Physics Commons^™

Discrimination Between Spin-Dependent Charge Transport And Spin-Dependent Recombination In Π-Conjugated Polymers By Correlated Current And Electroluminescence-Detected Magnetic Resonance, Marzieh Kavand, Douglas Baird, Kipp Van Schooten, Hans Malissa

Dartmouth Scholarship

Spin-dependent processes play a crucial role in organic electronic devices. Spin coherence can give rise to spin mixing due to a number of processes such as hyperfine coupling, and leads to a range of magnetic field effects. However, it is not straightforward to differentiate between pure single-carrier spin-dependent transport processes which control the current and therefore the electroluminescence, and spin-dependent electron-hole recombination which determines the electroluminescence yield and in turn modulates the current. We therefore investigate the correlation between the dynamics of spin-dependent electric current and spin-dependent electroluminescence in two derivatives of the conjugated polymer poly(phenylene-vinylene) using simultaneously measured pulsed …