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Electron Traps In Ag-Doped Li2B4O7 Crystals: The Role Of Ag Interstitial Ions, Timothy D. Gustafson, Brant E. Kananen, Nancy C. Giles, Brian C. Holloway, Volodymyr T. Adamiv, Ihor M. Teslyuk, Yaroslav V. Burak, Larry E. Halliburton
Electron Traps In Ag-Doped Li2B4O7 Crystals: The Role Of Ag Interstitial Ions, Timothy D. Gustafson, Brant E. Kananen, Nancy C. Giles, Brian C. Holloway, Volodymyr T. Adamiv, Ihor M. Teslyuk, Yaroslav V. Burak, Larry E. Halliburton
Faculty Publications
Electron paramagnetic resonance (EPR) is used to establish models for electron traps in Ag-doped lithium tetraborate (Li2B4O7) crystals. When exposed at room temperature to ionizing radiation, electrons are trapped at interstitial Ag+ ions and holes are trapped at Ag+ ions on Li+ sites. The trapped electrons occupy a 5s1 orbital on the interstitial Ag ions (some of the unpaired spin density is also on neighboring ions). Three EPR spectra are assigned to electrons trapped at interstitial Ag ions. Their g values are near 1.99 and they have resolved hyperfine structure …