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Improved Hydrogen Storage Properties Of Mgh2 Doped With Chlorides Of Transition Metals Hf And Fe, M Ismail Ismail, Yue Zhao, Xuebin Yu, S X. Dou
Improved Hydrogen Storage Properties Of Mgh2 Doped With Chlorides Of Transition Metals Hf And Fe, M Ismail Ismail, Yue Zhao, Xuebin Yu, S X. Dou
Shi Xue Dou
The effects of HfCl4 and FeCl3 addition on the de/rehydrogenation properties of MgH2 were investigated. Both HfCl4 and FeCl3-doped MgH2 samples started to released hydrogen at about 270 °C, a decreased of about 70 °C and about 140 °C compared to as-milled and as-received MgH2, respectively. In terms of the desorption kinetics, the HfCl4-doped MgH2 sample showed significant improvement, with 6.0 wt.% hydrogen released within 10 min at 300 °C, while the FeCl3-doped MgH2 and undoped MgH2 samples released 3.5 and 0.2 wt.% hydrogen, respectively, under the same conditions. In terms of the absorption kinetics, 5.5 wt.% hydrogen was charged …
Enhancement Of The Refrigerant Capacity In Low Level Boron Doped La0.8gd0.2fe11.4si1.6, P Shamba, R Zeng, Jianli Wang, S J. Campbell, S X. Dou
Enhancement Of The Refrigerant Capacity In Low Level Boron Doped La0.8gd0.2fe11.4si1.6, P Shamba, R Zeng, Jianli Wang, S J. Campbell, S X. Dou
Shi Xue Dou
The effects of boron doping on the itinerant-electron metamagnetic (IEM) transition and the magnetocaloric effects (MCEs) in the cubic NaZn13-type La0.8Gd0.2Fe11.4Si1.6 compound have been investigated. The Curie temperature, TC, of La0.8Gd0.2Fe11.4Si1.6Bx compounds with x=0, 0.03, 0.06, 0.2 and 0.3 was found to increase from 200 K to 222 K with increase in boron doping, x. The maximum values of the isothermal magnetic entropy change, ΔSM, (derived using the Maxwell relation for a field change ΔB=0-5 T) in La0.8Gd0.2Fe11.4Si1.6Bx with x=0, 0.03, 0.06, 0.2 and 0.3 are 14.8, 16, 15, 7.5 and 6.6 J kg−1 K−1 respectively, with corresponding values of …