Digital Commons Network^™

Computer Solutions To Depletion Drive Hydrocarbon Systems, Tu Kao Chen

Masters Theses

"Three computer analyses of oil production by depletion drive have been developed. These analyses, Tarner's method of depletion drive oil production prediction, depletion drive performance productions of Schilthuis, and depletion drive calculations by a finite difference material balance, have been programmed for computers having Fortran IV compilers and a minimum of 40 K bytes of core storage capacity. Modifications have been incorporated in the last two techniques for (a) constant volume injection of produced gas, (b) the presence of a gas cap, (c) gas-cap injection of produced gas volumes, (d) varying water encroachment and production, and/or, (e) varying sweep efficiencies …

Mass Transfer From A Torus Shaped Body, Kamalesh Suryakant Desai

Masters Theses

"A mathematical model for molecular diffusion in a torus was derived. Handlos and Baron have assumed a system of tori in their eddy diffusion model for liquid-liquid extraction from droplets. However, the effect of torus curvature was neglected in their studies. Since they assumed the torus could be represented by an infinite cylinder. In this study, the effect of torus curvature was considered on the concentration profile and the fraction of the solute extracted. The partial differential equation describing the model consists of three independent variables, and a finite difference technique was employed for the solution of the mathematical model. …

A Kinetic Study Of Ti⁺³ Oxidation To Ti⁺⁴ In Hydrofluoric Acid Solutions, Kuo-Shein Shen

Masters Theses

"The purpose of this investigation was to study the oxidation rate of Ti⁺³ to Ti⁺⁴ in hydrofluoric acid solutions in the absence of air. The concentration of hydrofluoric acid was varied from 0.25 to 2.00 M and the concentration of titanium from 0.05 to 0.50 M. The temperature was controlled at 25⁰C. The reaction rate was relatively slow. In most instances, less than 50 percent of the Ti⁺³ was oxidized during a period of 100 hours"--Abstract, page vii.

Velocity Profiles In Viscoelastic Drag Reducing Solutions, Luis Gustavo Florez E.

Masters Theses

"Turbulent velocity profiles in viscoelastic drag reducing solutions were measured using hot-film anemometer and Pitot tube techniques. Data were obtained in a solution of one per cent aluminium [sic] dioleate in toluene and in 0.2 and 0.4 per cent solutions of polyisobutylene (PIB) L-200 in cyclohexane. Velocity profiles were also obtained for comparison in toluene and cyclohexane by both techniques. By integrating the Pitot tube velocity profiles, large flow rate discrepancies between integrated and measured flow rates were found for the drag reducing polymer and soap solutions. This discrepancy was not observed in the hot-film anemometer measurements. The hot-film anemometer …

The Economics And Design Of Desalination By Evaporation Through Porous, Water-Repellent Membranes, Kuei-Hsiung Yang

Masters Theses

"The economics of desalination by evaporation through porous, water-repellent membranes has been studied in this investigation. Using reasonable assumptions this desalination process was found to be economical with the principal advantage being the simplification of multi-stage flash-type evaporation. Based on this process, two different methods were designed and studied by means of computer calculations for a 10 million gallons product water per stream day desalting plant. One method was based on a membrane evaporator and a heat exchanger and was designated Method I; and a combined evaporation-heat exchanger system was designated at Method II. The major factors affecting the economics …

Kinetics Of The Lactic Acid-Butyl Alcohol Esterification Reaction, Joel Howard Kaplan

Dissertations

Kinetic and equilibrium data for the esterification reaction of monomeric lactic acid with normal butanol were determined in a series of experiments utilizing a batch stirred tank reactor. The variables studied were temperature and catalyst concentration. The kinetic data were successfully represented by the integrated equation for a second order reversible reaction.

Rate constants were obtained at three temperature levels and four catalyst levels. The observed rate constants in the catalytic reaction were linearly correlated with catalyst concentration and also satisfied the Arrhenius criterion. The activation energy and frequency factor for the uncatalyzed reaction were determined to be 13,190 calories …

Current-Potential Effects Of Trace Impurities In Manganese Electrowinning-Ii, Bipinchandra Govindlal Shah

Theses

The effects of trace non-metallic impurities, found in manganese electrowinning solutions, on cathode current-potential curves have been investigated. Five impurities, e.g., Sulfur-dioxide, Ammonium Sulphide, Urea, Thiourea, and Gelatine were studied.

In the first phase of the study the effect of individual impurity on the standard polarization curve was determined for a range of concentration. It was observed that these impurities did not affect the standard polarization curve.

In the second phase the above observation was confirmed by using cobalt as metallic impurity in addition to the non-metallic impurity. A marked effect on the standard polarization curve was observed due to …

Fugacity And Activity Coefficients For The N-Butane-Nitrogen System, Richard E. Walter

Theses

Fugacity and activity coefficients were calculated for the nitrogen-n-butane system at 310°, 340°, 370°, and 400°F. in 100 atmosphere pressure intervals from 100 to 700 atmospheres for the pure components and mixtures of 10, 30, 50, 70, and 90 mol% n-butane. Calculations were based on a method proposed by Van Ness. This calculation procedure combines an analytical solution utilizing the Redlich and Kwong equation of state with a graphically obtained correction factor.

Vapor-Liquid Equilibria System : Chloroform, Carbon Tetrachloride, Isopropanol, Barnet H. Bursack

Theses

A study was made of the vapor-liquid equilibria of the ternary system: Chloroform (CHCl₃), Carbon Tetra-chloride (CCl₄) and Isopropanol (C₃H₈O). An Othmer still was used for the equilibria determination. Refractive index and density measurements were used to determine liquid and vapor compositions. A comparison between experimental and theoretical values was made using the Margules 3-suffix ternary equations for the correlation.

It was necessary to investigate the vapor-liquid equilibria of each of the three binary systems to evaluate the techniques and equipment used and obtain new data. Only one previous investigation of the …

Kinetics Of Hydrolysis Of Butyl Lactate, Peter Pommers

Theses

The acid catalyzed hydrolysis of butyl lactate with water, using lactic acid to achieve a homogeneous solution, was studied.

Experiments at various temperatures were run under catalyzed and uncatalyzed conditions. The course of the hydrolysis was followed by titrating the acidity of the reaction mass at certain time intervals. From the results of these titrations and from the experimental determinations of the equilibrium constant, the reaction velocity constants for the hydrolysis of butyl lactate were calculated. The velocity constants were found to range from .8 x 10^-5 to 25 x 10^-5 liters/ (g-mole)(min), depending upon the reaction temperature …

The Kinetics Of A Heterogeneous System, Francisco H. Fernandez-Ortega, Gonzalo D. Milian

Theses

The reaction between an acidic potassium dichromate solution and metallic copper has been studied at 25.0°C under batch quiescent and continuous flow conditions.

The effect of time of reaction, reactor diameter, acid, dichromate, and salt concentration upon reaction rate have been investigated for a quiescent batch reactor and found to influence the Reaction Velocity Constant of the system. As the reaction progressed, the Reaction Velocity Constant was observed to decrease. An increase in reactor diameter resulted in a Reaction Velocity Constant increase. Small increments in the dichromate concentration produced a decrease in the Reaction Velocity Constant. A maximum point of …

Diffusion Coefficients In Alcohol - Water, Frank Gustav Meier

Theses

Diffusion coefficients of potassium, calcium and magnesium ions in ethanol-water solutions have been determined at 20°C. by means of Dowex 50W-X8 under experimental conditions that indicate that the transfer rate is controlled by film diffusion.

This investigation presents, for the first time, diffusion coefficients for these ions in ethanol solutions at concentrations below 0.01N.

The combined effect of viscosity and dielectric Constant of the solvent on the diffusion coefficient of Ions is demonstrated.

Effects Of Non-Constant Molal Flow On Distillation Plate Separation, Joseph Lawrence Niedzwiecki, W. Weissman

Theses

This thesis presents new equations for predicting degree of separation on a distillation plate, recognizing non-constant molal flow effects. A FORTRAN program is included for solving the new equations. Experimental runs were made for comparison to theoretical predictions.

First an equation is derived for predicting separation at a point on a distillation plate. The derivation is analogous to Murphree's point efficiency equation except that the effects of flow between phases are included by applying the Colburn-Drew theory. Finally, an overall plate separation equation is derived analogous to the A.I.Ch.E. eddy diffusion model for Murphree plate efficiency, except that the rate …

Hydrotropic Extraction Of Hydrocarbon Mixtures, Michael Jay Ram

Dissertations

The solubilities at 25°C of selected aromatics and straight chain alkanes in hydrotropic solutions of sodium xylene sulfonate and sodium cymene sulfonate were studied. The results of this investigation are shown on distribution diagrams relating the solubilities of alkane and aromatic in each phase.

Two methods were investigated to predict the experimentally determined solubilities. The semi-empirical solubility parameter approach resulted in answers that were extremely low. A purely theoretical approach involves the calculation of dispersion forces between molecules. An equation for predicting solubilities has been derived so that it is applicable to four component systems. This method results in values …

Correlation And Coordination Of Engineering Properties Of Zirconium And Zirconium Alloys, Rasiklal Jethalal Shah

Theses

This thesis is a report on the mechanical, nuclear, electrical and chemical properties of the zirconium and five zirconium-base binary alloys: zirconium-tin alloys, zirconium-aluminium alloys, zirconium-titanium alloys, zirconium-niobium alloys, and zirconium-hafnium alloys. The peculiarities of these alloys, as related to its history, heat treatment and composition, are discussed. This work discusses the effect of temperature and impurities such as carbon, oxygen, nitrogen and hydrogen on mechanical properties and corrosion resistance of zirconium and zirconium alloys. Zirconium metal production is briefly discussed. Empirical formula, by which the thermal conductivity of zirconium alloys can be calculated by the measurements of thermal resistivity, …

A Systematic Evaluation Of Alternate Chemical Routes, Arthur H. Bobis

Dissertations

A systematic method for selecting from among alternative routes for chemical synthesis is developed and presented. Consideration is given not only to making the best decision, but of reaching that decision with a minimum of experiments.

A method is developed whereby the calculated differences in process cost due to variations in the levels of such responses as chemical yield, usage and recovery are displayed graphically. Such a representation by indicating the potential worth of any experiment focuses attention on those parts of the synthesis which have an economic bearing on the ultimate process cost.

The probability of achieving a particular …

Conversion Of Parahydrogen To Orthohydrogen, George A. Winkler

Chemical and Biological Engineering ETDs

Heisenberg (53) and Hund (57) postulated the existence of two modifications of hydrogen. This occurred as a result of Heisenberg's previous explanation of the existence for orthohelium and parahelium using quantum theory. From analogous considerations, he and Hund asserted that hydrogen was a mixture of two gases. Dennison (28) applied their theories to explain the falling off of the rotational specific heat of hydrogen. This had been observed by Eucken (34) in 1912. In 1928, Giaque and Johnston (45) held gaseous hydrogen at 85°K for six months. On liquefaction they found a detectable difference in vapor pressure. They stated that …

Vapor Liquid Equilibria Of The Isopropanol-Isopropylacetate-Water System, Amin Zavosh

Chemical and Biological Engineering ETDs

The separation of isopropylacetate from a ternary mixture of isopropanol, isopropylacetate and water by azeotropic distillation requires reliable and thermodynamically consistent vapor-liquid equilibrium data. By using a single experimental vapor-liquid equilibrium datum point for each of the related binaries of the above system, it is possible to determine the binary constants of some of the integrated forms of the Gibbs-Duhem equation such as the Van Laar or Margules equation. The binary constants can be used in the ternary forms of the above equations and in conjunction with the definition of activity coefficient to generate approximate vapor-liquid equilibrium data over the …

Nucleate Boiling Heat Transfer To Liquid Nitrogen At Atmospheric Pressure, Satish R. Parikh

Masters Theses

"The object of this investigation was to study the effect of micro-roughness, a thin layer of oil, and infra-red radiations on the cylindrical heat transfer surface of copper, in liquid nitrogen and at atmospheric pressure during nucleate boiling. An attempt was made to find any possible effect of orientation of the heat transfer element on nucleate boiling. A number of different runs were taken with different degrees of roughness, and different orientation positions. Nucleate boiling has been found to be nearly independent of the heat transfer surface roughness and of orientation while strongly dependent on the chemical nature of the …

A Study Of Molecular Diffusion In Polymer Solutions By A Microinterferometric Method, Girish T. Dalal

Masters Theses

"A microinterferometric method was used to study the effect of solute concentration on the diffusion coefficient in polymer solutions and also to determine the effect of polymer concentration on the diffusion coefficient. The polyacrylonitrile-dimethylformamide system was used as a means of determining the accuracy of the experimental apparatus and procedure. The non-ionic, water soluble polymer, hydroxyethyl cellulose (commercially known as Natrosol), was used to study this effect with urea and D-glucose as the solutes.

The results obtained for the polyacrylonitrile-dimethylformamide system were in close agreement with the results obtained by Secor, which meant that the experimental technique is accurate enough …

The Anodic Oxidation Of Maleic Acid, Larry D. Gilmartin

Masters Theses

"The purpose of this investigation was to determine the mechanism of the anodic oxidation of maleic acid on platinized-platinum electrodes at 80⁰C. Current density-potential studies were conducted varying the parameters of maleic acid concentration and pH. The faradaic efficiency of the oxidation of maleic acid to yield CO₂ was determined. The effect of temperature on current density was also studied to determine the activation energy for the reaction. The oxidation of maleic acid occurred only in acidic solutions. The faradaic efficiency was found to be approximately 97 ± 5 per cent. A linear Tafel region was found which had a …

Further Studies Of The Catalytic Oxidation Of Ortho-Xylene To Phthalic Anhydride Using A Fluidized Bed Reactor., Richard Shih-Chun Chu

Masters Theses

"This investigation was conducted to further study the vapor-phase oxidation or o-xylene to phthalic anhydride in a fluidized bed catalytic reactor. Parameters investigated during the study were temperature, catalyst volume, and catalyst activated by use or different promoters. Two different vanadium pentoxide catalysts were used. One was a new catalyst(Catalyst I) supported on a silica base and diluted with potassium sulfate. The other catalyst(Catalyst II) was similar to the first one except that it had been used in a commercial fixed bed reactor operated by the Monsanto Company, St. Louis, Missouri, using naphthalene as a reed material. It had been …

The Anodic Dissolution Of Magnesium In Aqueous Solutions, Chen-I Lu

Masters Theses

"The anodic dissolution of magnesium was studied in MgCl₂-KC1 and MgBr₂-KBr mixtures at 25, 40, and 55 °C. The parameters of the study were current density, concentration of magnesium ion, and temperature. The concentration of magnesium ions was varied from 0.001 to 1 N holding the ionic strength constant at 1.5. The weight loss of magnesium from the electrode during electrolysis was determined by weighing the electrode both before and after electrolysis. The current was measured with a sensitive milliammeter. The range of the current densities was varied from 0.001 to 0.1 amps·cm^-2. The …

Anodic Dissolution Of Silver In Aqueous Solutions, B. W. Jong

Masters Theses

"The purpose of this investigation was to study the anodic dissolution of silver in various electrolytes to determine if there existed any deviations from Faraday’s law in nitric acid-silver nitrate solutions. The effect of small additions (10^-4 and 10^-5 N) of Cl^-, SO₄⁼, and CrO₄⁼ on the apparent valence and dissolution potential was also studied. Current densities were varied from 0.00 to 0.07 amp·cm^-2.

Based on the observed apparent valences and a grey film containing metallic particles on the anode surface, it was concluded that deviations from Faraday’s law …

A Study Of The Removal Of Alkyl Benzene Sulfonate By Means Of A Column Packed With Sand Coated With Ferric Oxide, Chang I. Fung

Masters Theses

"Iron, precipitated in the form of hydroxides on sand particles (-48 + 65 mesh) and stabilized by drying at 100°C for 10 hours, was utilized to remove alkyl benzene sulfonate (ABS) from aqueous solutions. Solutions containing a maximum of 5 mg/l ABS were passed through a glass column packed with treated sand. The ABS formed a complex with the iron precipitants which adhered to the sand particles.

Preliminary work, in which solutions containing 10 mg/l ABS were treated with various concentrations of FeCl₂ at the equivalence point (pH about 9.5), verified the fact that ABS could be removed by …

A Crystallographic Study Of The Pbzro₃-Pbtio₃-Bifeo₃ Ternary System., Dannie R. Clarida

Masters Theses

"The purpose of this investigation was to conduct a crystallographic study of the PbZrO₃-PbTiO₃-BiFeO₃ ternary system, where all three components are perovskites. Lead zirconate is antiferroelectric, lead titanate is ferroelectric, and bismuth ferrate is thought to be ferroelectric. X-ray diffraction analysis was employed to determine the crystallographic structure and lattice parameters.

A tetragonal region was found to exist in the area of high PbTiO₃ content. A rhombohedral region occurred in the remainder of the system with high BiFeO₃ and PbZrO₃ content, except for an orthorhombic envelope along the PbZrO₃-BiFeO₃ side of the diagram up to approximately 70 per cent BiFeO₃.The …

Study Of Heat And Mass Transfer Through Non-Wettable Porous Membrane, Rajender Kumar Rohatgi

Masters Theses

"The object of this investigation was to study the use of non-wettable porous membranes for simultaneous heat transfer and mass transfer of water from a hot salt solution stream to a cold distilled water stream, the streams being in countercurrent flow separated by the membrane. This type of mass transfer was achieved in the experiments, and mass and heat transfer coefficients were measured.

The membranes studied in this work were made of fiberglas treated with Teflon dispersion and aluminum sulphate. The fiberglas membranes yielded desired results. Empirical correlations were proposed which predict values of heat and mass transfer coefficients close …

Permeability And Additive Sorption And Extraction In Lubricating Greases, Hsiu-Hsiung Lin

Masters Theses

"An important goal in the study of lubricating greases is the determination of the mechanism of additive action in lubricating greases and the effect of additive concentration on the improvement of particular properties. As a step in this direction, one aim of this investigation was an attempt to determine whether grease additives are sorbed on the thickener surface, or are dissolved in the oil phase, or if a combination of these effects prevails. Exploratory sorption and extraction experiments were run by Tu using greases thickened with lithium hydroxystearate and Baragel and using only one concentration of additive. More detailed studies …

The Kinetics Of The Reaction Of M-Nitrobenzyl Bromide With Hydroxide Ion In Aqueous-Aprotic Solvent Mixtures, Ramesh Nagindas Sheth

Masters Theses

"The reaction between m-nitrobenzyl bromide and sodium hydroxide in homogeneous aqueous dioxane and aqueous tetrahydrofuran media was studied.

The product of the reaction was identified by infrared, gas chromatography and chemical tests as m-nitrobenzyl alcohol.
The kinetics of the reaction are second order with practically no variation in the rate constants as the % of the organic solvent was changed in the medium. This seems to imply hydrolysis of the organic halide by a process involving both bond-breaking and bond-formation in the transition state.
The activation energy, measured in 50% aqueous dioxane, between 20⁰ and 69.5⁰C at 5 different temperatures, …

Kinetics And Mechanisms Of Base-Catalysed Reactions, Rohit Panalal Sheth

Masters Theses

"Base-catalysed reactions normally involve complex series of transformations. their kinetics is usually governed by a variety of equilibria, participating in the overall and concurrent processes as well as by competitive side-reactions that interfere with the normal course of such reactions. Mechanisms which have been proposed, by and large, are primarily based on product, by-product and intermediate analyses together with some scattered kinetic and isotopic evidence. In the cases where kinetic studies have been attempted, highly complex mechanisms have usually been proposed due to the frequent necessity of using heterogeneous media or employing involved mathematical treatments to describe the kinetics of …