Physics Commons^™

Properties Of Si Quantum Dots, Carolyn C. F Cadogan

Electronic Thesis and Dissertation Repository

The fundamental properties of matter in confined particles change dramatically due to quantum effects. In this work, we have explored the optical properties of silicon quantum dots (Si-QDs) embedded in Si₃N₄; and the role of crystallinity on the optical properties and formation of Si-QDs in Al₂O₃. This work examined the role of (1) annealing temperature and the composition of the film, (2) Al doping of the host Si₃N₄ film, (3) doping Si-QDs and (4) Al and P passivation of Si-QDs on the PL intensity of Si-QDs embedded in Si …

Computational Prediction, Characterization, And Methodology Development For Two-Dimensional Nanostructures: Phosphorene And Phosphide Binary Compounds., Congyan Zhang

Electronic Theses and Dissertations

In this thesis, a comprehensive computational simulation was carried out for predicting, characterizing, and applications of two-dimensional (2D) materials. The newly discovered GaP and InP layers were selected as an example to demonstrate how to explore new 2D materials using computational simulations. The performance of phosphorene as the anode material of Lithium-ion battery was discussed as the example of the application of 2D material. Furthermore, the semi-empirical Hamiltonian for phosphorous and lithium elements have been developed for our future work on the application of phosphorus and lithium-based systems. The novel 2D materials of GaP and InP binary compounds were found …

Physical Electronic Properties Of Self-Assembled 2d And 3d Surface Mounted Metal-Organic Frameworks, Radwan Elzein

USF Tampa Graduate Theses and Dissertations

Metal-organic frameworks stand at the frontiers of molecular electronic research because they combine desirable physical properties of organic and inorganic components. They are crystalline porous solids constructed by inorganic nodes coordinated to organic ligands to form 1D, 2D, or 3D structures. They possess unique characteristics such as ultrahigh surface area crystal lattices up to 10000 m² g^-1, and tunable nanoporous sizes ranging from 0.2 to 50 nm. Their unprecedented structural diversity and flexibility beyond solid state materials can lead to unique properties such as tailorable electronic and ionic conductivity which can serve as interesting platforms for a …

The Effects Of Pressure And Magnetic Field On Phase Transitions And Related Physical Properties In Solid State Caloric Materials, Ahmad Ikhwan Us Saleheen

LSU Doctoral Dissertations

Solid-state caloric effects, such as the magnetocaloric (MCE) and barocaloric (BCE) effects, may be utilized in future cooling technologies that are more efficient and environment-friendly. Large caloric effects often occur near phase transitions, especially near coupled first-order magnetostructural transitions (MST), and are initiated by external parameters, such as magnetic field or hydrostatic pressure. In this dissertation, the effects of pressure, temperature, and magnetic field on the phase transitions in three material systems are studied in order to elucidate how the respective caloric effects are affected.

In the first study, the realization of a coupled MST in a MnNiSi-based system through …

Quantum Phase Transitions In Disordered Boson Systems, Zhiyuan Yao

Doctoral Dissertations

In this dissertation, we study the superfluid-insulator quantum phase transition in disordered boson systems. Recently, there has been considerable controversy over the validity of the scaling relations of the superfluid--Bose-glass quantum phase transition in three dimensions. Results from experimental and numerical studies on disordered quantum magnets contradict the scaling relations and the associated conventional scaling hypothesis for the singular part of the free energy. We determine various critical exponents of the superfluid--Bose-glass quantum phase transition in three-dimensional disordered Bose-Hubbard model through extensive Monte Carlo simulations. Our numerical study shows the previous studies on disordered quantum magnets were performed outside the …

Geometry, Growth And Pattern Formation In Thin Elastic Structures, Salem Al-Mosleh

Doctoral Dissertations

Thin shells are abundant in nature and industry, from atomic to planetary scales. The mechanical behavior of a thin shell depends crucially on its geometry and embedding in 3 dimensions (3D). In fact, the behavior of extremely thin shells becomes scale independent and only depends on geometry. That is why the crumpling of graphene will have similarities to the crumpling of paper. In this thesis, we start by discussing the static behavior of thin shells, highlighting the role of asymptotic curves (curves with zero normal curvature) in determining the possible deformations and in controlling the folding patterns. In particular, we …

Copper-Nanoparticle Decorated Graphene Thin Films: Applications In Metal-Assisted Etching And Synthesis Of Next-Generation Graphene-Based Nanomaterials, Jaewoo Park

Electronic Thesis and Dissertation Repository

Since 2006, the experimental discovery of graphene, a single-layer of carbon atoms, has spurred tremendous efforts towards new graphene-based materials. In graphene research, there is a recent trend towards next-generation materials in which graphene layers are locally modified in a controlled fashion at the nanoscale and tailored for specific applications. Examples include nanoparticle-decorated graphene thin films with surface potential tailored for nanoelectronics or advanced catalysis, graphene nanoribbons, graphene quantum dots, and the scalable fabrication of tiny pores in graphene, which are suitable to applications requiring ultrathin molecular sieving membranes. This research is focused on the development of new applications of …

High Resolution Ion Beam Investigations Of The Mechanisms Of Titanium Anodization, Mitchell A. Brocklebank

Electronic Thesis and Dissertation Repository

The unique behaviour of thin films, and their surfaces and interfaces, significantly impact material and device properties. Probing these structures with ion beams (IB) provides quantitative composition and thicknesses measurements. In this dissertation, the IB techniques of medium energy ion scattering (MEIS), nuclear reaction profiling (NRP) and Rutherford backscattering spectrometry (RBS) are used to analyze energy losses in ultra-thin films, as well as elucidate the mechanisms of anodic film growth.

Accurate stopping cross sections of protons, ε, in the medium energy range (50-170 kV) often show deviations from Bragg’s rule. Here, ε_Ti, ε_Si, and ε_{TiO2 …}

Charge State Dynamics And Quantum Sensing With Defects In Diamond, Jacob D. Henshaw

Dissertations, Theses, and Capstone Projects

In recent years, defect centers in wide band gap semiconductors such as diamond, have received significant attention. Defects offer great utility as single photon emitters, nanoscale sensors, and quantum memories and registers for quantum computation. Critical to the utility of these defects, is their charge state.

In this dissertation, experiments surrounding the charge state dynamics and the carrier dynamics are performed and analyzed. Extensive studies of the ionization and recombination processes of defects in diamond, specifically, the Nitrogen Vacancy (NV) center, have been performed. Diffusion of ionized charge carriers has been imaged indirectly through the recapture of said carriers by …

Nmr Characterizations Of Candidate Battery Electrolytes, Stephen A. Munoz

Dissertations, Theses, and Capstone Projects

Enormous strides have been made in next-generation power sources to build a more sustainable society. Energy storage has become a limiting factor in our progress, and there are huge environmental and financial incentives to find the next step forward in battery technology. This work discusses NMR methods for characterizing materials for use in battery application, with a special focus on relaxometry and diffusometry. Examples are provided of various recent investigations involving novel candidate electrolyte materials with different collaborators. Works discussed in this thesis include: the characterization of a new disruptive solid polymer electrolyte technology, investigations of the dynamics of super …

Direct Experimental Evidence Of Toroidal Symmetry In A Lanthanide-Based Molecular Magnet, Qing Zhang

Dissertations, Theses, and Capstone Projects

Molecular magnets (MM) are finite clusters of identical exchange-coupled magnetic systems arranged within a crystalline array such that interactions between neighboring MMs are negligible. Their small size has proven them amenable test beds for the investigation of a wide range of fundamental quantum phenomena such as spin frustration quantum tunneling (QT) of magnetization and Neel vector quantum coherence and Berry phase interference.

Cases where MMs have been found to exhibit quantum wave-functions that evolve coherently are particularly interesting due to their potential for use in quantum information processing. Toroidal magnetic moments, a kind of MM, have fascinating properties that could …

Quantum And Classical Transport Of 2d Electrons In The Presence Of Long And Short Range Disorder, Jesse Kanter

Dissertations, Theses, and Capstone Projects

This work focuses on the study of electron transport of 2-D electron gas systems in relation to both fundamental properties of the systems such as disorder and scattering mechanisms, as well as unique magnetoresistance (MR) effects. A large portion of the discussion is built around the use of an in plane magnetic field to vary the ratio between the Zeeman energy between electrons of different spins and the Landau level spacing, creating a tool to control the quantization of the density of states (DOS).

This tool is first used to isolate Quantum Positive Magnetoresistance (QPMR), which grants insight to the …

Developing A Femtosecond Stimulated Raman Spectroscopy Experiment For Solid State Materials, Daniel Hammerland

Electronic Theses and Dissertations

Femtosecond Stimulated Raman Spectroscopy (FSRS) is a ultrafast spectroscopy technique first implemented by chemists to understand isomerization and other ultrafast molecular morphology changes by resolving vibrational dynamics[1, 2, 3]. FSRS has an unparalleled temporal and spectral resolution [4, 1, 5, 6] that arises as a result of a clever combination of picosecond and femtosecond pulses. However, despite this capability, FSRS has yet to be applied to modern materials in condensed matter physics. This thesis explores the design and implementation of FSRS to study two-dimensional materials in order to measure their quantum confined vibrational dynamics on utlrafast time scales.

Scanning Tunneling Microscopy Studies Of Superconducting Single Layer Iron Selenide On Strontium Titanate, Zhuozhi Ge

Theses and Dissertations

The search for high temperature superconductivity has been a prominent topic in the field of condensed matter physics ever since the discovery of this novel phenomenon more than 100 years ago. In addition to the search for new materials, interfacial superconductivity has shown great potential as demonstrated recently in monolayer FeSe grown on SrTiO3 (STO) (001) substrate, where superconducting transition temperature (Tc) has been enhanced by more than an order of magnitude compared to the bulk value. The uniqueness of this approach is the direct placement of the superconducting layer on a secondary substrate, which facilitates the independent control of …

Plasma Based Synthesis And Surface Modification Of Graphene., Rong Zhao

Electronic Theses and Dissertations

Graphene, an atom thick layer of carbon, has attracted intense scientific interest due to its exceptional electrical, mechanical and chemical properties. Especially, it provides a perfect platform to explore the unique electronic properties in absolute two-dimension. Pristine graphene possesses zero band gap and weakens its competitiveness in the field of semiconductors. In order to induce a band gap and control its semiconducting properties, functionalization and doping are two of the most feasible methods. In the context of functionalization, large area monolayer graphene synthesized by chemical vapor deposition was subjected to controlled and sequential fluorination using radio frequency plasma while monitoring …

Crystallographic Exploration Of Fundamental Technetium Species At Nonambient Conditions, Daniel S. Mast

UNLV Theses, Dissertations, Professional Papers, and Capstones

The study of mater under extreme conditions has yielded fascinating insight into the physical and chemical nature of materials that under more modest conditions are considered mundane but have quite unusual properties when under pressure. Examples of this are the lightest of elements found in the first two rows and in the heaviest elements of the lanthanide and actinide series. Pure elements, though the simplest possible chemical systems, have proven to be among the most complex and interesting. Technetium metal is a simple HCP transition metal that, due to its half-filled d-shell, has a rich chemistry and an important place …

Exotic Phases In Attractive Fermions: Charge Order, Pairing, And Topological Signatures, Peter Rosenberg

Dissertations, Theses, and Masters Projects

Strongly interacting many-body systems remain a central challenge of modern physics. Recent developments in the field of ultra-cold atomic physics have opened a new window onto this enduring problem. Experimental progress has revolutionized the approach to studying many-body systems and the exotic behaviors that emerge in these systems. It is now possible to engineer and directly measure a variety of models that can capture the essential features of real materials without the added complexity of disorder, impurities, or complicated or irregular geometries. The parameters of these models can be freely tuned with tremendous precision. These experimental realizations are an ideal …

Effects Of High Pressure On Photochemical Reactivity Of Organic Molecular Materials Probed By Vibrational Spectroscopy, Jiwen Guan

Electronic Thesis and Dissertation Repository

Chemical transformations of molecular materials induced by high pressure and light radiation exhibit novel and intriguing aspects that have attracted much attention in recent years. Particularly, under the two stimuli, entire transformations of molecular species can be realized in condensed phases without employing additional chemical constraints, e.g., the need of solvents, catalysts or radical initiators. This new synthetic approach in chemistry therefore satisfies increasing need for production methods with reduced environmental impacts. Motivated by these promises, my Ph. D thesis focuses on this state-of-the-art branch of high-pressure photochemistry. Specifically, high pressure is employed to create the necessary reaction conditions to …

Localization And Scrambling Of Quantum Information With Applications To Quantum Computation And Thermodynamics, Adrian Kristian Chapman

Physics & Astronomy ETDs

As our demand for computational power grows, we encounter the question: "What are the physical limits to computation?" An answer is necessarily incomplete unless it can incorporate physics at the smallest scales, where we expect our near-term high-performance computing to occur. Microscopic physics -- namely, quantum mechanics -- behaves counterintuitively to our everyday experience, however. Quantum matter can occupy superpositions of states and build stronger correlations than are possible classically. This affects how quantum computers and quantum thermodynamic engines will behave.

Though these properties may seem to overwhelmingly defeat our attempts to build a quantum computer at-first-glance, what is remarkable …

Computational Modeling Of Defect-Engineered Graphene Derivatives And Graphene-Polymer Nanocomposites, Asanka Weerasinghe

Doctoral Dissertations

Graphene has unique mechanical, electronic, and thermal properties, which enable a broad range of technological applications. For example, graphene flakes can be used as filler to enhance the properties of polymer-matrix nanocomposites and graphene derivatives, generated by defect engineering and chemical functionalization of single-layer graphene, have tunable properties that are very promising for engineering electronic and thermomechanical metamaterials. A fundamental understanding of the structure-property relationships that govern the function of such nanocomposites and graphene derivatives is required for designing and developing future graphene-based metamaterials. Toward this end, we have conducted a systematic study based on extensive molecular-dynamics simulations of mechanical …

Combined Spectroscopic And Scanning Probe Studies Of Electronic Interactions In Nanostructured 1d And 2d Semiconductors, Peijian Wang

Doctoral Dissertations

This dissertation includes the exploration about the following research questions: 1. What is the correlation between the work function and ground state interactions in organic semiconductor assemblies? 2. How do non-covalent chemical doping tune the work function in MoS₂? 3. Are there surface charges in the Aluminum doped ZnO nanocrystals (AZO) and what's the evolution of the surface charges and polarizabilities from undoped AZO to doped AZO? 4. How is the homogeneity like during doping in the organic thermoelectric materials? The techniques we employed in the research is the spatially registered Kelvin Probe Force Microscopy and Photoluminescence spectroscopy …

Antenna Enhanced Graphene Terahertz Emitter And Detector, And Graphene Microwave Detector, Jiayue Tong

Doctoral Dissertations

Graphene is a promising candidate for optoelectronic and fast electronics research. In THz and sub-THz frequency regime, sensitive detectors are very difficult to make. This dissertation presents my Ph.D study of THz sources and THz/Microwave (MW) detectors made with graphene. My work demonstrates the emission and detection of 1.9 THz radiation from graphene coupled to a double-patch antenna and a silicon lens. More than 3 orders of magnitude performance improvements are achieved in a half-edge-contacted graphene thermoelectric (TE) detector operating at 1.9 THz by antenna coupling and Si lens coupling. The thermoelectric mechanism is also employed in MW detection. A …

Complex Ground States Of Vortices And Filaments, Qingyou Meng

Doctoral Dissertations

This dissertation consists of two parts. In the first part, we studied the ground state configurations of vortices with multi-scale inter-vortex interactions in layered superconductors. We found that by tuning the multi-scale interaction length, we could create vortex lattice ground states with different symmetries. It has been proposed that these structures can trap ultra-cold atoms for use in quantum emulators. In further work, we measured the phase diagram and discovered many new phases by changing the relative magnitude of the interaction ranges. In the second part, we analyzed the ground state configurations of confined filaments with long-range repulsive interactions. We …

First-Principle Approaches To Strongly Correlated Quantum Spin Systems, Yuan Huang

Doctoral Dissertations

My Ph.D. research focuses on the numerical study of two quantum spin systems, one is the square-lattice Heisenberg antiferromagnet with ring-exchange interaction at the Neel to valence-bond solid state transition, which is proposed to be described by the theory of deconfined criticality; the other is the highly frustrated pyrochlore Heisenberg antiferromagnet. Both systems are known as prototypical candidates for the exotic spin-liquid state with emergent fractionalized excitations and gauge structure. Regarding the long standing controversy of deconfined criticality, our results conclude that the deconfined critical theory capture the essence of the Neel to valence-bond solid state transition at least at …

Emergent Phenomena In Quantum Critical Systems, Kun Chen

Doctoral Dissertations

A quantum critical point (QCP) is a point in the phase diagram of quantum matter where a continuous phase transition takes place at zero temperature. Low-dimensional quantum critical systems are strongly correlated, therefore hosting nontrivial emergent phenomena. In this thesis, we first address two decades-old problems on quantum critical dynamics. We then reveal two novel emergent phenomena of quantum critical impurity problems. In the first part of the thesis, we address the linear response dynamics of the $(2+1)$-dimensional $O(2)$ quantum critical universality class, which can be realized in the ultracold bosonic system near the superfluid (SF) to Mott insulator (MI) …

Towards Fundamental Understanding Of Thermoelectric Properties In Novel Materials Using First Principles Simulations, Artem R. Khabibullin

USF Tampa Graduate Theses and Dissertations

Thermoelectric materials play an important role in energy conversion as they represent environmentally safe and solid state devices with a great potential towards enhancing their efficiency. The ability to generate electric power in a reliable way without using non-renewable resources motivates many experimentalists as well as computational physicists to search and design new thermoelectric materials. Several classes of materials have been identified as good candidates for high efficient thermoelectrics because of their inherently low thermal conductivity. The complex study of the crystal and electronic structures of such materials helps to reveal hidden properties and give fundamental understanding, necessary for the …

Surface And Interface Effects Of Magnetoimpedance Materials At High Frequency, Tatiana M. Eggers

USF Tampa Graduate Theses and Dissertations

Amorphous and nanocrystalline transition metal magnetic alloys (TMMAs) have been the subjects of fundamental and applied study due to their unique structure. The lack of long-range order in these materials sets the stage for their soft magnetic properties to be tuned for a variety of technological applications, such as sensitive magnetic field sensors, high frequency transformers, and stress sensors. Fundamental investigation of the magnetic and structural properties of these materials is also motivated by their unique amorphous or nanocrystalline-embedded amorphous matrix morphology, which has consequences on both the magnetism seen from both the atomic and macro-scale. The surfaces of these …

Defect-Related Magnetic Properties Of Nanostructured Nickel Oxide Thin Films For Solar Cell Applications, Angela E. Ezugwu

Electronic Thesis and Dissertation Repository

Transparent conducting oxides (TCOs) are extensively investigated because of their applications as transparent electrodes in solar cells and light-emitting devices. TCOs of interest include indium-tin oxide, aluminum-doped zinc oxide, nickel oxide (NiO), and their combinations. There is strong interest in NiO because no heteroatoms are required to “dope” it at high transparency levels. It has been speculated that paramagnetic defects due to Ni³⁺ centers and O interstitials are responsible for the electrical conductivity of otherwise insulating and antiferromagnetic NiO, but direct investigation of such defects has been limited. Here, the electrical conductivity in nanostructured NiO thin films is investigated …

Granular Convection And Crystallization Of A Two-Dimensional Granular Medium, Donley S. Cormode

Honors Projects

Granular media are everywhere from beaches to factories to your kitchen cabinets. There are a rich array of phenomena to study with granular media. These include granular convection, jamming, and crystallization. The systems tend to be macroscopic, so it is easy to collect data. The supplies are low-cost and easy to obtain. Studying granular media gives researchers the opportunity to explore foundational ideas in fields such as crystallography and condensed matter. This paper describes a simple, low cost apparatus used to study a vertically shaken two-dimensional granular medium of glass beads. This paper will also describe a few preliminary studies …

Pseudo Power Law Statistics In A Jammed, Amorphous Solid, Jacob Brian Hass

Physics

Simulations have shown that in many solid materials, rearrangements within the solid obey power-law statistics. A connection has been proposed between these statistics and the ability of a system to reach a limit cycle under cyclic driving. We study experimentally a 2D jammed solid that reaches such a limit cycle. Our solid consists of microscopic plastic beads adsorbed at an oil-water interface and cyclically sheared by a magnetically driven needle. We track each particles trajectory in the solid to identify rearrangements. By associating particles both spatially and temporally, we can measure the extent of each rearrangement. We study specifically the …