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Rydberg states

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Electric Field Controlled, Pulsed Autoionization In Two Electron Wave Packets, J. Greg Story, Heider N. Ereifej Jan 2001

Electric Field Controlled, Pulsed Autoionization In Two Electron Wave Packets, J. Greg Story, Heider N. Ereifej

Physics Faculty Research & Creative Works

In this paper, control of the evolution of a two electron wave packet through the application of a static electric field is demonstrated. Specifically, application of a small electric field is used to produce pulsed autoionization events, the timing of which can be controlled on a picosecond time scale. The technique is demonstrated by exciting calcium atoms using a short-pulsed laser to the 4p3/219d doubly excited state, which is energy degenerate with the 4p1/2nk stark states. Evolution of the resultant wave packet is monitored through the application of a second short laser pulse, which stimulates the …


Landau-Zener Treatment Of Intensity-Tuned Multiphoton Resonances Of Potassium, J. Greg Story, D. I. Duncan, Thomas F. Gallagher Aug 1994

Landau-Zener Treatment Of Intensity-Tuned Multiphoton Resonances Of Potassium, J. Greg Story, D. I. Duncan, Thomas F. Gallagher

Physics Faculty Research & Creative Works

When exposed to intense light of ~580 nm, the ground state of K shifts up in energy, passing through two photon resonances with Rydberg states, and finally crossing the two-photon ionization limit. We have used laser pulses of varying duration to study the nature of the population transfer from the ground state to the excited state due to the intensity-tuned resonances encountered during the rising edge of the pulse. A dynamic Floquet approach in which the resonances are treated as avoided crossings of the Floquet energy levels is used to model the population transfer and gives excellent agreement with the …