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Full-Text Articles in Physics
Thermo-Mechanical Response Of Self-Assembled Nanoparticle Membranes, Yifan Wang, Henry Chan, Badri Narayanan, Sean P. Mcbride, Subramanian K.R.S. Sankaranarayanan, Xiao-Min Lin, Heinrich M. Jaeger
Thermo-Mechanical Response Of Self-Assembled Nanoparticle Membranes, Yifan Wang, Henry Chan, Badri Narayanan, Sean P. Mcbride, Subramanian K.R.S. Sankaranarayanan, Xiao-Min Lin, Heinrich M. Jaeger
Dr. Sean P. McBride
Ultrathin membranes composed of metallic or semiconducting nanoparticles capped with short ligand molecules are hybrid materials that have attracted considerable research interest.1-12 In contrast to two-dimensional (2D) membranes such as graphene and transition metal dichalcogenides monolayers, nanoparticle membranes can be engineered to achieve widely tunable mechanical, electronic or optical properties through different combinations of inorganic cores and organic ligands. In terms of mechanical properties, these membranes can form large area (tens of microns in diameter) freestanding structures with high Young’s moduli (~GPa) and fracture strength.1,13-15 Molecular dynamics (MD) simulations have indicated how this mechanical robustness can arise from …
Fracture And Failure Of Nanoparticle Monolayers And Multilayers, Yifan Wang, Pongsakorn Kanjanaboos, Edward Barry Edward Barry, Sean P. Mcbride, Xiao-Min Lin, Heinrich M. Jaeger
Fracture And Failure Of Nanoparticle Monolayers And Multilayers, Yifan Wang, Pongsakorn Kanjanaboos, Edward Barry Edward Barry, Sean P. Mcbride, Xiao-Min Lin, Heinrich M. Jaeger
Dr. Sean P. McBride
We present an experimental investigation of fracture in self-assembled gold nanoparticle mono- and multilayers attached to elastomer substrates and subjected to tensile stress. Imaging the fracture patterns down to the scale of single particles provides detailed information about the crack width distribution and allows us to compare the scaling of the average crack spacing as a function of strain with predictions by shear-lag models. With increasing particle size, the fracture strength is found to increase while it decreases as the film thickness is built up layer by layer, indicating stress inhomogeneity in the thickness dimension.
Rhodizonic Acid On Noble Metals: Surface Reactivity And Coordination Chemistry, Donna A. Kunkel, James Hooper, Scott Simpson, Sumit Beniwal, Katie L. Morrow, Douglas C. Smith, Kimberly Cousins, Stephen Ducharme, Eva Zurek, Axel Enders
Rhodizonic Acid On Noble Metals: Surface Reactivity And Coordination Chemistry, Donna A. Kunkel, James Hooper, Scott Simpson, Sumit Beniwal, Katie L. Morrow, Douglas C. Smith, Kimberly Cousins, Stephen Ducharme, Eva Zurek, Axel Enders
Axel Enders
A study of the two-dimensional crystallization of rhodizonic acid on the crystalline surfaces of gold and copper is presented. Rhodizonic acid, a cyclic oxocarbon related to the ferroelectric croconic acid and the antiferroelectric squaric acid, has not been synthesized in bulk crystalline form yet. Capitalizing on surface-assisted molecular self-assembly, a two-dimensional analogue to the well-known solution-based coordination chemistry, two-dimensional structures of rhodizonic acid were stabilized under ultrahigh vacuum on Au(111) and Cu(111) surfaces. Scanning tunneling microscopy, coupled with first-principles calculations, reveals that on the less reactive Au surface, extended two-dimensional islands of rhodizonic acid are formed, in which the molecules …
Self-Assembled Nanometer-Scale Magnetic Networks On Surfaces: Fundamental Interactions And Functional Properties, Carlo Carbone, Sandra Gardonio, Paolo Moras, Samir Lounis, Marcus Heide, Gustav Bihlmayer, Nicolae Atodiresei, Peter Dederichs, Stefan Blügel, Sergio Vlaic, Anne Lehnert, Safia Ouazi, Stefano Rusponi, Harald Brune, Jan Honolka, Axel Enders, Klaus Kern, Sebastian Stepanow, Cornelius Krull, Timofey Balashov, Aitor Mugarza, Pietro Gambardella
Self-Assembled Nanometer-Scale Magnetic Networks On Surfaces: Fundamental Interactions And Functional Properties, Carlo Carbone, Sandra Gardonio, Paolo Moras, Samir Lounis, Marcus Heide, Gustav Bihlmayer, Nicolae Atodiresei, Peter Dederichs, Stefan Blügel, Sergio Vlaic, Anne Lehnert, Safia Ouazi, Stefano Rusponi, Harald Brune, Jan Honolka, Axel Enders, Klaus Kern, Sebastian Stepanow, Cornelius Krull, Timofey Balashov, Aitor Mugarza, Pietro Gambardella
Axel Enders
Nanomagnets of controlled size, organized into regular patterns open new perspectives in the fields of nanoelectronics, spintronics, and quantum computation. Self-assembling processes on various types of substrates allow designing fine-structured architectures and tuning of their magnetic properties. Here, starting from a description of fundamental magnetic interactions at the nanoscale, we review recent experimental approaches to fabricate zero-, one-, and two-dimensional magnetic particle arrays with dimensions reduced to the atomic limit and unprecedented areal density. We describe systems composed of individual magnetic atoms, metal-organic networks, metal wires, and bimetallic particles, as well as strategies to control their magnetic moment, anisotropy, and …
Self-Assembly Of Helical Ribbons, Yevgeniya V. Zastavker, Neer Asherie, Aleksey Lomakin, Jayanti Pande, Joanne M. Donovan, Joel M. Schnur, George B. Benedek
Self-Assembly Of Helical Ribbons, Yevgeniya V. Zastavker, Neer Asherie, Aleksey Lomakin, Jayanti Pande, Joanne M. Donovan, Joel M. Schnur, George B. Benedek
Yevgeniya V. Zastavker
The self-assembly of helical ribbons is examined in a variety of multicomponent enantiomerically pure systems that contain a bile salt or a nonionic detergent, a phosphatidylcholine or a fatty acid, and a steroid analog of cholesterol. In almost all systems, two different pitch types of helical ribbons are observed: high pitch, with a pitch angle of 54 ± 2°, and low pitch, with a pitch angle of 11 ± 2°. Although the majority of these helices are right-handed, a small proportion of left-handed helices is observed. Additionally, a third type of helical ribbon, with a pitch angle in the range …
Stability Of A Strongly Anisotropic Thin Epitaxial Film In A Wetting Interaction With Elastic Substrate, Mikhail Khenner, Wondimu T. Tekalign, Margo S. Levine
Stability Of A Strongly Anisotropic Thin Epitaxial Film In A Wetting Interaction With Elastic Substrate, Mikhail Khenner, Wondimu T. Tekalign, Margo S. Levine
Mikhail Khenner
The linear dispersion relation for longwave surface perturbations, as derived by Levine et al. Phys. Rev. B 75, 205312 (2007) is extended to include a smooth surface energy anisotropy function with a variable anisotropy strength (from weak to strong, such that sharp corners and slightly curved facets occur on the corresponding Wulff shape). Through detailed parametric studies it is shown that a combination of a wetting interaction and strong anisotropy, and even a wetting interaction alone results in complicated linear stability characteristics of strained and unstrained films.