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Full-Text Articles in Physics

Primary Relaxation Processes At The Band Edge Of Sio₂, Peter N. Saeta, Benjamin I. Greene Jun 1993

Primary Relaxation Processes At The Band Edge Of Sio₂, Peter N. Saeta, Benjamin I. Greene

All HMC Faculty Publications and Research

The kinetics of photoinduced defect formation in high-purity silicas has been studied by femtosecond transient absorption spectroscopy in the visible and ultraviolet. Band edge two-photon excitation produces singlet excitons which decay in 0.25 ps into defects with the absorption spectra of nonbridging oxygen hole centers (≡Si-O⋅) and silicon E’ centers (≡Si⋅). We identify these defect pairs with the self-trapped triplet exciton and the 0.25 ps decay with the motion of the photoexcited oxygen atom. Similar results were obtained with both crystalline and amorphous silica samples.


The Effect Of Ionizing And Displacive Radiation On The Thermal Conductivity Of Alumina, D. P. White Apr 1993

The Effect Of Ionizing And Displacive Radiation On The Thermal Conductivity Of Alumina, D. P. White

Physics Faculty Publications

The effects of ionizing and displacive radiation on the thermal conductivity of alumina at high temperatures have been studied. The phonon scattering relaxation times for several scattering mechanisms have been used to determine the effect on the thermal conductivity. The scattering mechanisms considered are scattering by electrons excited into the conduction band, vacancies, aluminum precipitates, and voids. It is found that under irradiation conditions where the electrical conductivity and dielectric loss tangent are greatly increased there is not a significant decrease in the thermal conductivity due to phonon-electron scattering. The conditions under which the scattering due to vacancies, aluminum precipitates, …