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Vapor-Liquid Equilibria System : Acetone, Ethylene Dichloride, Toluene, Donald Warren Krech

Theses

The vapor-liquid equilibria data have been determined for the ternary system acetone (C₃H₆O), ethylene dichloride (C₂H4Cl₂), and toluene (C₇H₈), using a modified Othmer continuous distillation equilibrium still. The data were correlated to theoretical values using the Margules three-suffix ternary equations.

Although equilibria data are available in the literature for the three binary systems, new data were collected for each system to evaluate the validity of the experimental apparatus and techniques. Consistency of the experimental data was demonstrated.

For the acetone-ethylene dichloride binary system, where similar apparatus was …

Zirconium-Hafnium Equilibria, Edwin Otto Eisen

Theses

Equilibria in the thiocyanate-methyl isobutyl ketone process for the separation of zirconium and hafnium were studied. The effects of average thiocyanate concentration, feed acidity, and feed zirconium concentration on the separation factor of hafnium and the distribution coefficients of zirconium and hafnium were investigated. The hafnium separation factor was significantly dependent on the feed acidity but only slightly affected by the average thiocyanate concentration. No conclusion was reached about the effect of the feed zirconium conoentration on the hafnium separation factor. The polymerization of thiocyanic acid was found to be strongly dependent on the average thiocyanate concentration.

The Electrolytic Refining Of Tellurim, Patsy Patrick Napolitano

Theses

The purpose of this investigation was to obtain new and to extend existing information on the method or methods used to produce high purity Tellurium using electrolytic refining methods. All available methods were investigated, in order to substantiate or disprove the available procedures. The main concern of this investigation is the outlined procedure to produce a metallic Tellurium product of 99.9999% purity. Any information which proved to be correct was used in attaining the ultimate goal of this thesis.

A literature search revealed only one good source of information. A United States patent, No. 2,258,963, dated October 14, 1941, issued …

Vapor-Liquid Equilibria System : Carbon Tetra-Chloride, Toluene, N-Heptane, Joel Philip Pearlstein

Theses

A study was made of the vapor-liquid equilibria of the ternary system: carbon tetrachloride (CCl₄), n-Heptane (C₇H₁₆) and Toluene (C₇H₈). An Othmer still was used for the determination of the equilibria and the liquid and vapor compositions were ascertained by refractive index and density measurements. A comparison between experimental values and theoretical values was made using the Margules 3-suffix ternary equations for the correlation. Although the Margules equations did not correlate the experimental data very well, this is most likely due to the fact that the ternary solution was close …

The Stability And Response Of An Automatically Controlled Liquid Level System, Milton Kalman Rosen

Theses

Stability and response of automatically controlled liquid level systems was investigated theoretically by transient and frequency response analysis and experimentally on a laboratory liquid level system.

Transfer functions were derived for each component and were used to describe the response of the experimental system. The effect of measurement time constants on system performance was experimentally investigated. Poor control, but not instability, resulted from an increase in measurement time constant. The behavior of the system at various operating loads was determined experimentally. The system was unstable at the maximum measureable flow rate, but stable at all other loads. Theoretical response curves …

The Evaluation Of A Three Mode Temperature Controller By Pulse Techniques, Sanford Allen Schram

Theses

Work was performed to evaluate a commercial three mode temperature controller by pulse techniques. The extensive calculations were performed on an I. B. M. 1620 general purpose computer. Bode diagrams are presented to graphically show the instrument's dynamic response. The conclusions reached are as follows:

1. Pulse tests provide a quick method of testing the dynamic response of instruments.

2. A computer should be used for the efficient calculation of results from pulse tests.

3. Limitations of pulse tests are not yet defined but it appears that an increase in the energy of the input pulse leads to an increase …

Urea Adduction Of Oleic Acid, Leroy A. Dahm

Theses

The purpose of this project was to study the separation of the fatty acids and waxes found in cranberry skins by means of the formation of urea adducts. Current literature does not indicate equilibrium and rate data as controlled by mixing energy for the separation. Therefore this rate data was determined for the adduct formation of oleic acid, one of the constituents of cranberry skins.

A saturated aqueous solution of urea was used in the preparation of the urea adduct of oleic acid. Methyl isobutyl ketone and methanol were investigated as solvents for the fatty acids. Methyl isobutyl ketone was …

The Corrosion Of Zinc-Stainless Steel Couples In Flowing Sea Water, Henry Shaw

Theses

The effect of sea water flow on passivated stainless steel 304 coupled to high purity zinc was studied for more than 1000 hours at 23°C. The corrosion of both members of the couple increased over that of the metals alone. Zinc suffered severe pitting while the Stainless Steel was not visibly corroded, When the metals were exposed alone, zinc corroded uniformly while the stainless steel was not affected at all. The use of zinc coupled to Stainless Steel is not recommended in systems exposed to sea water.

The Effect Of Liquid Surface Tension On Wire Mesh Entrainment Separators, Herbert Franklyn Schroeder

Theses

The effect of liquid surface tension on the capacity of a wire mesh entrainment separator was studied. An air-rater system was used and, the surface tension of the water was reduced through the use of surfactants.

Five test series were run, each with a different surface tension of water. The surface tensions examined covered the range of 30 dynes/cm to 70 dynes/cm. For each test run series, the effect of liquid loading was investigated. Liquid loading rates were varied between 55 and 550 lbs/hr/ft².

Entrainment separator capacity was found to vary linearly with liquid surface tension. As surface tension decreased, …

Packed Bed Heat Transfer, Anthony William Sposaro

Theses

The use of various published correlations to determine apparent thermal conductivities was found to give results of differing ma; magnitudes. For this reason when these values were utilized in the theoretical relationships proposed by McAdams:

tw-t2/tw-t1 = 0.692e^-23.14X + 0.1312e^-121.9X + 0.0535e^-299.6X

in which X is defined as

X = (KaL/CpGoD²t)

For packed bed systems the results were found to be inconsistent.

In this investigation a dimensionless equation:

Ka/kg = 0.00105 (DpGo/εpμ)^1.32

has been developed which permits the prediction of apparent thermal conductivities to air flowing through a 1 inch tube picked with glass …

Power Consumption In Horizontal Cylindrical Tanks, John J. Schlager

Theses

The general correlation of Power Number vs. Reynolds Number for flat six blade turbines in a horizontal cylindrical tank without baffles has been determined. The correlation has been found to apply to this system and corresponds to the 4 - 10% baffle region in the vertical cylindrical tank as determined by Rushton, et. al. ⁽¹⁾

An important variable to be considered is the length of tank to impeller diameter ratio which was found to seriously affect the power consumption.

A power fall off was observed at high Reynolds Numbers and coincided with visual vortexing. This power fall off was found …

A Study Of The Dissolution Of Zr-O Alloys In Hydrofluoric Acid, Wayne Gilbert Custead

Doctoral Dissertations

"The purpose of this investigation was to ascertain and explain, if possible, the effect of oxygen in the metal on the kinetics and electrochemistry of the reaction of zirconium in hydrofluoric acid solutions. This entailed the determination of the effect of oxygen on the dissolution rates, activation energies, dissolution potentials, and difference effect for zirconium in hydrofluoric acid and hydrofluoric-hydrochloric acid mixtures.

The alpha-phase solid solutions of oxygen and zirconium were synthesized by the powder-metallurgy technique. Both the alloy analysis and dissolution rates were obtained by the gas evolution method according to the reaction:

ZrO_x + 4HF → ZrF …

Lattice Parameters, Densities And Imperfections In Indium And Indium-Cadmium Alloys Rich In Indium, Paluri Bhimeswara Rao

Doctoral Dissertations

"An investigation of perfection of the structure of the indium-cadmium system was suggested by the interesting properties of indium and its cadmium alloys. The lattice of indium, though tetragonal, may be considered as distorted cubic, its axial ratio being 1.0767 at 20°C. Furthermore earlier studies have revealed a transformation of the tetragonal structure to cubic in the presence of cadmium.

To determine the perfection or soundness of the indium and indium-cadmium alloys rich in indium, pure indium (99.999 per cent purity) and eight samples of the indium-cadmium alloys ranging in composition from 2.977 to 10.015 per cent by weight of …

Detection Of Rust Formed Under Paint Films, James Larry Inglis

Masters Theses

"Corrosion is an evil that has plagued man since before the iron age. Three ways of controlling corrosion are: 1. alloy the metal to make it chemically inert to corrosion, .2. change the surroundings to a noncorrosive atmosphere, and 3. isolate the metal from the corrosive atmosphere, as for instance by the application of a number of coats of paint that has been found to be the most economical method.

At present, there is no reliable method of testing the effectiveness of a paint film that does not require the corrosion products to destroy the paint film and show themselves …

A Study Of The Permeability And Separation Of Carbon Dioxide And Hydrogen By Gaseous Diffusion Employing Barriers Of Polystyrene, Carl J. Wallace

Masters Theses

"The purpose of this investigation was to study the permeability and separation of carbon dioxide and hydrogen by gaseous diffusion employing barriers of polystyrene. The offset of temperature and barrier thickness on the permeability and separation of carbon dioxide and hydrogen wore Investigated for barriers of one, three, and five-mil thicknesses and for temperatures of 26, 35, 45, and 50 degrees centigrade.

With an increase in barrier thickness of one to five- mils, the permeability of carbon dioxide decreased to one-fourth of its value at the one-mil thickness. The hydrogen permeability decreased to approximately two- thirds of its value at …

The Experimental Determination And Prediction Of Ternary-Liquid Equilibria Data, Risdon William Hankinson

Masters Theses

"Although the field of liquid extraction is of increasing importance in today's chemical industry, the ternary-liquid data so necessary to the design and study of extraction operations are available in the literature only to a limited extent. During the twentieth century, approximately 120 ternary-liquid systems have been studied. However, limiting solubility data have been reported for approximately one-third of these systems, and about 30 per cent of the equilibria data reported for the remainder of these systems are incomplete or inaccurate.

Within limits, liquid equilibria data may be calculated for a ternary system from the properties of its constituents which …

Fractionation Of Fission Elements By Electrodialysis, George Joseph Bub

Masters Theses

"The development of nuclear power has presented countless problems to the scientists and engineers of today. A problem of extreme importance is the disposal of radioactive wastes. Another is the recovery of some of the useful radioisotopes from fission product waste solutions. This investigation is concerned with the recovery of some of the fission elements for use in radiochemical and medical research and in industry.

At present little effort is made to recover useful fission elements. The fission product waste solutions are treated to reduce the volume and are stored until the radiological hazard is reduced and are then disposed …

The Dissolution Of Magnesium In Strong Acids, Baldev K. Bhatia

Masters Theses

"The rapidly growing demand for magnesium and magnesium-base alloys in the manufacture of aircraft has led to a great amount of research into the corrosion characteristics of these materials. The result of such research has been the development of suitable magnesium alloys and protective coatings to retard corrosion.

The standard electrode potential of magnesium lies between -2.35 volts and -2.54 volts at 25⁰C (hydrogen scale). Thus, magnesium lies next to aluminium in the electrochemical series of elements. The atmospheric corrosion of magnesium has been studied under conditions of indoor and outdoor exposure. Under these conditions the initial attack is formation …

Permeability Of Poly (Ethylene Terephthalate), James G. Harvey

Masters Theses

"Corrosion is a phenomenon which has been the subject of extensive research, in order to find a way to control or completely stop it. Two general methods, either placing the material which corrodes in an anti-corrosive atmosphere or protecting the material which corrodes from the corrosive atmosphere, are the chief means of preventing corrosion today.

The second method is probably most widely used presently. One of the most important methods of protection is by means of organic protective coatings, or paints, but at best these only retard corrosion, due to the fact that corrosive media e.g. water vapor, ions etc. …

New Genera And Species Of Myripristid Fishes, In The Gulf Coast Cenozoic, Known From Otoliths (Pisces, Beryciformes)

School of Mines and Metallurgy Bulletins

Studies of fossil and Recent otoliths (sagittae) supply an important line of evidence, bearing on classification of teleost fishes, supplementary to that of anatomy, osteology, and "phylogenetic" paleoichthyology.

Squirrelfishes ( " Holocentridae" of authors) are generalized forms in which evolutionary divergence of some mag nitude is reflected in unpreservable details of anatomy, inconspicuous skeletal structures, and striking differentiation of the sagittae. Otoliths show the holocentroid complex to consist of one homogeneous unit (l\fyripristidae, elevated) and another more heterogeneous group (Holocentridae, restricted). These lineages have been separate. at least since the middle Eocene.

A revised classification, based on available lines of …

Heat Transfer Coefficients Of Non-Newtonian Slurries In Laminar Flow, Robert Frederick Roth, David B. Swanson

Theses

A total of 51 heat transfer runs were made in the first 25 runs, slurries of half micron and finer kaolin at 3.0, 5.6, 9.6 and 12.9% solids were used. Slurries of two microns and finer kaolin at 10.1, 13.7, 20.4 and 23.1% solids were used in the remaining 26 runs.

The Reynolds Numbers ranged from 0.9 to 2,020 for the 51 runs.

The data was correlated by the following equation:

H_f/C_bV_bP_b C_bR_b/K_b ^2/3 = 0.70 DV_bP_b/R_b ^-2/3

for an L/D ratio of …

Electrolytic Amalgam Reduction Of Cinnamic Acid, Alan Ira Mytelka

Theses

The use of sodium amalgam and potassium amalgam to reduce cinnamic acid to hydrocinnamic acid was accomplished in two concentrically constructed cylindrical cells.

In the outer cell, liquid amalgam was prepared electrolytically using a mercury cathode. The amalgam was moved by a rocking motion into the inner cell where the cinnamic acid dissolved in ethanol was reduced to hydrocinnamic acid. The actual percent conversion as measured by iodine numbers varied from 6.0% to 567, the percentage depending upon the number of coulombs passed into the electrolytic cell, the amalgam used, and whether or not stirring in the inner reduction cell …

Surface Area Of Small Particles, Richard Henry Ullrich

Theses

Experiments using glass beads and water were performed to obtain data to relate evaporation rates with the total surface area of a small sample of particles. The object of this work was to explore the possibility of devising a new method of determining surface areas which would be simple, rapid and non-destructive.

One gram samples of glaze beads ranging in diameter from 840 to 150 microns were wet with water and dryed to constant weight under controlled conditions. Residual water was removed by continued heating at a higher temperature. The experimental conditions were deliberately simple in keeping with the purpose …

Physical And Electrical Properties Of The Manganin-Type Alloys, Wallace William Macintosh

Theses

This thesis is a report on the physical and electrical properties of the manganin-type alloys as compiled from the published literature on the subject. The peculiarities of these alloys, as related to mechanical history, heat treatment, and composition, are discussed. Empirical formulae, by which the temperature coefficient of resistance, the temperature of maximum resistance, the temperature-resistance equation, and the thermoelectric emf of these alloys against copper may be calculated, are shown.

A comparison of the effect of elongation on the specific resistivity of several sizes of manganin wire is made on the basis of experimental results. The effect of impurities …

The Electrolytic Preparation Of Perbromates, Robert M. Casciano

Theses

Since perchlorates and periodates can be formed by the electrolytic oxidation of chlorate and iodate solutions and since bromine lies between chlorine and iodine in the periodic table, it should be possible to electrolytically prepare perbromates. As yet, however, perbromates have not been prepared by any methods.

It was desired to attempt to prepare perbromates electrolytically and to definitely show their presence or absence after electrolysis. In order to accomplish this a new method of analysis was developed.

This work has shown that perbromates cannot be prepared by the electrolytic oxidation of bromate solutions under various conditions of temperature, current …

Effect Of Elevated Temperature On Efficiency Of Corrosion Inhibitors, Walter Dzingala

Theses

An experimental program was set up to investigate the effect of temperature on the protection efficiency of various inhibitors of metal corrosion. Contrary to most studies, an appreciable amount of the work was done with the corrosive effect being determined on the metal specimens that were exposed first to the inhibitor, then to air at different temperature, and finally to the corrosive medium with no inhibitor present. The purpose being to determine whether the inhibitor treatment would provide a permanent protection for a metal surface or would it be necessary to furnish a continuous supply of the inhibitor to the …

Extrapolation Of Viscosity Data For Liquids, Julius Irwin Gnapp

Theses

The method of finite-difference recurrence relations* is here applied to viscosity-temperature data to determine whether it offers an improved means of extrapolating such data. The best of the existing parametric correlations, which is considered to be that of Andrade, was found to be subject to important departures from linearity and dependent upon the particular data points used in its formulation. The proposed method is non-parametric in that it does not require an assumption of the explicit function relating viscosity with temperature. Instead, it assumes that there is a linear relation between successive values of viscosity at equal intervals of temperature. …

Catalytic Activity Studies In Aromatic Sulfonation, William Marvin Jayne Jr.

Theses

The object of this investigation has been to determine the catalytic activity of several inorganic materials in promoting the sulfonation of aromatic organic compounds. Initial work involved sulfonation of p-nitroaniline with an excess of sulfuric acid. However, due to insufficient precision of the method of analysis, this system was abandoned. Thereafter, the study was concerned chiefly with the benzene and other aromatic compounds in nitrobenzene solution. This phase of the work proved to be successful, and the results are reported in the text of the thesis.

The author gratefully acknowledges the suggestions and counsel given throughout these investigations by Professor …

A Simplified Procedure For Diffusion Coefficients From Cation Exchange Studies, Robert Peter Lanyon

Theses

The purpose of this investigation was to extend the data and to improve the procedures of previous investigators (1), (2), and (3), in the study of diffusion coefficients in aqueous media.

The main contribution of this investigation is the elimination of the tedious work of size grading, drying, weighing, and rehumidification of the Dowex 50 W - X8 resin, which is used to determine the ion exchange rates for the cations under consideration, The simplified procedure measures the resin volume by displacing a known volume of water. The method of calculating diffusion coefficients follows the procedure of (1), (2), (3), …

Binary Vapor Liquid Equilibria Isobaric Systems, Ira Lichtenstein

Theses

Oalculations of activity coefficients for thirty isobaric binary systems from vapor-liquid equilibria data were made using the Gilmont equation© An extensive literature survey showed the Gilmont equation provides an excellent means of correlating equilibrium data in most binary isothermal systems° However, the Gilmont equation’s applicability to isobaric systems had not been satisfactorily proven, and became the object of this investigation.

The Gilmont equation gave satisfactory correlation of the binary isobaric data for various systems. The correlation was found to improve as the systems approached ideal behavior. The introduction of a temperature correction to the relative volatility, term improved the correlation …