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Full-Text Articles in Physics
Solid State Phase Transitions And Molecular Reorientation In Ortho-Carborane And Para-Carborane: An Isomer Effect, Peter A. Beckmann, Amos J. Leffler
Solid State Phase Transitions And Molecular Reorientation In Ortho-Carborane And Para-Carborane: An Isomer Effect, Peter A. Beckmann, Amos J. Leffler
Physics Faculty Research and Scholarship
The proton nuclear spin-lattice relaxation times at 30 MHz have been measured for ortho- and paracarborane between 170 and 310 K and between 210 and 320 K, respectively. Para-carborane undergoes solid-solid transitions at about 300 and 238 K while the ortho isomer shows only one transition at about 265 K. The details of the phase transitions are discussed and molecular reorientation in the isomers is compared.
Proton Spin-Lattice Relaxation In Meta-Carborane, Peter A. Beckmann, Armin Wendel
Proton Spin-Lattice Relaxation In Meta-Carborane, Peter A. Beckmann, Armin Wendel
Physics Faculty Research and Scholarship
No abstract provided.
A Deuterium Nuclear Magnetic Resonance Study Of Chain Disorder In Lamellar Potassium Palmitate: The Effect Of Long And Short Chain Guests, Peter A. Beckmann, E. E. Burnell, M. A. Heldman, K. R. Northey, T. P. Higgs
A Deuterium Nuclear Magnetic Resonance Study Of Chain Disorder In Lamellar Potassium Palmitate: The Effect Of Long And Short Chain Guests, Peter A. Beckmann, E. E. Burnell, M. A. Heldman, K. R. Northey, T. P. Higgs
Physics Faculty Research and Scholarship
The deuterium magnetic resonance spectra of lamellar phases of host perdeuterated potassium palmitate mixed with varying amounts of guest protiated potassium octanoate and behenate and 86.3 mol% D2O are reported. At higher temperatures, the short chain guests give rise to more fluidity and the long chain guests give rise to less fluidity towards the end of the host chain. At low temperatures there are changes in the interaction between the polar head group and the water which depend on sample composition. The transition from the lamellar phase to the low temperature gel phase is investigated and in some …