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Full-Text Articles in Science and Technology Studies

A Strategy For Configuration Of An Integrated Flexible Sulfur Cathode For High-Performance Lithium-Sulfur Batteries, Hongqiang Wang, Wenchao Zhang, Hua-Kun Liu, Zaiping Guo Jan 2016

A Strategy For Configuration Of An Integrated Flexible Sulfur Cathode For High-Performance Lithium-Sulfur Batteries, Hongqiang Wang, Wenchao Zhang, Hua-Kun Liu, Zaiping Guo

Faculty of Engineering and Information Sciences - Papers: Part A

Lithium-sulfur batteries are regarded as promising candidates for energy storage devices owing to their high theoretical energy density. The practical application is hindered, however, by low sulfur utilization and unsatisfactory capacity retention. Herein, we present a strategy for configuration of the sulfur cathode, which is composed of an integrated carbon/sulfur/carbon sandwich structure on polypropylene separator that is produced using the simple doctor-blade technique. The integrated electrode exhibits excellent flexibility and high mechanical strength. The upper and bottom carbon layers of the sandwich-structured electrode not only work as double current collectors, which effectively improve the conductivity of the electrode, but also …


V2o5/Mesoporous Carbon Composite As A Cathode Material For Lithium-Ion Batteries, Mohammad Ihsan, Qing Meng, Li Li, Dan Li, Hongqiang Wang, Kuok Hau Seng, Zhixin Chen, Shane J. Kennedy, Zaiping Guo, Hua-Kun Liu Jan 2015

V2o5/Mesoporous Carbon Composite As A Cathode Material For Lithium-Ion Batteries, Mohammad Ihsan, Qing Meng, Li Li, Dan Li, Hongqiang Wang, Kuok Hau Seng, Zhixin Chen, Shane J. Kennedy, Zaiping Guo, Hua-Kun Liu

Faculty of Engineering and Information Sciences - Papers: Part A

V2O5/mesoporous carbon composite has been prepared by an ultrasonically assisted method followed by a sintering process. The as-prepared V2O5/mesoporous carbon material containing 90 wt% V2O5 shows better electrochemical performance, with capacity of 163 mA h g-1 after 100 cycles at the current density of 500 mA g-1, as well as better charge/discharge rate capability for lithium storage than V2O5 nanoparticles. The improved electrochemical performance indicates that the V2O5/mesoporous carbon composite could be used as a promising cathode material for …


Structural Evolution Of Electrodes In The Ncr And Cgr Cathode-Containing Commercial Lithium-Ion Batteries Cycled Between 3.0 And 4.5 V: An Operando Neutron Powder-Diffraction Study, Wei Kong Pang, Moshiul Alam, Vanessa K. Peterson, Neeraj Sharma Jan 2015

Structural Evolution Of Electrodes In The Ncr And Cgr Cathode-Containing Commercial Lithium-Ion Batteries Cycled Between 3.0 And 4.5 V: An Operando Neutron Powder-Diffraction Study, Wei Kong Pang, Moshiul Alam, Vanessa K. Peterson, Neeraj Sharma

Faculty of Engineering and Information Sciences - Papers: Part A

The dissimilar lattice-evolution of the isostructural layered Li(Ni,Co,Al)O2 (NCR) and Li(Ni,Co,Mn)O2 (CGR) cathodes in commercial lithium-ion batteries during overcharging/discharging was examined using operando neutron powder-diffraction. The stacking axis (c parameter) of both cathodes expands on initial lithiation and contracts on further lithiation. Although both the initial increase and later decrease are smaller for the CGR cathode, the overall change between battery charged and discharged states of the c parameter is larger for the CGR (1.29%) than for the NCR cathode (0.33%). We find these differences are correlated to the transition metal to oxygen bond (as measured through …


Electrospun P2-Type Na 2/3 (Fe 1/2 Mn 1/2 )O 2 Hierarchical Nano Fibers As Cathode Material For Sodium-Ion Batteries, Sujith Kalluri, Kuok Hau Seng, Wei Kong Pang, Zaiping Guo, Zhixin Chen, Hua-Kun Liu, S X. Dou Oct 2014

Electrospun P2-Type Na 2/3 (Fe 1/2 Mn 1/2 )O 2 Hierarchical Nano Fibers As Cathode Material For Sodium-Ion Batteries, Sujith Kalluri, Kuok Hau Seng, Wei Kong Pang, Zaiping Guo, Zhixin Chen, Hua-Kun Liu, S X. Dou

Shi Xue Dou

Sodium-ion batteries can be the best alternative to lithium-ion batteries, because of their similar electrochemistry, nontoxicity, and elemental abundance and the low cost of sodium. They still stand in need of better cathodes in terms of their structural and electrochemical aspects.


Electrospun P2-Type Na 2/3 (Fe 1/2 Mn 1/2 )O 2 Hierarchical Nano Fibers As Cathode Material For Sodium-Ion Batteries, Sujith Kalluri, Kuok Hau Seng, Wei Kong Pang, Zaiping Guo, Zhixin Chen, Hua-Kun Liu, S X. Dou Jan 2014

Electrospun P2-Type Na 2/3 (Fe 1/2 Mn 1/2 )O 2 Hierarchical Nano Fibers As Cathode Material For Sodium-Ion Batteries, Sujith Kalluri, Kuok Hau Seng, Wei Kong Pang, Zaiping Guo, Zhixin Chen, Hua-Kun Liu, S X. Dou

Faculty of Engineering and Information Sciences - Papers: Part A

Sodium-ion batteries can be the best alternative to lithium-ion batteries, because of their similar electrochemistry, nontoxicity, and elemental abundance and the low cost of sodium. They still stand in need of better cathodes in terms of their structural and electrochemical aspects.


The Effect Of Different Binders On Electrochemical Properties Of Lini1/3mn1/3c1/3o2 Cathode Material In Lithium Ion Batteries, Jiantie Xu, Shulei Chou, Qinfen Gu, Hua Liu, S Dou Feb 2013

The Effect Of Different Binders On Electrochemical Properties Of Lini1/3mn1/3c1/3o2 Cathode Material In Lithium Ion Batteries, Jiantie Xu, Shulei Chou, Qinfen Gu, Hua Liu, S Dou

Shulei Chou

LiNi1/3Mn1/3Co1/3O2 (NMC) as a cathode material for lithium ion batteries has been synthesized by the sol-gel method. The X-ray diffraction Rietveld refinement results indicated that single-phase NMC with hexagonal layered structure was obtained. Scanning electron microscope images revealed well crystallized NMC with uniform particle size in the range of 100-200 nm. The performance of the NMC electrodes with sodium carboxylmethyl cellulose (CMC), poly(vinylidene fluoride) (PVDF), and alginate from brown algae as binders was compared. Constant current charge-discharge test results demonstrated that the NMC electrode using CMC as binder had the highest rate capability, followed by those using alginate and PVDF …


Rapid Synthesis Of Free-Standing Moo3/Graphene Films By The Microwave Hydrothermal Method As Cathode For Bendable Lithium Batteries, Lukman Noerochim, Jia-Zhao Wang, David Wexler, Zhong Chao, Hua-Kun Liu Jan 2013

Rapid Synthesis Of Free-Standing Moo3/Graphene Films By The Microwave Hydrothermal Method As Cathode For Bendable Lithium Batteries, Lukman Noerochim, Jia-Zhao Wang, David Wexler, Zhong Chao, Hua-Kun Liu

Faculty of Engineering and Information Sciences - Papers: Part A

Highly flexible, binder-free, MoO3 nanobelt/graphene film electrode is prepared by a two-step microwave hydrothermal method. Graphene is first prepared by an ultra-fast microwave hydrothermal method and then mixed with MoO3 solution to synthesize the MoO3 nanobelt/graphene composite, which exhibits the combination of stacked graphene sheets and uniform MoO3 nanobelts with widths of 200-500 nm and lengths of 5-10 μm. The charge-discharge measurements show that the as-synthesized MoO3/graphene hybrid materials demonstrate excellent rate capability, large capacity, and good cycling stability compared to the pure MoO3 film. An initial discharge capacity of 291 mAh g-1 can be obtained at 100 mA g-1, …