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Theoretical Study Of Impurity-Induced First-Order Raman Spectra For The Alkali Halides, Arnold Karo, John R. Hardy
Theoretical Study Of Impurity-Induced First-Order Raman Spectra For The Alkali Halides, Arnold Karo, John R. Hardy
John R. Hardy Papers
A deformation-dipole model with first- and second-neighbor central short-range forces is used as a basis for calculating all symmetry-adapted combinations of eigenvectors (SACEV) necessary for the study of defect vibrations in alkali-halide crystals. As an example of the full set of spectral weight functions, which are tabulated separately, sample results are given for the predicted defect-activated E, Raman spectra for KC1, KI, RbCl, and KBr, assuming no force-constant changes and that the defect is located at a positive-ion site. The results show qualitative agreement with the earlier findings of Harley, Page, and Walker, even though the deformation-dipole model is not …
Theoretical Study Of Impurity-Induced First-Order Raman Spectra For The Alkali Halides, Arnold Karo, John Hardy
Theoretical Study Of Impurity-Induced First-Order Raman Spectra For The Alkali Halides, Arnold Karo, John Hardy
John R. Hardy Papers
A deformation-dipole model with first- and second-neighbor central short-range forces is used as a basis for calculating all symmetry-adapted combinations of eigenvectors (SACEV) necessary for the study of defect vibrations in alkali-halide crystals. As an example of the full set of spectral weight functions, which are tabulated separately, sample results are given for the predicted defect-activated E, Raman spectra for KCl, KI, RbCl, and KBr, assuming no force-constant changes and that the defect is located at a positive-ion site. The results show qualitative agreement with the earlier findings of Harley, Page, and Walker, even though the deformation-dipole model is not …