Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Physics
Neutral Nitrogen Acceptors In Zno: The 67Zn Hyperfine Interactions, Eric M. Golden, S. M. Evans, Larry E. Halliburton, Nancy C. Giles
Neutral Nitrogen Acceptors In Zno: The 67Zn Hyperfine Interactions, Eric M. Golden, S. M. Evans, Larry E. Halliburton, Nancy C. Giles
Faculty Publications
Electron paramagnetic resonance (EPR) is used to characterize the 67Zn hyperfine interactions associated with neutral nitrogen acceptors in zinc oxide. Data are obtained from an n-type bulk crystal grown by the seeded chemical vapor transport method. Singly ionized nitrogen acceptors (N−) initially present in the crystal are converted to their paramagnetic neutral charge state (N0) during exposure at low temperature to 442 or 633 nm laser light. The EPR signals from these N0 acceptors are best observed near 5 K. Nitrogen substitutes for oxygen ions and has four nearest-neighbor cations. The zinc ion …
Insertion Of Lithium Ions Into Tio2 (Rutile) Crystals: An Electron Paramagnetic Resonance Study Of The Li-Associated Ti3+ Small Polaron, A. T. Brant, Nancy C. Giles, Larry E. Halliburton
Insertion Of Lithium Ions Into Tio2 (Rutile) Crystals: An Electron Paramagnetic Resonance Study Of The Li-Associated Ti3+ Small Polaron, A. T. Brant, Nancy C. Giles, Larry E. Halliburton
Faculty Publications
Electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) are used to identify a Ti3+-Li+ complex in TiO2 crystals having the rutile structure. This defect consists of an interstitial Li+ ion adjacent to a substitutional Ti3+ ion (the unpaired electron on the Ti3+ ion provides charge compensation for the Li+ ion). The neutral Ti3+-Li+ complex is best described as a donor-bound small polaron and is similar in structure to the recently reported neutral fluorine and hydrogen donors in TiO2 (rutile). Lithium ions are diffused into the crystals at …