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The Crystal Structure Of (Cuxzn1-X)0:456in1:084ge0:46o3 (Cuzigo) Using Neutron And X-Ray Diffraction, Boluwatife A. Adekoya Mar 2020

The Crystal Structure Of (Cuxzn1-X)0:456in1:084ge0:46o3 (Cuzigo) Using Neutron And X-Ray Diffraction, Boluwatife A. Adekoya

College of Science and Health Theses and Dissertations

The solid solution (CuxZn(1-x))0.456In1.084Ge0.46O3 (CuZIGO) has a complex structure where zinc and copper partially occupy a site shared by indium and germanium. ZIGO, the x = 0 endpoint, is a potential transparent conducting oxide (TCO) with similar conductivity and transparency to cubic In2O3, which, when doped with Sn4+, is the most prevalent TCO. ZIGO structure possesses a tetragonal structure and has the ability to produce multiple new phases with an array of properties that are beneficial to identify and understand. Analyzing this structure is best done through chemical substitution to identify the newly produced phases. Copper is a suitable choice …