Physics Commons^™

Revealing Interaction Of Organic Adsorbates With Semiconductor Surfaces Using Chemically Enhanced Raman, Andrew K. Kuhlman, Alexey T. Zayak

Physics and Astronomy Faculty Publications

Surface enhanced Raman spectroscopy (SERS) is frequently associated with "chemical enhancement" (CE), which is an effect of the chemical coupling between reporting molecules and surfaces. While SERS technique is mainly attributed to the studies of metallic surfaces, chemical coupling must be present on semiconductor surfaces as well. Here, we examine binding of trans-1,2-two(4-pyridyl) ethylene (BPE) to various crystallographic facets of PbSe semiconductor. The calculated off-resonant Raman spectra vary significantly on different crystallographic facets of PbSe, correlating with the electronic structure of each type of semiconductor surface. We distinguish situations when the charge transfer is present and when it is not, …