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1999

Portland State University

Chemistry Faculty Publications and Presentations

Articles 1 - 3 of 3

Full-Text Articles in Physics

Anomalous Low-Temperature And High-Field Magnetoresistance In The Organic Superconductor Β″-(Bedt-Ttf)2sf5ch2cf2so3, F. Zuo, X. Su, P. Zhang, J. S. Brooks, J. Wosnitza, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard Sep 1999

Anomalous Low-Temperature And High-Field Magnetoresistance In The Organic Superconductor Β″-(Bedt-Ttf)2sf5ch2cf2so3, F. Zuo, X. Su, P. Zhang, J. S. Brooks, J. Wosnitza, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard

Chemistry Faculty Publications and Presentations

We report direct observations of anomalous magnetic-field and temperature dependences of the Shubnikov–de Haas oscillations in the organic superconductor β″-(BEDT-TTF)₂SF₅CH₂CF₂SO₃. Unlike other BEDT-TTF based organic superconductors, a nonmetallic temperature dependence of the background magnetoresistance is clearly observed. It is speculated that the nonmetallic behavior may arise from a partial nesting of the open orbits, similar to the field-induced density wave in the quasi-one-dimensional systems or a charge localization. The analysis of the magnetoresistance oscillations are found to deviate from the conventional Lifshitz-Kosevich description at high field and low temperatures. [S0163-1829(99)05433-8]


Optical Properties Of Β″-(Et)2sf5ch2cf2so3: A Layered Molecular Superconductor With Large Discrete Counterions, J. Dong, J. L. Musfeldt, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard Aug 1999

Optical Properties Of Β″-(Et)2sf5ch2cf2so3: A Layered Molecular Superconductor With Large Discrete Counterions, J. Dong, J. L. Musfeldt, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard

Chemistry Faculty Publications and Presentations

We report the polarized infrared and optical reflectance of β″-(ET)₂SF₅CH₂CF₂SO₃ as a function of temperature. This fully organic superconductor displays weakly metallic behavior over the entire temperature range of our investigation. The electronic properties present several unusual features including the lack of a conventional free carrier (Drude) response at low temperature, infrared localization phenomena, and an unexpected temperature dependence of the oscillator strength. Similar behavior is observed in other β and β″ superconductors above Tc, suggesting that this class of compounds is very close to a metal→insulator transition where electronic correlations are important and the Drude response carries very little …


Anisotropic Magnetoresistance In The Organic Superconductor Β″–(Bedt-Ttf)2sf5ch2cf2so3, X. Su, F. Zuo, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard Feb 1999

Anisotropic Magnetoresistance In The Organic Superconductor Β″–(Bedt-Ttf)2sf5ch2cf2so3, X. Su, F. Zuo, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard

Chemistry Faculty Publications and Presentations

In this paper, we report transport measurements of interlayer magnetoresistance with field parallel and perpendicular to the current direction in an all organic superconductor β″–(BEDT-TTF)₂SF₅CH₂CF₂SO₃. For H∥I, the isothermal magnetoresistance R(H) at low temperatures (T