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Network-Based Assessments Of Percolation-Induced Current Distributions In Sheared Rod Macromolecular Dispersions, Feng Shi, Simi Wang, M. Gregory Forest, Peter J. Mucha, Ruhai Zhou

Mathematics & Statistics Faculty Publications

Conducting high-aspect-ratio rods with 1-10 nm-scale diameters dispersed in poorly conducting matrices at extremely low, O(1%), volume fractions induce dramatic gains in bulk conductivity at rod percolation threshold. Experimentally [Nan, Shen, and Ma, Annu. Rev. Mater. Res., 40 (2010), pp. 131-151], bulk conductivity abandons the prepercolation, linear scaling with volume fraction that follows from homogenization theory [Zheng et al., Adv. Funct. Mater., 15 (2005), pp. 627-638], and then postpercolation jumps orders of magnitude to approach that of the pure rod macromolecular phase as predicted by classical percolation theory [Stauffer and Aharony, Introduction to Percolation Theory, CRC …