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Structure Symmetry Determination And Magnetic Evolution In Sr2Ir1−XRhXO4, Feng Ye, Xiaoping Wang, Christina Hoffmann, Jinchen Wang, Songxue Chi, Masaaki Matsuda, Bryan C. Chakoumakos, Jaime A. Fernandez-Baca, Gang Cao

Physics and Astronomy Faculty Publications

We use single-crystal neutron diffraction to determine the crystal structure symmetry and the magnetic evolution in the rhodium-doped iridates Sr₂Ir_1−xRh_xO₄ (0≤ x ≤ 0.16). Throughout this doping range, the crystal structure retains a tetragonal symmetry (space group I4₁/a) with two distinct magnetic Ir sites in the unit cell forming staggered IrO₆ rotation. Upon Rh doping, the magnetic order is suppressed and the magnetic moment of Ir⁴⁺ is reduced from 0.21μ_B/Ir for x=0 to 0.18μ_B/Ir for x=0.12. The magnetic structure …