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Full-Text Articles in Physics

Self-Assembly Of Nanoparticles At Liquid-Liquid Interfaces, Kan Du Sep 2010

Self-Assembly Of Nanoparticles At Liquid-Liquid Interfaces, Kan Du

Open Access Dissertations

In this thesis, we studied the self-assembly of nanoparticles at liquid metal-water interfaces and oil-water interfaces. We demonstrated a simple approach to form nanostructured electronic devices by self-assembly of nanoparticles at liquid metal surfaces. In this approach, two liquid-metal droplets, which were coated with a monolayer of ligand-stabilized nanoparticles, were brought into contact. They did not coalesce but instead remained separated by the nanoparticles assembled at the interface. Devices formed by this method showed electron transport between droplets that was characteristic of the Coulomb blockade, where current was suppressed below a tunable threshold voltage because of the energy of charging …


Theoretical Investigation Of The Structures And Stability Of Gas Phase Neutral And Cationic Tixoy Clusters., Baljeet Kaur May 2010

Theoretical Investigation Of The Structures And Stability Of Gas Phase Neutral And Cationic Tixoy Clusters., Baljeet Kaur

Theses and Dissertations

Theoretical investigation of the structure and stability of neutral and cationic TixOy cluster series (where y =2x-1, 2x, 2x+1) have been performed. The lowest lying structures for the neutral clusters are usually found in the singlet state. Generally, in bulk and in the case of the neutral TixOy clusters, the 2x cluster series is relatively more abundant than the 2x-1 and the 2x+1 cluster series. But in the case of cationic TixOy clusters, the 2x-1 series is more abundant. To understand the origin of the stability of the TixO2x-1+ clusters, we use density functional theory within the NRLMOL set of …


Plasmon Enhanced Near-Field Interactions In Surface Coupled Nanoparticle Arrays For Integrated Nanophotonic Devices, Amitabh Ghoshal Jan 2010

Plasmon Enhanced Near-Field Interactions In Surface Coupled Nanoparticle Arrays For Integrated Nanophotonic Devices, Amitabh Ghoshal

Electronic Theses and Dissertations

The current thrust towards developing silicon compatible integrated nanophotonic devices is driven by need to overcome critical challenges in electronic circuit technology related to information bandwidth and thermal management. Surface plasmon nanophotonics represents a hybrid technology at the interface of optics and electronics that could address several of the existing challenges. Surface plasmons are electronic charge density waves that can occur at a metal-dielectric interface at optical and infrared frequencies. Numerous plasmon based integrated optical devices such as waveguides, splitters, resonators and multimode interference devices have been developed, however no standard integrated device for coupling light into nanoscale optical circuits …


Supported Mono And Bimetallic Platinum And Iron Nanoparticles Electronic, Structural, Catalytic, And Vibrational Properties, Jason Robert Croy Jan 2010

Supported Mono And Bimetallic Platinum And Iron Nanoparticles Electronic, Structural, Catalytic, And Vibrational Properties, Jason Robert Croy

Electronic Theses and Dissertations

Catalysis technologies are among the most important in the modern world. They are instrumental in the realization of a variety of products and processes including chemicals, polymers, foods, pharmaceuticals, fuels, and fuel cells. As such, interest in the catalysts that drive these processes is ongoing, and basic research has led to significant advances in the field, including the production of more environmentally friendly catalysts that can be tuned at the molecular/atomic level. However, there are many factors which influence the performance of a catalyst and many unanswered questions still remain. The first part of this work is concerned with the …