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Full-Text Articles in Physics
Cu2+ And Cu3+ Acceptors In Β-Ga2O3 Crystals: A Magnetic Resonance And Optical Absorption Study, Timothy D. Gustafson, Nancy C. Giles, Brian C. Holloway, Christopher A. Lenyk, J. Jesenovec, J. S. Mccloy, M. D. Mccluskey, Larry E. Halliburton
Cu2+ And Cu3+ Acceptors In Β-Ga2O3 Crystals: A Magnetic Resonance And Optical Absorption Study, Timothy D. Gustafson, Nancy C. Giles, Brian C. Holloway, Christopher A. Lenyk, J. Jesenovec, J. S. Mccloy, M. D. Mccluskey, Larry E. Halliburton
Faculty Publications
Electron paramagnetic resonance (EPR) and optical absorption are used to characterize Cu2+ (3d9) and Cu3+ (3d8) ions in Cu-doped β-Ga2O3. These Cu ions are singly ionized acceptors and neutral acceptors, respectively (in semiconductor notation, they are Cu− and Cu0 acceptors). Two distinct Cu2+ EPR spectra are observed in the as-grown crystals. We refer to them as Cu2+(A) and Cu2+(B). Spin-Hamiltonian parameters (a g matrix and a 63,65Cu hyperfine matrix) are obtained from the angular dependence of each spectrum. Additional electron-nuclear double resonance …
Ground State Of The Singly Ionized Oxygen Vacancy In Rutile Tio2, A. T. Brant, Nancy C. Giles, Shan Yang (杨山), M. A. R. Sarker, S. Watauchi, M. Nagao, I. Tanaka, D. A. Tryk, A. Manivannan, Larry E. Halliburton
Ground State Of The Singly Ionized Oxygen Vacancy In Rutile Tio2, A. T. Brant, Nancy C. Giles, Shan Yang (杨山), M. A. R. Sarker, S. Watauchi, M. Nagao, I. Tanaka, D. A. Tryk, A. Manivannan, Larry E. Halliburton
Faculty Publications
Results from electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) experiments are used to establish the model for the ground state of the singly ionized oxygen vacancy in the interior of bulk rutile TiO2 crystals. Hyperfine from 47Ti and 49Ti nuclei show that the unpaired electron in this S = 1/2 defect is localized on one titanium ion adjacent to the oxygen vacancy (i.e., the spin is not shared by two titanium ions). These defects are formed at low temperature (∼35 K) in as-grown oxidized crystals when sub-band-gap 442 nm laser light converts doubly ionized nonparamagnetic …
Insertion Of Lithium Ions Into Tio2 (Rutile) Crystals: An Electron Paramagnetic Resonance Study Of The Li-Associated Ti3+ Small Polaron, A. T. Brant, Nancy C. Giles, Larry E. Halliburton
Insertion Of Lithium Ions Into Tio2 (Rutile) Crystals: An Electron Paramagnetic Resonance Study Of The Li-Associated Ti3+ Small Polaron, A. T. Brant, Nancy C. Giles, Larry E. Halliburton
Faculty Publications
Electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) are used to identify a Ti3+-Li+ complex in TiO2 crystals having the rutile structure. This defect consists of an interstitial Li+ ion adjacent to a substitutional Ti3+ ion (the unpaired electron on the Ti3+ ion provides charge compensation for the Li+ ion). The neutral Ti3+-Li+ complex is best described as a donor-bound small polaron and is similar in structure to the recently reported neutral fluorine and hydrogen donors in TiO2 (rutile). Lithium ions are diffused into the crystals at …