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2000

Dissertations, Theses, and Masters Projects

Condensed Matter Physics

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Full-Text Articles in Physics

Structural Instabilities In Strontium Titanate From First-Principles Calculations, Christopher A. Lasota Jan 2000

Structural Instabilities In Strontium Titanate From First-Principles Calculations, Christopher A. Lasota

Dissertations, Theses, and Masters Projects

For some time now, first-principles calculation methods have proven to be an effective tool for investigating the physics of condensed matter systems. The additional use of density functional theory (DFT) and the local density approximation (LDA) has permitted even complex materials to be studied on desktop workstations with remarkable success. The incorporation of linear response theory into these methods has extended their power, allowing investigation of important dynamical properties.;Contained within the following pages are the results of a first-principles study of SrTiO3. This transition metal oxide is often grouped with ferroelectric materials, due to its similar composition and perovskite structure. …


Plasma Source Ion Implantation Of High Voltage Electrodes, Thomas Joseph Venhaus Jan 2000

Plasma Source Ion Implantation Of High Voltage Electrodes, Thomas Joseph Venhaus

Dissertations, Theses, and Masters Projects

Field emission and breakdown characteristics of high voltage, large area electrodes determine the performance of many vacuum-based electron sources. A corroborative project with the Thomas Jefferson National Accelerator Facility involves studying the behavior of such electrodes after nitrogen ion implantation. A Plasma Source Ion Implantation (PSII) facility is designed and constructed at William and Mary, and used to treat stainless steel electrodes. PSII is a novel implantation technique developed at the University of Wisconsin-Madison. A workpiece is submerged in a quiescent plasma of the species to be implanted. A series of high, negative voltages (30--100 kV) is applied to the …


Surface Processing By Rfi Pecvd And Rfi Psii, Lingling Wu Jan 2000

Surface Processing By Rfi Pecvd And Rfi Psii, Lingling Wu

Dissertations, Theses, and Masters Projects

An RFI plasma enhanced chemical vapor deposition (PECVD) system and a large-scale RF plasma source immersion ion implantation (PSII) system were designed and built to study two forms of 3-D surface processing, PECVD and PSII. Using the RFI PECVD system, Ti-6Al-4V substrates were coated with diamond-like carbon films with excellent tribological and optical properties. as an innovation, variable angle spectroscopic ellipsometry (VASE) was successfully applied for non-destructive, 3-D, large-area tribological coatings quality investigation.;Based on the experience with the RFI PECVD system, a large-scale RFICP source was designed and built for the PSIL Langmuir probe and optical emission spectroscopy studies indicated …