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Polymer

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Full-Text Articles in Physics

Polymer Molded Templates For Nanostructured Amorphous Silicon Photovoltaics, Lei Pei, Amy Balls, Cary Tippets, Jonathan Abbott, Matthew R. Linford, David D. Allred, Richard R. Vanfleet, Robert C. Davis, Jian Hu, Arun Madan Apr 2011

Polymer Molded Templates For Nanostructured Amorphous Silicon Photovoltaics, Lei Pei, Amy Balls, Cary Tippets, Jonathan Abbott, Matthew R. Linford, David D. Allred, Richard R. Vanfleet, Robert C. Davis, Jian Hu, Arun Madan

Faculty Publications

Here, the authors report the fabrication of transparent polymer templates for nanostructured amorphous silicon photovoltaics using low-cost nanoimprint lithography of polydimethylsiloxane. The template contains a square two-dimensional array of high-aspect-ratio nanoholes (300 nm diameter by 1 µm deep holes) on a 500X500 nm^2 pitch. A 100 nm thick layer of a-Si:H was deposited on the template surface resulting in a periodically nanostructured film. The optical characterization of the nanopatterned film showed lower light transmission at 600-850 nm wavelengths and lower light reflection at 400-650 nm wavelengths, resulting in 20% higher optical absorbance at AM 1.5 spectral irradiance versus a nonpatterned …


Density And Conformation With Relaxed Substrate, Bulk, And Interface In Electrophoretic Deposition Of Polymer Chains, F.W. Bentrem, J. Xie, Ras B. Pandey Sep 2002

Density And Conformation With Relaxed Substrate, Bulk, And Interface In Electrophoretic Deposition Of Polymer Chains, F.W. Bentrem, J. Xie, Ras B. Pandey

Faculty Publications

Characteristics of relaxed density profile and conformation of polymer chains are studied by a Monte Carlo simulation on a discrete lattice in three dimensions using different segmental (kink-jump (K), crank-shaft (C), reptation (R)) dynamics. Three distinct density regimes, substrate, bulk, and interface, are identified. With the KC segmental dynamics, we find that the substrate coverage grows with a power law, dstγ with a field (E) dependent non-universal exponent γ=0.23+0.7E. The bulk volume fraction db and the substrate polymer density (ds) increases with the field with power-laws (db …