Physics Commons^™

Molecules And Metals In The Distant Universe: Sub-Mm And Optical Spectroscopy Of Quasar Absorbers, Sean Stephen Morrison

Theses and Dissertations

In order to gain a complete understanding of galaxy formation and evolution, knowledge of the atomic and molecular gas in the interstellar medium (ISM) is required. Absorption-line spectroscopy of quasars offers a powerful and luminosity independent probe of gas in distant galaxies. The Damped Lyman- systems (DLAs; 20.3 . log NHI ), are the highest neutral hydrogen column density quasar absorbers and contain a substantial fraction of the neutral gas available for star formation in the high-redshift Universe. This thesis presents a study of the metal content in some DLAs, based on optical spectroscopy, and a search for molecules based …

The Inferred Evolution Of The Cold Gas Properties Of Candels Galaxies At 0.5 < Z < 3.0, G. Popping, K. Caputi, S. C. Trager, Rachel S. Somerville, Avishai Dekel, Susan A. Kassin, Dale D. Kocevski, Anton M. Koekemoer, Sandra M. Faber, Henry C. Ferguson, A. Galametz, Norman A. Grogin, Yicheng Guo, Y. Lu, Arjen Van Der Wel, Benjamin J. Weiner

Physics and Astronomy Faculty Publications

We derive the total cold gas, atomic hydrogen, and molecular gas masses of approximately 24 000 galaxies covering four decades in stellar mass at redshifts 0.5 < z < 3.0, taken from the Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey survey. Our inferences are based on the inversion of a molecular hydrogen based star formation law, coupled with a prescription to separate atomic and molecular gas. We find that: (1) there is an increasing trend between the inferred cold gas (H i and H₂), H i, and H₂ mass and the stellar mass of galaxies down to stellar masses of 10⁸ M_⊙ already in place at z = 3; (2) the molecular fractions of cold gas increase with increasing stellar mass and look-back time; (3) there is hardly any evolution in the mean H i content of galaxies at fixed stellar mass; (4) the cold gas fraction and relative amount of molecular …

Comparison Of Experimental And Theoretical Electron-Impact-Ionization Triple-Differential Cross Sections For Ethane, Esam Ali, Kate Nixon, Andrw Murray, Chuangang Ning, James Colgan, Don H. Madison

Physics Faculty Research & Creative Works

We have recently examined electron-impact ionization of molecules that have one large atom at the center, surrounded by H nuclei (H₂O, NH₃, CH₄). All of these molecules have ten electrons; however, they vary in their molecular symmetry. We found that the triple-differential cross sections (TDCSs) for the highest occupied molecular orbitals (HOMOs) were similar, as was the character of the HOMO orbitals which had a p-type "peanut" shape. In this work, we examine ethane (C₂H₆) which is a molecule that has two large atoms surrounded by H nuclei, so that …

Theoretical And Experimental Study Of (E,2e) Ionization Of The Co₂ (1ΠG) Molecule At 250 Ev, Mevlut Dogan, Zehra Nur Ozer, Murat Yavuz, Osman Alwan, Adnan Naja, Boghos B. Joulakian, Esam S M Ali, Chuangang Ning, Don H. Madison

Physics Faculty Research & Creative Works

Triple differential cross sections (TDCSs) of the electron-impact ionization of carbon dioxide are measured in the coplanar asymmetric geometry, with incident electron energy value of 250eV, and ejected electron of 37eV. We will report the experimental results in comparison with the theoretical calculations of the M3DW and TCC (type 5) calculations.

First Evidence Of Interference Effects In The Ionization Of N₂ Molecule, Zehra Nur Ozer, Hari Chaluvadi, Mevlut Dogan, James Colgan, Don H. Madison

Physics Faculty Research & Creative Works

We will present an experimental and theoretical investigation of triple differential cross sections for electron- impact ionization of nitrogen molecules at intermediate energies. A discussion of interference effects contained in the theoretical and experimental interference factors will be presented.

Interference Effects For Intermediate Energy Electron-Impact Ionization Of H₂ And N₂ Molecules, Zehra Nur Ozer, Hari Chaluvadi, Don H. Madison, Mevlut Dogan

Physics Faculty Research & Creative Works

We have studied electron impact ionization of H₂ and N₂ molecules at intermediate energies to look for possible two center interference effects experimentally and theoretically. Here we report a study of the interference factor I for 250 eV electron-impact ionization. The experimental measurements are performed using a crossed-beam-type electron-electron coincidence spectrometer and theoretical calculations are obtained using the Molecular Three Body Distorted Wave Approximation (M3DW). We found that the I-factor demonstrated strong evidence for two-center interference effects for both H₂ and N₂. We also found that the I-factor is more sensitive to projectile angular scans …

Measurement Of The Formation Rate Of Muonic Hydrogen Molecules, V. A. Andreev, T. I. Banks, R. M. Carey, T. A. Case, S. M. Clayton, K. M. Crowe, J. Deutsch, J. Egger, S. J. Freedman, V. A. Ganzha, Tim Gorringe, F. E. Gray, D. W. Hertzog, M. Hildebrandt, P. Kammel, B. Kiburg, S. Knaack, P. A. Kravtsov, A. G. Krivshich, B. Lauss, K. R. Lynch, E. M. Maev, O. E. Maev, F. Mulhauser, C. Petitjean, G. E. Petrov, R. Prieels, G. N. Schapkin, G. G. Semenchuk, M. A. Soroka, Vladimir Tishchenko, A. A. Vasilyev, A. A. Vorobyov, M. E. Vznuzdaev, P. Winter

Physics and Astronomy Faculty Publications

Background: The rate λ_ppμ characterizes the formation of ppμ molecules in collisions of muonic pμ atoms with hydrogen. In measurements of the basic weak muon capture reaction on the proton to determine the pseudoscalar coupling g_P, capture occurs from both atomic and molecular states. Thus knowledge of λ_ppμ is required for a correct interpretation of these experiments.

Purpose: Recently the MuCap experiment has measured the capture rate Λ_S from the singlet pμ atom, employing a low-density active target to suppress ppμ formation [V. Andreev et al. (MuCap Collaboration), Phys. Rev. Lett. 110, 012504 (2013) …

Target Electron Ionization In Li²⁺-L-Li Collisions: A Multi-Electron Perspective, Maciej Dominik Piewanowski, Laszlo Gulyas, Marko W. Horbatsch, Johannes Goullon, Natalia Ferreira, Renate Hubele, Vitor L B D De Jesus, H. Lindenblatt, Katharina R. Schneider, Michael Schulz, Michael Schuricke, Z. Song, Shaofeng Zhang, Daniel Fischer, Tom Kirchner

Physics Faculty Research & Creative Works

Target electron removal in Li²⁺-Li collisions at 2290 keV/amu is studied experimentally and theoretically for ground and excited lithium target configurations. It is shown that in outer-shell ionization a single-electron process plays the dominant part. However, the K-shell ionization results are more difficult to interpret. According to our calculations, the process is shown to be strongly single-particle like. On one hand, a high resemblance between theoretical single-particle ionization and exclusive inner-shell ionization is demonstrated, and contributions from multi-electron processes are found to be weak. On the other hand, it is indicated by the discrepancy between experimental and single-particle …

Wavelength Dependent Specific Plasmon Resonance Coupling Of Single Silver Nanoparticles With Egfp, Kerry J. Lee, Tao Huang, Prakash D. Nallathamby

Chemistry & Biochemistry Faculty Publications

Noble metal nanoparticles (NPs) possess unique plasmonic properties, enabling them to serve as sub-diffraction light sources and nano-antennae for a wide range of applications. Here we report the specific interaction of single Ag NPs with single EGFP molecules and a high dependence of their interaction upon localized-surface-plasmon-resonance (LSPR) spectra of single Ag NPs and EGFP. The LSPR spectra of single red Ag NPs show a stunning 60 nm blue-shift during their incubation with EGFP, whereas they remain unchanged during their incubation with bovine serum albumin (BSA). Interestingly, the peak wavelengths of the LSPR spectra of green and blue Ag NPs …