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Polyatomic Molecular Structure Retrieval Using Laser-Induced Electron Diffraction, Michael G. Pullen, Benjamin Wolter, Anh-Thu Le, Matthias Baudisch, Michael Hemmer, Arne Senftleben, M. Sclafani, Claus Dieter Schroeter, Joachim Ullrich, Robert Moshammer, C. D. Lin, Jens Biegert
Polyatomic Molecular Structure Retrieval Using Laser-Induced Electron Diffraction, Michael G. Pullen, Benjamin Wolter, Anh-Thu Le, Matthias Baudisch, Michael Hemmer, Arne Senftleben, M. Sclafani, Claus Dieter Schroeter, Joachim Ullrich, Robert Moshammer, C. D. Lin, Jens Biegert
Physics Faculty Research & Creative Works
Laser-induced electron diffraction is a developing dynamical imaging technique that is already able to probe molecular dynamics at few-femtosecond temporal resolutions and has the potential to reach the sub-femtosecond level. Here we provide the recipe for the extension of the technique to polyatomic molecules and we demonstrate the method by extracting the structure of aligned and anti-aligned acetylene (C₂H₂). We show that multiple bond lengths can be simultaneously imaged at high accuracy including elusive hydrogen containing bonds. Our results open the door to the investigation of larger complex molecules and the realization of a true molecular movie.
Imaging An Aligned Polyatomic Molecule With Laser-Induced Electron Diffraction, Michael G. Pullen, Benjamin Wolter, Anh-Thu Le, Matthias Baudisch, Michael Hemmer, Arne Senftleben, Claus Dieter Schroeter, Joachim Ullrich, Robert Moshammer, C. D. Lin, Jens Biegert
Imaging An Aligned Polyatomic Molecule With Laser-Induced Electron Diffraction, Michael G. Pullen, Benjamin Wolter, Anh-Thu Le, Matthias Baudisch, Michael Hemmer, Arne Senftleben, Claus Dieter Schroeter, Joachim Ullrich, Robert Moshammer, C. D. Lin, Jens Biegert
Physics Faculty Research & Creative Works
Laser-induced electron diffraction is an evolving tabletop method that aims to image ultrafast structural changes in gas-phase polyatomic molecules with sub-Ångström spatial and femtosecond temporal resolutions. Here we demonstrate the retrieval of multiple bond lengths from a polyatomic molecule by simultaneously measuring the C-C and C-H bond lengths in aligned acetylene. Our approach takes the method beyond the hitherto achieved imaging of simple diatomic molecules and is based on the combination of a 160kHz mid-infrared few-cycle laser source with full three-dimensional electron-ion coincidence detection. Our technique provides an accessible and robust route towards imaging ultrafast processes in complex gas-phase molecules …