Physics Commons^™

Direct Detection Of 5-Mev Protons By Flexible Organic Thin-Film Devices, Ilaria Fratelli, Andrea Ciavatti, Enrico Zanazzi, Laura Basiricò, Massimo Chiari, Laura Fabbri, John E. Anthony, Alberto Quaranta, Beatrice Fraboni

Chemistry Faculty Publications

The direct detection of 5-MeV protons by flexible organic detectors based on thin films is here demonstrated. The organic devices act as a solid-state detector, in which the energy released by the protons within the active layer of the sensor is converted into an electrical current. These sensors can quantitatively and reliably measure the dose of protons impinging on the sensor both in real time and in integration mode. This study shows how to detect and exploit the energy absorbed both by the organic semiconducting layer and by the plastic substrate, allowing to extrapolate information on the present and past …

Growth And Characterization Of Organic Ferroelectric And Magnetic Thin Films, Xuanyuan Jiang

Department of Physics and Astronomy: Dissertations, Theses, and Student Research

Compared to inorganic materials, organic materials are environmentally friendly, flexible, and often with low cost. Inspired by these advantages, organic materials-based electronics have been intensively studied for comparable or better functionalities to inorganic electronics.

This dissertation mainly focuses on the growth and characterizations of organic ferroelectrics and magnetic thin films. For organic ferroelectrics, we investigate the growth and ferroelectric measurements of thin film croconic acid (CA), a proton-transfer molecular ferroelectric (FE) material with a large spontaneous polarization and a small coercive field, as well as the origin of ferroelectricity in CA in terms of the photostriction effect, including the discovery …

Y2O3 Optical Constants Between 5 Nm And 50 Nm, Joseph B. Muhlestein, Benjamin D. Smith, Margaret Miles, Stephanie M. Thomas, Anthony Willey, David D. Allred, R. Steven Turley

Faculty Publications

We report optical constants of e-beam evaporated yttrium oxide Y₂O₃ thin films as determined from angle-dependent reflectance measurements at wavelengths from 5 to 50 nm. Samples were measured using synchrotron radiation at the Advanced Light Source. The experimental reflectance data were fit to obtain values for the index of refraction and thin film roughness. We compare our computed constants with those of previous researchers and those computed using the independent atom approximation from the CXRO website. We found that the index of refraction near 36 nm is much lower than previous data from Tomiki as reported by …

Molecular Assembly Of Monolayer-Protected Gold Nanoparticles And Their Chemical, Thermal, And Ultrasonic Stabilities, Steven Ray Isaacs

Masters Theses & Specialist Projects

Gold monolayer-protected nanoclusters (MPCs) with average diameters of 1-5 nm protected by alkane- and arenethiolates were synthesized. Mixed-monolayer protected nanoparticles (MMPCs) were prepared by functionalizing hexanethiolate-protected MPCs with either 11-mercaptoundecanoic acid (MUA-MMPC), 11-mercaptoundecanol (MUO-MMPC), or 4-aminothiophenol (ATP-MMPC) using ligand place exchange. Presentation of various chemical reagents such as nucleophile, acid, or base and change in physical environment through ultrasonic and thermal irradiation resulted in changes to particles and their physical properties. Thermogravimetric analysis (TGA) was used to measure maximum temperature of the derivated thermogravimetric peaks (Tmax,DTG) as a means of comparing temperature dependence of mass loss. The absorption spectrum within …

Vanadium Oxide Thin-Film Variable Resistor-Based Rf Switches, Kuanchang Pan, Weisong Wang, Eunsung Shin, Kelvin Freeman, Guru Subramanyam

Electrical and Computer Engineering Faculty Publications

Vanadium dioxide (VO2) is a unique phase change material (PCM) that possesses a metal-to-insulator transition property. Pristine VO2 has a negative temperature coefficient of resistance, and it undergoes an insulator-to-metal phase change at a transition temperature of 68°C. Such a property makes the VO2 thin-film-based variable resistor (varistor) a good candidate in reconfigurable electronics to be integrated with different RF devices such as inductors, varactors, and antennas. Series single-pole single-throw (SPST) switches with integrated VO2 thin films were designed, fabricated, and tested. The overall size of the device is 380 μm × 600 μm. The SPST switches were fabricated on …

A Lateral Field Excited Thin Film Bulk Acoustic Wave Sensor, Michael R. Fitzgerald

Honors College

Medical and environmental needs have served as a catalyst for the development of sensors that can probe the molecular level and below. This study addresses the practicality of highly sensitive aluminum nitride (AlN) thin film bulk acoustic wave resonators (FBARs) as sensors from theoretical and experimental points of view. Theoretically, COMSOL Multiphysics simulations predict that lateral field excitation of AlN produces an electric field perpendicular to the c-axis, with the electrical energy density being concentrated in the active area of the sensor. An analysis of the piezoelectrically stiffened Christoffel equation shows that the shear mode can be excited by an …

Modeling The Behavior Of Heat-Shrinkable Thin Films, Pavel Bělík, Bob Jennings, Mikhail M. Shvartsman, Christina U. Thomas

Faculty Authored Articles

We describe an asymptotic model for the behavior of PET-like heat-shrinkable thin films that includes both membrane and bending energies when the thickness of the film is positive. We compare the model to Koiter’s shell model and to models in which a membrane energy or a bending energy are obtained by Γ-convergence techniques. We also provide computational results for various temperature distributions applied to the films.

Stability Of Traveling Waves In Thin Liquid Films Driven By Gravity And Surfactant, Ellen Peterson, Michael Shearer, Thomas P. Witelski, Rachel Levy

All HMC Faculty Publications and Research

A thin layer of fluid flowing down a solid planar surface has a free surface height described by a nonlinear PDE derived via the lubrication approximation from the Navier Stokes equations. For thin films, surface tension plays an important role both in providing a significant driving force and in smoothing the free surface. Surfactant molecules on the free surface tend to reduce surface tension, setting up gradients that modify the shape of the free surface. In earlier work [12, 13J a traveling wave was found in which the free surface undergoes three sharp transitions, or internal layers, and the surfactant …

Effective Medium Theory, Rough Surfaces, And Moth’S Eyes, David D. Allred, Zephne Larsen, Joseph Muhlestein, R. Steven Turley, Anthony Willey

Faculty Publications

Optics in the extreme ultraviolet (XUV) have important applications in microelectronics, microscopy, space physics, and in imaging plasmas. Because of the short wavelengths involved in these applications, it is critical to account for interfacial roughness to accurately predict the reflection and absorption of XUV optics. This paper examines two possible effects of roughness on optical absorption, non-specular reflection and enhanced transmission and compares these to measured experimental data on a rough Y2O3 thin film.

The Effect Of Copt Crystallinity And Grain Texturing On Properties Of Exchange-Coupled Fe/Copt Systems, H. Oguchi, A. Zambano, M. Yu, Jason R. Hattrick-Simpers, D. Banerjee, Y. Liu, Z. L. Wang, J. P. Liu, S. E. Lofland, D. Josell, I. Takeuchi

Faculty Publications

The effect of the crystallinity and the grain texturing of CoPt hard layers on exchange coupled Fe/CoPt soft/hard magnetic systems was studied using gradient thickness multilayer thin films. We have studied the hard layer structures by transmission electron microscopy and x-ray diffraction, and characterized the exchange coupling interaction through magnetization loops obtained by the magneto-optical Kerr effect measurement. We found that exchange coupling strongly depends on the crystalline characteristics of the CoPt hard layer. There is correlation between the mixture of different grain orientations of the CoPt hard layer and coupling efficiency. In particular, interlayer coupling is enhanced when there …

Gravity-Driven Thin Liquid Films With Insoluble Surfactant: Smooth Traveling Waves, Rachel Levy, Michael Shearer, Thomas P. Witelski

All HMC Faculty Publications and Research

The flow of a thin layer of fluid down an inclined plane is modified by the presence of insoluble surfactant. For any finite surfactant mass, traveling waves are constructed for a system of lubrication equations describing the evolution of the free-surface fluid height and the surfactant concentration. The one-parameter family of solutions is investigated using perturbation theory with three small parameters: the coefficient of surface tension, the surfactant diffusivity, and the coefficient of the gravity-driven diffusive spreading of the fluid. When all three parameters are zero, the nonlinear PDE system is hyperbolic/degenerateparabolic, and admits traveling wave solutions in which the …

Rapid Structural Mapping Of Ternary Metallic Alloy Systems Using The Combinatorial Approach And Cluster Analysis, C. J. Long, Jason R. Hattrick-Simpers, M. Murakami, R. C. Srivastava, I. Takeuchi, V. L. Karen, X. Li

Faculty Publications

We are developing a procedure for the quick identification of structural phases in thin film composition spread experiments which map large fractions of compositional phase diagrams of ternary metallic alloy systems. An in-house scanning x-ray microdiffractometer is used to obtain x-ray spectra from 273 different compositions on a single composition spread library. A cluster analysissoftware is then used to sort the spectra into groups in order to rapidly discover the distribution of phases on the ternary diagram. The most representative pattern of each group is then compared to a database of known structures to identify known phases. Using this method, …

Data Management And Visualization Of X-Ray Diffraction Spectra From Thin Film Ternary Composition Spreads, I. Takeuchi, C. J. Long, O. O. Famodu, M. Murakami, Jason R. Hattrick-Simpers, G. W. Rubloff, M. Stukowski, K. Rajan

Faculty Publications

We discuss techniques for managing and visualizing x-ray diffraction spectrum data for thin film composition spreads which map large fractions of ternary compositional phase diagrams. An in-house x-ray microdiffractometer is used to obtain spectra from over 500 different compositions on an individual spread. The MATLAB software is used to quickly organize the data and create various plots from which one can quickly grasp different information regarding structural and phase changes across the composition spreads. Such exercises are valuable in rapidly assessing the “overall” picture of the structural evolution across phase diagrams before focusing in on specific composition regions for detailed …