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Biological and Chemical Physics

Peer Reviewed Articles

2007

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Full-Text Articles in Physics

Exploring Renner-Teller Induced Quenching In The Reaction H(2S)+Nh(A1Δ): A Combined Experimental And Theoretical Study, L. Adam, W. Hack, George C. Mcbane, H. Zhu, Z.-W. Qu, Reinhard Schinke Jan 2007

Exploring Renner-Teller Induced Quenching In The Reaction H(2S)+Nh(A1Δ): A Combined Experimental And Theoretical Study, L. Adam, W. Hack, George C. Mcbane, H. Zhu, Z.-W. Qu, Reinhard Schinke

Peer Reviewed Articles

Experimental rate coefficients for the removal of NH(a1Δ) and ND(a1Δ) in collisions with H and D atoms are presented; all four isotope combinations are considered: NH+H, NH+D, ND+H, and ND+D. The experiments were performed in a quasistatic laser-flash photolysis/laser-induced fluorescence system at low pressures. NH(a1Δ) and ND(a1Δ) were generated by photolysis of HN3 and DN3, respectively. The total removal rate coefficients at room temperature are in the range of (3-5) x 1013 cm3 mol-1 s-1. For two ...