of CNSL during the initial stages of extraction at different extraction conditions. Findings indicated that higher CO2 mole fractions reduced CNSL solubility, while higher temperatures enhanced it. …

Integrated Decision-Support Framework For Enhancing Coastal Community Resilience Against Hurricane-Induced Hazards, Kooshan Amini, Tanmoy Palit, Abigail L. Beck, Jayant Patil, Tao Lu, Himadri Sen Gupta, Yousef Darestani, Et. Al

Michigan Tech Publications

Coastal communities face escalating threats from hurricanes, necessitating a shift from descriptive risk assessment to prescriptive, optimized portfolio planning to enhance resilience. This study introduces an integrated decision-support framework that couples high-fidelity, multi-hazard socio-physical system modeling with a multi-objective optimization model. The framework quantifies the cascading impacts of hurricane-induced wind, storm surge, and waves on a community’s interdependent buildings, transportation network, and detailed distribution-level electric power network (EPN), along with the resulting population dislocation and long-term recovery. It then identifies Pareto-optimal portfolios of mitigation strategies by simultaneously minimizing three conflicting objectives—economic loss, population dislocation, and recovery time—under various budget constraints. …

Converting Co2 Into Carbon Nanotubes Via Sequential Co2 Methanation And Methane Pyrolysis, Kaiying Wang, Hao Feng, Ahmad Helaley, Xiaoqing He, Bohong Zhang, Jie Huang, Xinhua Liang

Electrical and Computer Engineering Faculty Research & Creative Works

This study presents a sequential thermochemical catalytic process for converting CO₂ into carbon nanotubes (CNTs), achieving nearly 99% overall CO₂ conversion and solid carbon yields of up to 49% in a single pass. The overall transformation is divided into two thermodynamically favorable steps: (1) low-temperature CO₂ methanation to CH₄ over a sol-gel-prepared Ni87Ce_6.5Zr_6.5-SG catalyst, which achieved >95% CO₂ conversion at 250 °C in a single pass, and (2) subsequent methane pyrolysis to CNTs and H₂ over a Ni@Al₂O₃-IE core-shell catalyst, which showed improved stability and carbon …

Design Framework For Polymer Gel Treatments From A Database Of Field Projects, Baojun Bai, Munqith Aldhaheri, Mingzhen Wei

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This study compiles and analyzes data from over 125 published field projects around the world, covering nearly 900 treated wells. Building on those detailed studies, this paper distills the most important findings into a concise, practical, and actionable framework to guide where in-situ gel treatments should be applied, how they should be designed, and how their outcomes can be evaluated. The proposed workflow guides engineers through five integrated stages: screening appropriate gel types, designing formulation and injection strategies, predicting field response, evaluating treatment performance, and conducting iterative refinement with feedback loops to adjust designs based on observed outcomes. The framework …

Engineering Nanoelectrocatalytic Systems For Co2 And Nitrate Conversion Into Value-Added Chemicals, Abdelrahman Mohamed Abdelmohsen

Theses and Dissertations

The thesis addresses two major related environmental crises: nitrate pollution of water systems and the ever-increasing levels of atmospheric carbon dioxide. Both challenges are closely linked to anthropogenic disturbance of nitrogen and carbon cycles and require sustainable, energy efficient mitigation techniques. In this study, we investigate electrochemical conversion routes as a unified approach to convert these pollutants into value-added compounds: ammonia (NH3) via nitrate reduction (NO3-RR) and ethylene (C2H4) via carbon dioxide reduction (CO2RR). The first half of this work deals with the design and engineering of Cu-Zn alloy electrocatalysts for efficient NO3-RR. Tuning the alloy composition and surface nanostructure …

Oriented Electrospun Fibers Of Poly(Pro-Curcumin/Peg) Sequester Reactive Oxygen Species And Promote The Growth Of Schwann Cells, Jack W. Devlin, Payton R. O'Connor, Conrad H. Cheung, John T. Leman, Martin Oudega, Edmund F. Palermo, Ryan J. Gilbert

Chemical and Biochemical Engineering Faculty Research & Creative Works

In the biological injury microenvironment, pathologically elevated oxidative stress hinders healthy cell migration. Aligned electrospun fibers are used as tissue engineering scaffolds to support and guide the directionality of cell migration. The ability of cells in the central nervous system to sequester and quench reactive oxygen species is limited, and most electrospun fibers do not exert any antioxidant activity on contact. Thus, the challenge remains in designing a scaffold that can both guide cells to the injury site as well as sequester and quench excess free radicals, allowing cells to thrive and potentially regenerate. Curcumin is a well-known, potent antioxidant, …

Moisture-Induced Degradation And Mechanical Durability Of Mineral-Filled Polylactide (Pla) Composites, Barbara Szaraniec, Aleksandra Ptaszkowska, Alicja Rapacz-Kmita

Journal of Sustainable Construction Materials and Technologies

This study investigates the influence of mineral fillers on the hydrolytic stability and mechanical durability of polylactide (PLA) composites under accelerated aqueous ageing conditions. Composites containing halloysite nanotubes (HNT) and bentonite-based fillers (BM, BS, BSP) at 2 wt.% were prepared using a powder-coating and injection moulding approach. Accelerated hydrolytic degradation was conducted at 50 °C for up to six weeks. The degradation behaviour was evaluated through mass variation, water absorption, incubation medium analysis (pH and electrical conductivity), mechanical testing, surface observations, and contact angle measurements. The results revealed a clear filler-dependent response. Bentonite-filled composites exhibited increased water absorption and accelerated …

Applications Of Geosynthetics In Tunnels Construction: A Sustainable Approach To Carbon Footprint Reduction, Ibraheem Rais, Abdullah H. Alsabhan, Md. Rehan Sadique, Shamshad Alam

Journal of Sustainable Construction Materials and Technologies

The use of geosynthetics has transformed tunnelling practices by enhancing structural integrity, durability, and environmental sustainability. This review adopts a systematic literature review design, covering publications from 2000 to 2025 sourced from Scopus, Web of Science, ScienceDirect, and Google Scholar. The selected studies were screened based on relevance, quality, and focus on tunnelling applications, then thematically analyzed into four domains: geosynthetic types, applications, sustainability, and performance evaluation. This review focuses on the applications of various geosynthetics, including geotextiles, geogrids, geocomposites, geocells, and geomembranes, in tunnelling projects. These materials play crucial roles in reinforcing tunnel walls and slopes, improving load distribution, …

Investigation Of Portland Limestone Cement Blended With Biochar From Downdraft Gasification: Hydration Kinetics, Microstructure, Rheology, And Performance Mechanisms, Ugochukwu Ewuzie, Paul C. Ani, Abdulkareem O. Yusuf, Joseph D. Smith, Monday Uchenna Okoronkwo

Chemical and Biochemical Engineering Faculty Research & Creative Works

The widespread adoption of Portland Limestone Cement (PLC) in U.S. concrete production has necessitated research into commercially available supplementary cementitious materials (SCMs) for formulating high-performance, low-carbon blended binders with PLC. This study investigated the influence of biochar (BC) in biochar-PLC composites (CBCs), focusing on hydration kinetics, microstructure, rheology, pore-solution chemistry, compressive strength, and the underlying mechanisms. Biochar was produced via downdraft gasification at 850 °C and incorporated into PLC at 5, 7, and 10% substitution by mass. Isothermal calorimetry and hydration data modeled using the Knudsen equation revealed that BC retarded early hydration but improved hydration degree and later-age heat …

Investigations Of Carbon Dioxide Storage In Low-Temperature Reservoirs For Non-Leaking Storage, Md Nahin Mahmood

Doctoral Dissertations

Carbon dioxide (CO₂) injection into subsea or low-temperature water zones has emerged as a promising strategy for long-term, non-leaking CO₂ storage through the formation of solid hydrates. This research investigates CO₂ injection into Berea sandstone cores saturated with water under simulated subsea conditions, focusing on hydrate formation behavior across varying temperatures, pressures, and injection flow rates. Experimental results demonstrate that CO₂ hydrate formation under dynamic (flowing) conditions occurs at significantly higher pressure compared to static conditions reported previously. At temperatures ranging from 0 °C to 5 °C, dynamic hydrate formation pressures were observed to be approximately double. This can be …

Automating Distillation Column Internals Design Via Reinforcement Learning: A Hybrid Action Space Approach, Holden B. Broussard

Masters Theses

Distillation columns are the most used separation technique in all chemical fields. The design of column internals presents a hybrid action space problem, where trayed internal parameters are continuous and packed parameters are discrete; Hybrid meaning the action space consists of both discrete and continuous design parameters. Hybrid action spaces have presented a challenge in the reinforcement learning space, since the most robust algorithms are designed to handle specific action types. This research develops and validates a hierarchical multi-agent reinforcement learning framework that divides the action spaces into different agents. The Controller agent selects between internal types, the Soft Actor- …

Geological Carbon Storage In Deep, Low Permeable Shale Reservoirs: Insights From The Haynesville Formation, Louisiana, Himakshi Goswami

Masters Theses

As global initiatives to mitigate greenhouse gas emissions intensify, depleted unconventional shale gas formations have emerged as critical candidates for large-scale geological carbon storage (GCS). This study investigates the feasibility, dynamic trapping mechanisms, and operational optimization of CO₂ sequestration in deep, low-permeability shale reservoirs, using the Upper Jurassic Haynesville Shale in northwest Louisiana as a comprehensive case study. Compositional reservoir simulation (CMG GEM 2021.10) was performed using the SPE Haynesville dataset, with CO₂ injected at a rate of 10,000 ft³/day across single and multiple depth intervals spanning 11,290–11,314 feet. Results demonstrate that multi-depth injection significantly improves residual trapping, reduces buoyancy-driven …

Mitigating Surfactant-Gas Interactions In Associated Gas Reservoirs: A Simulation And Machine Learning Guided Approach, Francis Dela Nuetor

Masters Theses

Surfactant flooding is a promising chemical enhanced oil recovery (EOR) method for mobilizing residual oil through interfacial tension reduction and wettability alteration. However, its performance in associated-gas reservoirs can be limited by salinity, gas composition, surfactant adsorption, and possible chemical instability. This study investigates the effect of salinity on surfactant flooding efficiency using an integrated reservoir simulation and machine learning workflow. A synthetic three-dimensional reservoir model was developed in ECLIPSE using a 10 × 10 × 3 Cartesian grid to simulate surfactant flooding over a 300-day production period under salinity conditions ranging from 100 to 50,000 ppm. Key outputs, including …

Optimizing Co₂ Wag Flooding Parameters For Enhanced Oil Recovery And Formation Damage Control In Asphaltene Reservoirs Using Soft Experimentation, Derrick Amoah Oladele

Masters Theses

CO₂ Water Alternating Gas flooding has become an important enhanced oil recovery process in increasing oil production in medium to heavy oil reservoirs. However, CO₂ injections have the potential to cause asphaltene destabilization, leading to precipitation, deposition, and pore plugging. This study evaluated and optimized the effect of CO₂ flooding parameters to maximize oil recovery and minimized formation damage. Eclipse 300 compositional reservoir simulator was used to assess the effect of CO₂ Water Alternating Gas (WAG) Injection Rate, WAG Ratio, and CO₂ Water Alternating Gas (WAG) Injection Pressure on the reservoir. Predictive models for Cumulative Oil Production (FOPT) and Asphaltene …

S-[2-(Hydroxyamino)-2-Oxoethyl]-O-Octyl-Dithiocarbonate Ester (Ehaox): Performance And Adsorption Mechanism, Yue Zhou, Jiaxiang Li, Hongli Fan, Zhilong Li, Yuesheng Gao, Tian Lin, Haiyan Tang, Tingting Wang, Wei Sun

Michigan Tech Publications

This study explores the interfacial interactions between a novel collector, S-[2-(hydroxyamino)-2-oxoethyl]-O-octyl-dithiocarbonate ester (EHAOX), and bastnaesite mineral surfaces during selective flotation. Compared to conventional octylhydroxamic acid (OHA), EHAOX demonstrated superior recovery, achieving an over 40% absolute increase in recovery compared to octylhydroxamic acid (OHA) at the same collector concentration (1 × 10⁻⁵ mol/L) and pH 8.0, and selectivity for bastnaesite, attributed to its optimized hydrophobicity (supported by CLogP calculations). Mechanistic studies via zeta potential, UV/vis spectroscopy, and FTIR revealed the formation of a complex composite via chemisorption between EHAOX and Ce³⁺ sites on the bastnaesite surface, with coordination occurring …

Design And Development Of A Resonance Ignition System Using Gaseous Propellants, Benjamin J. Hoefer

Master's Theses

This work presents the development and experimental evaluation of a resonance igniter (RI) operating with premixed gaseous propellants. Resonance ignition is a non-electrical ignition concept in which an underexpanded jet impinges on a closed-end Hartmann–Sprenger tube (HST), generating cyclic compression and expansion waves that rapidly heat gas near the tube endwall. A modular experimental system was designed and built to investigate resonance ignition using methane–air and methane–oxygen mixtures. The system includes a supplemental configuration that may probe for mixture conditions favorable to ignition, informing RI testing. Pressure and temperature measurements were used to characterize pressure control, mixture pressure ratio (MPR), …

Improving The Reliability And Performance Of A Supersonic Indraft Tube Wind Tunnel, Christian J. Kaml

Master's Theses

Access to supersonic testing is increasing in demand, and wind tunnels remain one of the safest and most cost-effective methods for gathering high-speed flow data. Despite being more economical than alternative options, supersonic wind tunnel facilities often require substantial investment to construct, operate, and maintain.

The novel indraft tube tunnel architecture was conceived as a high-speed flow testbed that incorporates features of both Ludwieg tubes and indraft wind tunnels to maintain costs low enough to be accessible even to small universities. This design was first developed and tested in 2018 at California Polytechnic State University, featuring a cost per test …

Multiple-Nozzle Sprays: Comparison To Single-Nozzle Sprays And Role Of Directional Conditional Filtering, Farzad Hossain, Matthew J. Cleary, Yasir M. Al-Abdeli, Mehdi Khiadani

Research outputs 2022 to 2026

Spray-based droplet evaporation systems used in desalination and cooling applications depend on both nozzle arrangement and the interpretation of measured droplet behaviour. This study examines (i) how multi-nozzle configurations differ from single-nozzle characteristics and (ii) how ensemble-averaged measurements change when droplets are separated according to their motion direction (upward or downward). Atmospheric water sprays generated by full-cone spray nozzles were investigated using Particle Image Velocimetry (PIV) for droplet axial velocity measurements and Shadowgraph imaging to determine droplet size and count. Directional filtering was performed using Large Eddy Simulation (LES), validated against experiments. Single- and dual-nozzle configurations were tested with horizontal …

Green-Synthesised Nh₂-Mil-101(Cr) Mof–Reinforced Starch Bioplastic Films For Sustainable Food Packaging, Shima Jafarzadeh, Yasaman Esmaeili, Moon Paul, Seyedeh Zahra Haeri, Colin J. Barrow, Mina Dokouhaki, Masoumeh Zargar, Minoo Naebe

Research outputs 2022 to 2026

This study introduces a green, aqueous synthesis approach for NH₂-MIL-101(Cr), avoiding toxic organic solvents while preserving its high crystallinity, porosity (>1000 m2/g), and amino functionality. To develop sustainable packaging materials the synthesized MOF was incorporated into sago starch-based bioplastic films across control 0%, 1%, 3%, and 5% treatments. Nanoparticle characterizations via SEM, TEM, FTIR, XRD, and nitrogen adsorption-desorption isotherms confirmed a porous, crystalline structure (100–300 nm) with a surface area exceeding 1000 m2/g. Film characterizations using SEM, FTIR, color analysis, tensile testing, TGA, and UV-Vis spectroscopy revealed that the 3% treatment offered the best balance, with tensile strength increasing …

Nanofluid Flooding As A Sufficient Alternative To Waterflooding For Incremental Oil Recovery From Carbonate Reservoirs, Sarmad Al-Anssari, Dhifaf Sadeq, Hassanain A. Hassan, Ahmed Hamid Al-Taie, Hasan Ali Abood, Mohammed Mahdi, Zain Ul Abedin Arain

Research outputs 2022 to 2026

Oil recovery from carbonate reservoirs is one of the critical challenges in the oil industry due to the strongly oil-wet nature, natural fractures, and the heterogeneity of carbonate rocks. Subsequently, waterflooding can only displace oil from large fractures, leaving the majority of oil trapped in the rock matrix. This work suggests that nanofluid flooding, as a predesigned flooding method, is an alternative to conventional waterflooding. Various concentrations of silica nanofluid at different nanoparticle concentrations were formulated and systematically investigated for their characteristics, stability at reservoir conditions, and their influence on wettability and oil recovery. Silica nanoparticles were sustainably synthesized from …

Gas Adsorption Behavior In Organic-Rich Carbonate Source Rocks: Insights Into Hydrogen Storage, Methane Recovery, And Co2 Sequestration In Oil Shales, Muhammad Usman, Muhammad Ali, Tawanda Matamba, Alireza Keshavarz, Stefan Iglauer, Hussein Hoteit, Volker Vahrenkamp

Research outputs 2022 to 2026

Gas adsorption in unconventional petroleum source rocks, e.g. organic-rich mudrocks and shales, is influenced by significant heterogeneities in organic and inorganic composition, structure, and pore networks. An understanding of the interplay between these properties is essential for optimizing hydrocarbon extraction, CO2 sequestration, and hydrogen storage in such reservoirs. Herein, the factors controlling hydrogen, methane, and CO2 adsorption in unconventional organic-rich Jordan source rock samples are investigated, focusing on the roles of organic matter, mineral composition, and textural properties. The samples are characterized via multiple techniques, followed by adsorption experiments. The results reveal that H2 has the lowest adsorption capacity, being …

Glass Transition Temperature Of Plga Nanoparticles And The Application In Drug Delivery, Guangliang Liu

Dissertations

The glass transition temperature (T_g) of poly(D,L-lactic-co-glycolic acid) (PLGA) nanoparticles plays a crucial role in governing molecular mobility, diffusion, and consequently, drug release kinetics. However, the interaction among residual surfactant, drug effect, nanoscale confinement, and release medium on T_g remains insufficiently characterized. This study aims to bridge this gap by correlating the thermal behavior of PLGA nanoparticles with their drug release behavior under physiologically relevant conditions.

In the present study, PLGA nanoparticles were synthesized using both nano-emulsion and surfactant-free nano-precipitation approaches. The influence of residual surfactants - poly(vinyl alcohol) (PVA) and didodecyldimethylammonium bromide (DMAB) - was systematically …

Membrane-Engineered Nanotherapeutic Platforms For Drug Delivery: Hollow Fiber Membrane Synthesis Of Lipid Nanoparticles, Biomimetic Nanocarriers, And Nanobubbles, Zhixiang Liu

Dissertations

Lipid-based nanocarriers have emerged as a cornerstone technology for RNA therapeutics, enabling effective intracellular delivery for applications ranging from vaccination to gene regulation. However, current manufacturing approaches, particularly microfluidic-based platforms, face inherent limitations in scalability, throughput, and structural tunability due to their reliance on confined channel geometries and restricted mixing architectures. Addressing these challenges requires fundamentally new strategies that decouple nanoparticle formation from traditional microscale flow constraints while maintaining precise control over physicochemical properties.

This dissertation presents a comprehensive framework for the design, engineering, and application of advanced lipid-based nanocarriers, centered on a hollow fiber membrane (HFM)—assisted nanopore-mediated assembly platform. …

Machine Learning-Driven Prediction And Mechanistic Insight Into Co2 Adsorption On Biomass-Derived Activated Carbons Using Explainable Ai (Xai), Dalia A. Ali Dr.

Chemical Engineering

To improve CO2 uptake in Biomass-Derived Activated Carbon (BDAC), this study develops a multiscale hybrid digital twin framework. By integrating microscopic descriptors from Density Functional Theory and Molecular Dynamics (DFT/MD) with experimental data from 63 chemically diverse biomass precursors, a Gaussian Process Regression (GPR) model was developed using the Materń 5/2 Automatic Relevance Determination (ARD) kernel. The framework achieved high internal training accuracy (R2 = 0.968) and Root Mean Square Error (RMSE = 0.2552), while providing a realistic generalization baseline across heterogeneous precursors with a 5-fold Cross Validated (CV) R2 of 0.1567 and CV RMSE of 0.283. Explainable Artificial Intelligence …

Modulating Electronic Structure With Linearly Fused Pyrazine Units For High-Voltage And Stable Zinc-Organic Batteries Cathode, Min-Jian Zhao, Li-Bin Zhang, Jin-Tao Wang, Kun Ding, Hai-Mei Liu, Yong-Gang Wang

Journal of Electrochemistry

High-voltage n-type organic cathode materials are critical for constructing zinc-organic batteries (ZOBs) with high energy density and long cycle life. However, the intrinsically unfavorable electronic structures and relatively high LUMO energy levels of most n-type materials often lead to sluggish kinetics, high solubility, and suboptimal discharge voltages (< 0.8 V). Here, we design a small molecule, quinoxalino[2’,3’:5,6]pyrazino[2,3-f][1,10]phenanthroline (DPQP), as a ZOB cathode by introducing locally electron-deficient motifs into the conjugated backbone of aromatic compounds. The linearly fused pyrazine units extending the pyrazine–benzene framework effectively optimize the electronic structure, thereby significantly enhancing the discharge voltage. Meanwhile, the expanded π-conjugated plane suppresses dissolution and accelerates charge-transfer kinetics. Benefiting from these features, the DPQP electrode exhibits an exceptional increase in average operating voltage from 0.61 V to 1.07 V (vs. Zn²⁺/Zn) at 0.1 A·g^–1, with an overpotential of only 140 mV. Notably, no discernible voltage decay occurs as the current density increases, indicating rapid and highly reversible redox kinetics. Furthermore, the DPQP cathode delivers outstanding cycling stability, maintaining over 2000 h of continuous operation at 0.1 A·g^{–1 …}

(Co,Ni,Mn,Cu,Zn)O High-Entropy Oxide Nanotubes As Efficient Bifunctional Electrocatalyst For Oxygen Evolution And Hydrazine Oxidation Reactions, Pan-Yan Chen, Wan-Wan Wu, Heng Bian, Wei-Wei Li, Xin-Sheng Zhao, Lu Wei

Journal of Electrochemistry

High-entropy oxides (HEOs) present significant scientific challenges in both design and synthesis due to their multielement and high-entropy nature, which involves complex combinations of multiple metal cations and oxygen anions, typically arranged in equimolar ratios to achieve structural stability. Herein, one-dimensional (Co,Ni,Mn,Cu,Zn)O high-entropy oxide nanotubes (HEO-NTs) are fabricated by means of a gradient electrospinning strategy with a tailored polyvinyl alcohol (PVA) molecular weight distribution and controlled pyrolysis. Benefiting from the HEO features and the synergistic effect of multicomponent sites, the as-synthesized (Co,Ni,Mn,Cu,Zn)O HEO-NTs exhibit exceptional bifunctional electrocatalytic activity for the oxygen evolution and hydrazine oxidation reactions (OER/HzOR). This study offers …