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Toward Non-Invasive Measurement Of Atmospheric Temperature Using Vibro-Rotational Raman Spectra Of Diatomic Gases, Tyler Capek, Jacek Borysow, Claudio Mazzoleni, Massimo Moraldi

Michigan Tech Publications

We demonstrate precise determination of atmospheric temperature using vibro-rotational Raman (VRR) spectra of molecular nitrogen and oxygen in the range of 292–293 K. We used a continuous wave fiber laser operating at 10 W near 532 nm as an excitation source in conjunction with a multi-pass cell. First, we show that the approximation that nitrogen and oxygen molecules behave like rigid rotors leads to erroneous derivations of temperature values from VRR spectra. Then, we account for molecular non-rigidity and compare four different methods for the determination of air temperature. Each method requires no temperature calibration. The first method involves fitting …