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Defect Induced Ferromagnetism In Undoped Zno Nanoparticles, K. Rainey, J. Chess, J. Eixenberger, D. A. Tenne, C. B. Hanna, A. Punnoose
Defect Induced Ferromagnetism In Undoped Zno Nanoparticles, K. Rainey, J. Chess, J. Eixenberger, D. A. Tenne, C. B. Hanna, A. Punnoose
Physics Faculty Publications and Presentations
Undoped ZnO nanoparticles (NPs) with size ∼12 nm were produced using forced hydrolysis methods using diethylene glycol (DEG) [called ZnO-I] or denatured ethanol [called ZnO-II] as the reaction solvent; both using Zn acetate dehydrate as precursor. Both samples showed weak ferromagnetic behavior at 300 K with saturation magnetization Ms = 0.077 ± 0.002 memu/g and 0.088 ± 0.013 memu/g for ZnO-I and ZnO-II samples, respectively. Fourier transform infrared(FTIR) spectra showed that ZnO-I nanocrystals had DEG fragments linked to their surface. Photoluminescence (PL) data showed a broad emission near 500 nm for ZnO-II which is absent in the ZnO-I samples, …