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Kinetic-Energy Release In Coulomb Explosion Of Metastable C3h52+, K. Gluch, J. Fedor, S. Matt-Leubner, Olof E. Echt, A. Stamatovic, M. Probst, P. Scheier, T. D. Mark
Kinetic-Energy Release In Coulomb Explosion Of Metastable C3h52+, K. Gluch, J. Fedor, S. Matt-Leubner, Olof E. Echt, A. Stamatovic, M. Probst, P. Scheier, T. D. Mark
Physics & Astronomy
C3H52+, formed by electron impact ionization of propane, undergoes metastable decay into C2H2++CH3+. We have monitored this reaction in a magnetic mass spectrometer of reversed geometry that is equipped with two electric sectors (BEE geometry). Three different techniques were applied to identify the fragment ions and determine the kinetic-energy release (KER) of spontaneous Coulomb explosion of C3H52+ in the second and third field free regions of the mass spectrometer. The KER distribution is very narrow, with a width of about 3% [root-mean square standard deviation]. An average KER of 4.58+/-0.15 eV is derived from the distribution. High level ab initio …