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Articles 1 - 2 of 2
Full-Text Articles in Physics
Temperature-Induced Configurational Excitations For Predicting Thermodynamic And Mechanical Properties Of Alloys, Duane D. Johnson, Andrei V. Smirnov, J. B. Staunton, F. J. Pinski, W. A. Shelton
Temperature-Induced Configurational Excitations For Predicting Thermodynamic And Mechanical Properties Of Alloys, Duane D. Johnson, Andrei V. Smirnov, J. B. Staunton, F. J. Pinski, W. A. Shelton
Duane D. Johnson
We show that a structural energy difference, ΔE, must include explicit symmetry-breaking changes of the electronic structure due to temperature-induced configurational excitations, and why ΔE at T=0 K is not necessarily relevant to thermodynamic and mechanical modeling. In Ni3V, we calculate a tenfold decrease of ΔE between D022 and L12 structures from T=0 K to states of order relevant to experiment. ΔE calculated directly from states with short-range order (8 meV) or with low partial order (7–12 meV) agree with high-T experiment (10 meV).
Quantitative Analysis Of Ultra-Fine Goethite In Rust Layer On Steel Using Mossbauer And X-Ray Diffraction Spectroscopy, Masato Yamashita, Toshihei Misawa, H. E. Townsend, D. C. Cook
Quantitative Analysis Of Ultra-Fine Goethite In Rust Layer On Steel Using Mossbauer And X-Ray Diffraction Spectroscopy, Masato Yamashita, Toshihei Misawa, H. E. Townsend, D. C. Cook
Physics Faculty Publications
We have proposed determination procedure of the relative amounts of rust constituents of steel. Mossbauer spectroscopy provides the relative amounts of crystalline rust constituents including ultra-fine crystals. A quantitative analysis of ultra-fine crystals is possible with the resolution of several percent by comparing the Mossbauer results with the relative amounts of rust constituents determined by X-ray diffraction spectroscopy.