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Full-Text Articles in Physics
Infrared Fluorescence Studies Of Electronic-To-Vibrational Energy Transfer In A Br2:No System, Michael R. Hawks
Infrared Fluorescence Studies Of Electronic-To-Vibrational Energy Transfer In A Br2:No System, Michael R. Hawks
Theses and Dissertations
Steady-state photolysis techniques were used to study electronic-to- vibrational energy transfer mechanisms from atomic bromine to nitric oxide. Molecular bromine was photodissociated by 488nm radiation to produce equal parts Br(2P1/2) and Br(2P3/2). Side fluorescence intensity from Br(2P1/2) at 2.7 µm and from NO (v=1 and 2) around 5.3 µm measured as a function of bromine pressure and nitric oxide pressure. The branching ratio collisional transfer into the first and second states of NO was determined, and previously reported rates for quenching of NO by molecular bromine were verified.
High Resolution Fourier Transform Absorption Spectrum Of 79Br2 B3Π(0U+) ← X1ΣG+, Robert E. Franklin
High Resolution Fourier Transform Absorption Spectrum Of 79Br2 B3Π(0U+) ← X1ΣG+, Robert E. Franklin
Theses and Dissertations
High Resolution Fourier Transform Spectroscopy has been conducted for the 79Br2 B3π(0u+) ← X1Σg+ system of 79Br2. A total of 64 vibrational levels, including v"= 0-3 and v' = 10-33, have been observed and assigned. Rotational levels as high as J=76 were observed. A global fitting routine has been developed to fit the rotational spectra to the Dunham Expansion. Using Bv and Dv for both the X and B state, rotational transitions were calculated to within 0. 02 cm-1. The expansions of …
Hyperspectral Analysis Of Space Objects: Signal To Noise Evaluation, Daniel Hrovat
Hyperspectral Analysis Of Space Objects: Signal To Noise Evaluation, Daniel Hrovat
Theses and Dissertations
Hyperspectral analysis of space objects is being considered as a means of enhancing Space Object Identification. SOI capabilities. This study develops a mathematical simulation based on fundamental radiometry principles to evaluate the feasibility of hyperspectral analysis of space objects. The study uses Signal to Noise Ratio SNR as the basis for the feasibility evaluation, and addresses the question Is there enough target signal in narrow wavelength bandwidths to conduct hyperspectral measurements of space objects The analysis characterizes the target signal and noise sources using fundamental radiometry, and develops a flexible radiometry model which calculates the target signal count rate, and …
Vibrational Energy Transfer Within The B3Π(0+U) State Of 79Br2 Upon Collision With N2, O2, No, And Sf6, Gregory S. Williams
Vibrational Energy Transfer Within The B3Π(0+U) State Of 79Br2 Upon Collision With N2, O2, No, And Sf6, Gregory S. Williams
Theses and Dissertations
Vibrational transfer and electronic quenching in the lower vibrational levels of the 79Br2(B; v'≤3) were investigated using spectrally resolved, temporally resolved pulsed laser induced fluorescence techniques. Spectrally resolved emissions from collisionally populated Br2(B) vibrational levels were observed for N2, O2, NO, and SF6collision partners. The vibrational transfer was efficient in the nonpredissociative vibrational levels and is adequately described by the Montroll-Shuler model. An average fundamental vibrational transfer rate coefficient of kv(l,0)=3.4(±0.6) x 10-11 cm3/molec-sec predicts the vibrational transfer rates for the 0≤v'≤3 collisions with …
Design And Performance Evaluation Of A Gas Chromatograph Micromachined In A Single Crystal Silicon Substrate, Rocky R. Reston
Design And Performance Evaluation Of A Gas Chromatograph Micromachined In A Single Crystal Silicon Substrate, Rocky R. Reston
Theses and Dissertations
This investigation designed and developed a miniature gas chromatograph (GC) using silicon micromachining techniques. The GC is composed of a miniature sample injector (10 µl sample loop); a 0.9 m long, rectangular-shaped (300 µm width and 10 micrometers height) capillary column coated with a 0.2 µm thick copper phthalocyanine (CuPc) stationary phase; and a dual-detector scheme incorporating a CuPc-coated chemiresistor and a 125 µm diameter thermal conductivity detector bead. Micromachining was employed to fabricate the sample injector interface, the GC column, and the dual-detector cavity. A novel processing technique was developed to sublime the CuPc stationary phase coating on the …