Physics Commons^™

Dielectric Saturation In Dipolar Fluids. I. The Single-Molecule Distribution Function, John D. Ramshaw

Physics Faculty Publications and Presentations

The functional-derivative formalism is used to investigate the form of the equilibrium single-molecule distribution function n(1) in a finite fluid system of rigid polar molecules subjected to a strong external electric field that varies slowly with position. The investigation is based on the assumption that the long-range asymptotic behavior of the direct correlation function is independent of the external field, and is hence the same as in the unperturbed fluid. This assumption implies that n(1) has the form of a single-molecule Boltzmann factor in which the interaction energy is that of a deformable quasidipole with the local Lorentz electric field …