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Diffusion

Wayne State University Dissertations

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Diffusion Of Gold Nanoparticles Within Polymer Solutions And Gels, Kavindya Kumari Senanayake R W H Jan 2019

Diffusion Of Gold Nanoparticles Within Polymer Solutions And Gels, Kavindya Kumari Senanayake R W H

Wayne State University Dissertations

Soft matter is a subfield of condensed matter physics including systems, such as polymers, colloidal dispersions, liquid crystals, surfactants. Understanding their interaction and dynamics is essential for many interdisciplinary fields of study as well as important for technological advancements. We used gold nanoparticles (AuNPs) to investigate the length-scale dependent dynamics in dilute, semidilute, entangled polymer solutions and gels. Two-photon fluctuation correlation spectroscopy (FCS) technique was used to investigate the translation diffusion coefficient of AuNPs. For polymer solutions, we found that existing hydrodynamic and obstruction models are inadequate to describe the size dependence of the particle diffusion coefficient. Within entangled Poly …


Dynamics Of Nanoparticles In Complex Fluids., Rami Ahmad Saleh Omari Jan 2011

Dynamics Of Nanoparticles In Complex Fluids., Rami Ahmad Saleh Omari

Wayne State University Dissertations

Soft matter is a subfield of condensed matter including polymers, colloidal dispersions, surfactants, and liquid crystals. These materials are familiar from our everyday life- glues, paints, soaps, and plastics are examples of soft materials. Many phenomena in these systems have the same underlying physical mechanics. Moreover, it has been recognized that combinations of these systems, like for example polymers and colloids, exhibit new properties which are found in each system separately. These mixed systems have a higher degree of complexity than the separate systems. In order to understand their behavior, knowledge from each subfields of soft matter has to be …