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Open Access. Powered by Scholars. Published by Universities.®

2013

Liquid Crystals

Satyendra Kumar

Articles 1 - 4 of 4

Full-Text Articles in Physics

Effect Of Mosaicity In X-Ray Studies Of Critical Behavior At The Nematic To Smectic-A Transition, Andrew Primak, Michael Fisch, Satyendra Kumar Oct 2013

Effect Of Mosaicity In X-Ray Studies Of Critical Behavior At The Nematic To Smectic-A Transition, Andrew Primak, Michael Fisch, Satyendra Kumar

Satyendra Kumar

Previous studies of critical behavior at the nematic to smectic-A transition by high-resolution x-ray scattering were performed using low magnetic fields of 0.1-0.8 T. In those studies, the transverse resolution was limited by the sample mosaicity which complicated data analysis. In order to understand the effect of sample mosaicity on the measured values of critical exponents, the divergence of the smectic order correlation lengths xi(parallel to,perpendicular to) and susceptibility sigma(o) was studied in a magnetic field ranging from 0.25 to 5 T. The use of high (5 T) field reduced the sample mosaicity and improved the effective transverse resolution by …


Absence Of The Incommensurate Smectic-A Phase In Db7ocn+8ocb Mixtures, Satyendra Kumar, Li Chien, V. Surendranath Oct 2013

Absence Of The Incommensurate Smectic-A Phase In Db7ocn+8ocb Mixtures, Satyendra Kumar, Li Chien, V. Surendranath

Satyendra Kumar

The results of a high-resolution x-ray-diffraction study of the smectic phases in mixtures of DB7OCN and 8OCB show that the incommensurate smectic-Ai2 phase, previously reported in this mixture, is in fact a coexistence of the partially bilayer smectic-Ad and the bilayer smectic-A2phases at a first-order phase transition between them.


Critical Behavior At The Nematic To Lamellar Phase Transitions: A Synchrotron X-Ray Scattering Study, S. T. Shin, J. D. Brock, Mark Sutton, J. D. Lister, Satyendra Kumar Oct 2013

Critical Behavior At The Nematic To Lamellar Phase Transitions: A Synchrotron X-Ray Scattering Study, S. T. Shin, J. D. Brock, Mark Sutton, J. D. Lister, Satyendra Kumar

Satyendra Kumar

The nematic (N) to lamellar (Lα) phase transition in binary mixtures of cesium-perfluoro-octanoate (CsPFO) and water has been studied by high-resolution synchrotron x-ray scattering at 46.6 weight % CsPFO. The longitudinal correlation length ξ∥ and the susceptibility σ associated with the lamellar phase fluctuations in the N phase, measured over three decades of reduced temperature, diverge with critical exponents ν∥=0.86±0.04 and γ=1.37±0.11, respectively. These results show that the N to Lα phase transition is quantitatively similar to the N to smectic-A phase transition of thermotropic liquid crystals with a wider nematic range.


High Resolution X-Ray Diffraction Study Of Smectic Polymorphism And Fluctuations In A Mixture Of Octyl- And Decyl-Oxyphenyl Nitrobenzoyloxy Benzoate, Yushan Shi, George Nounesis, Carl W. Garland, Satyendra Kumar Oct 2013

High Resolution X-Ray Diffraction Study Of Smectic Polymorphism And Fluctuations In A Mixture Of Octyl- And Decyl-Oxyphenyl Nitrobenzoyloxy Benzoate, Yushan Shi, George Nounesis, Carl W. Garland, Satyendra Kumar

Satyendra Kumar

Reentrant nematic phases and smectic antiphases occur as intermediate states between two one-dimensionally ordered frustrated smectic phases, characterized by two competing and, in general, incommensurate smectic density waves. Using high-resolution x-ray diffraction, we have examined the evolution of the two density waves as a function of temperature in all phases of a mixture of polar liquid crystals octyl-and decyl-oxyphenyl nitrobenzoyloxy benzoate (47.4 mol% DB8ONO2+52.6% DB10ONO2). This mixture exhibits at temperatures below 127 degrees C the liquid-crystal phase sequence: smectic-A(d), reentrant nematic phases N-d and N-1, smectic-A(1), tilted antiphase (C) over tilde, smectic-A(2), and smectic-C-2 phases. Detailed investigations of several order-disorder …